Uranium(Ⅵ) complex [UO2((R,S)-1,1′-binaphthylene-2,2′-dicarboxylate)(H2O)] was obtained by thehydrothermal treatment of UO2(NO3)2.6H2O with(R,S)-1,1′-binaphthylene-2,2′-dicarboxylic acid(BCA)(L) in water at 180 ...Uranium(Ⅵ) complex [UO2((R,S)-1,1′-binaphthylene-2,2′-dicarboxylate)(H2O)] was obtained by thehydrothermal treatment of UO2(NO3)2.6H2O with(R,S)-1,1′-binaphthylene-2,2′-dicarboxylic acid(BCA)(L) in water at 180 ℃ in Pyrex tube.The crystal belongs to monoclinic system,space group C2/c,with a=1.640 3(3) nm,b= 1.1967(2) nm,c=1.0663(17) nm,β=104.412(4)°,V=2.0272(6) nm3,Z=4.CCDC: 659617.展开更多
A very complex 3D Uranium(Ⅳ) metal-organic framework was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R,S)-2,2′-dinitro-biphenyl-4,4′-dicarboxylic acid (BTNCA) (L) in water at 180 ℃ in Pyrex...A very complex 3D Uranium(Ⅳ) metal-organic framework was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R,S)-2,2′-dinitro-biphenyl-4,4′-dicarboxylic acid (BTNCA) (L) in water at 180 ℃ in Pyrex tubes. The crystal belongs to monoclinic system with space group P21/c, and a=0.545 90(3) nm, b=3.676 01(18) nm, c=2.659 81(13) nm, β=91.4060(10)°, V=5.335 9(5) nm3, Z=4. CCDC:659615.展开更多
Uranium(Ⅵ)complex {[UO2((R,S)-1,1′-biphenyl-6,6′-dinitro-2,2′-dicarboxylate)(H2O)](H2O)}was obtained by the hydrothermal treatment of UO2(NO3)2.6H2O with(R,S)-6,6′-dinitro-biphenyl-2,2′-dicarboxylic acid(BSNCA) ...Uranium(Ⅵ)complex {[UO2((R,S)-1,1′-biphenyl-6,6′-dinitro-2,2′-dicarboxylate)(H2O)](H2O)}was obtained by the hydrothermal treatment of UO2(NO3)2.6H2O with(R,S)-6,6′-dinitro-biphenyl-2,2′-dicarboxylic acid(BSNCA) (L) in water at 180 ℃ in Pyrex tube.The crystal belongs to triclinic system,space group P1,with a=0.90345(14) nm,b=1.02443(16) nm,c=1.05895(16) nm,α=90.411(3)°,β=112.934(3)°,γ=92.554(3)°.CCDC: 659613.展开更多
文摘Uranium(Ⅵ) complex [UO2((R,S)-1,1′-binaphthylene-2,2′-dicarboxylate)(H2O)] was obtained by thehydrothermal treatment of UO2(NO3)2.6H2O with(R,S)-1,1′-binaphthylene-2,2′-dicarboxylic acid(BCA)(L) in water at 180 ℃ in Pyrex tube.The crystal belongs to monoclinic system,space group C2/c,with a=1.640 3(3) nm,b= 1.1967(2) nm,c=1.0663(17) nm,β=104.412(4)°,V=2.0272(6) nm3,Z=4.CCDC: 659617.
文摘A very complex 3D Uranium(Ⅳ) metal-organic framework was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R,S)-2,2′-dinitro-biphenyl-4,4′-dicarboxylic acid (BTNCA) (L) in water at 180 ℃ in Pyrex tubes. The crystal belongs to monoclinic system with space group P21/c, and a=0.545 90(3) nm, b=3.676 01(18) nm, c=2.659 81(13) nm, β=91.4060(10)°, V=5.335 9(5) nm3, Z=4. CCDC:659615.
文摘Uranium(Ⅵ)complex {[UO2((R,S)-1,1′-biphenyl-6,6′-dinitro-2,2′-dicarboxylate)(H2O)](H2O)}was obtained by the hydrothermal treatment of UO2(NO3)2.6H2O with(R,S)-6,6′-dinitro-biphenyl-2,2′-dicarboxylic acid(BSNCA) (L) in water at 180 ℃ in Pyrex tube.The crystal belongs to triclinic system,space group P1,with a=0.90345(14) nm,b=1.02443(16) nm,c=1.05895(16) nm,α=90.411(3)°,β=112.934(3)°,γ=92.554(3)°.CCDC: 659613.
