Iron oxide supported Au nanomaterials are one of the most studied catalysts for low-temperature CO oxidation.Catalytic performance not only critically depends on the size of the supported Au nanoparticles(NPs)but also...Iron oxide supported Au nanomaterials are one of the most studied catalysts for low-temperature CO oxidation.Catalytic performance not only critically depends on the size of the supported Au nanoparticles(NPs)but also strongly on the chemical nature of the iron oxide.In this study,Au NPs supported on iron oxide nanorods with different surface properties throughβ-FeOOH annealing,at varying temperatures,were synthesized,and applied in the CO oxidation.Detailed characterizations of the interactions between Au NPs and iron oxides were obtained by X-ray diffraction,transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy.The results indicate that the surface hydroxyl group on the Au/FeOOH catalyst,before calcination(Au/FeOOH-fresh),could facilitate the oxygen adsorption and dissociation on positively charged Au,thereby contributing to the low-temperature CO oxidation reactivity.After calcination at 200℃,under air exposure,the chemical state of the supported Au NP on varied iron oxides partly changed from metal cation to Au0,along with the disappearance of the surface OH species.Au/FeOOH with the highest Au0 content exhibits the highest activity in CO oxidation,among the as-synthesized catalysts.Furthermore,good durability in CO oxidation was achieved over the Au/FeOOH catalyst for 12 h without observable deactivation.In addition,the advanced identical-location TEM method was applied to the gas phase reaction to probe the structure evolution of the Au/iron oxide series of the catalysts and support structure.A Au NP size-dependent Ostwald ripening process mediated by the transport of Au(CO)x mobile species under certain reaction conditions is proposed,which offers a new insight into the validity of the structure-performance relationship.展开更多
Palaeosols associated with fluvial of the Siwalik Group are and lacustrine deposits that occur as thick multiple pedocomplexes. The bright red color of the palaeosol beds has been earlier interpreted as a result of ho...Palaeosols associated with fluvial of the Siwalik Group are and lacustrine deposits that occur as thick multiple pedocomplexes. The bright red color of the palaeosol beds has been earlier interpreted as a result of hot and arid palaeoclimate. However, as against this view, our investigations of the bright red palaeosol beds of the Lower Siwaliks suggest that the climate was cool and subhumid, instead of hot and arid during the deposition of these beds. Since cold climate is not very conducive to impart red coloration, further research is needed to explain the cause of these red beds. For this, the micromorphological study of soil thin sections was done which showed the presence of features such as dissolution and recrystallisation of quartz, feldspar and mica, compaction, slickensides, presence of calcite spars, subrounded and cracked nature of quartz grains, microfabric, complex patterns of birefringence fabrics, pigmentary ferric oxides, thick cutans and cementation by calcite. These features indicate that diagenesis took place on a large scale in these sediments. The positive Eh and neutral-alkaline pH of soils also suggest that the conditions were favorable for the formation of diagenetic red beds. During burial diagenesis of sediments, the hydroxides of ferromagnesian minerals got converted into ferric oxide minerals （hematite）. During deep burial diagenesis smectite was converted into illite and the preponderance of illite over smectite with increasing depth of burial also indicates the diagenesis of sediments. Thus, the red color of the Lower Siwalik palaeosols seems to be due mainly to the burial diagenesis of sediments and does not appear to be due to the then prevailing climatic condition.展开更多
A simple ultrasound-assisted co-precipitation method was developed to prepare ferroferric oxide/graphene oxide magnetic nanoparticles(Fe_3O_4/CO MNPs).The hysteresis loop of Fe_3O_4/GO MNPs demonstrated that the sampl...A simple ultrasound-assisted co-precipitation method was developed to prepare ferroferric oxide/graphene oxide magnetic nanoparticles(Fe_3O_4/CO MNPs).The hysteresis loop of Fe_3O_4/GO MNPs demonstrated that the sample was typical of superparamagnetic material.The samples were characterized by transmission electron microscope,and it is found that the particles are of small size.The Fe_3O_4/GO MNPs were further used as an adsorbent to remove Rhodamine B.The effects of initial pH of the solution,the dosage of adsorbent,temperature,contact time and the presence of interfering dyes on adsorption performance were investigated as well.The adsorption equilibrium and kinetics data were fitted well with the Freundlich isotherm and the pseudosecond-order kinetic model respectively.The adsorption process followed intra-particle diffusion model with more than one process affecting the adsorption of Rhodamine B.And the adsorption process was endothermic in nature.Furthermore,the magnetic composite with a high adsorption capacity of Rhodamine B could be effectively and simply separated using an external magnetic field.And the used particles could be regenerated and recycled easily.The magnetic composite could find potential applications for the removal of dye pollutants.展开更多
Objective：To evaluate the in vitro and in vivo toxicity of self-prepared nanosized Fe2O3, which has the potential implication in tumor hyperthermia. Methods： Fe2O3 nanoparticles were prepared by improving co-precipi...Objective：To evaluate the in vitro and in vivo toxicity of self-prepared nanosized Fe2O3, which has the potential implication in tumor hyperthermia. Methods： Fe2O3 nanoparticles were prepared by improving co-precipitation, which characterization was detected by TEM, XRD, CMIAS, EDS. MTT assay was used to evaluate the in vitro cytotoxicity test; hemolytic test was carried out to estimate whether it has blood toxicity; Fe2O3 suspended in sterile 0.9% NaCl was intraperitoneally injected into Kumning mouse to calculate the LD50 ; micronucleus （MN） were reckoned to identify whether it is genotoxic. Results：The nanoparticles are brown spherical particles with diameter ranging from 8 to 15 nm, which have good decentralization and stability. The experiments also showed that the toxicity of the material on mouse fibroblast （L-929） cell lines was 0 - 1 degree ; it has no hemolysis activity; LD50 arrived at 5.45 g/kg^-1 after intraperitoneal injection of 1 ml suspension; micronucleus test showed that it has no genotoxic effects either. Conclusion： The results showed that the Fe2O3 nanoparticles are prepared successfully, the self-prepared nanosized Fe2O3 is a kind of high biocompatibility materials and perhaps it is suitable for further application in tumor hyperthermia.展开更多
基金supported by the National Natural Science Foundation of China(21773269,21761132025,91545119,21703262)the Youth Innovation Promotion Association CAS(2015152)+1 种基金the Joint Foundation of Liaoning Province Natural Science FoundationShenyang National Laboratory for Materials Science(20180510047)~~
文摘Iron oxide supported Au nanomaterials are one of the most studied catalysts for low-temperature CO oxidation.Catalytic performance not only critically depends on the size of the supported Au nanoparticles(NPs)but also strongly on the chemical nature of the iron oxide.In this study,Au NPs supported on iron oxide nanorods with different surface properties throughβ-FeOOH annealing,at varying temperatures,were synthesized,and applied in the CO oxidation.Detailed characterizations of the interactions between Au NPs and iron oxides were obtained by X-ray diffraction,transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy.The results indicate that the surface hydroxyl group on the Au/FeOOH catalyst,before calcination(Au/FeOOH-fresh),could facilitate the oxygen adsorption and dissociation on positively charged Au,thereby contributing to the low-temperature CO oxidation reactivity.After calcination at 200℃,under air exposure,the chemical state of the supported Au NP on varied iron oxides partly changed from metal cation to Au0,along with the disappearance of the surface OH species.Au/FeOOH with the highest Au0 content exhibits the highest activity in CO oxidation,among the as-synthesized catalysts.Furthermore,good durability in CO oxidation was achieved over the Au/FeOOH catalyst for 12 h without observable deactivation.In addition,the advanced identical-location TEM method was applied to the gas phase reaction to probe the structure evolution of the Au/iron oxide series of the catalysts and support structure.A Au NP size-dependent Ostwald ripening process mediated by the transport of Au(CO)x mobile species under certain reaction conditions is proposed,which offers a new insight into the validity of the structure-performance relationship.
文摘Palaeosols associated with fluvial of the Siwalik Group are and lacustrine deposits that occur as thick multiple pedocomplexes. The bright red color of the palaeosol beds has been earlier interpreted as a result of hot and arid palaeoclimate. However, as against this view, our investigations of the bright red palaeosol beds of the Lower Siwaliks suggest that the climate was cool and subhumid, instead of hot and arid during the deposition of these beds. Since cold climate is not very conducive to impart red coloration, further research is needed to explain the cause of these red beds. For this, the micromorphological study of soil thin sections was done which showed the presence of features such as dissolution and recrystallisation of quartz, feldspar and mica, compaction, slickensides, presence of calcite spars, subrounded and cracked nature of quartz grains, microfabric, complex patterns of birefringence fabrics, pigmentary ferric oxides, thick cutans and cementation by calcite. These features indicate that diagenesis took place on a large scale in these sediments. The positive Eh and neutral-alkaline pH of soils also suggest that the conditions were favorable for the formation of diagenetic red beds. During burial diagenesis of sediments, the hydroxides of ferromagnesian minerals got converted into ferric oxide minerals （hematite）. During deep burial diagenesis smectite was converted into illite and the preponderance of illite over smectite with increasing depth of burial also indicates the diagenesis of sediments. Thus, the red color of the Lower Siwalik palaeosols seems to be due mainly to the burial diagenesis of sediments and does not appear to be due to the then prevailing climatic condition.
基金Supported by the National Natural Science Foundation of China(21107143,21207033)the Fundamental Research Funds for the Central Universities,South-Central University for Nationalities(CZY15003)
文摘A simple ultrasound-assisted co-precipitation method was developed to prepare ferroferric oxide/graphene oxide magnetic nanoparticles(Fe_3O_4/CO MNPs).The hysteresis loop of Fe_3O_4/GO MNPs demonstrated that the sample was typical of superparamagnetic material.The samples were characterized by transmission electron microscope,and it is found that the particles are of small size.The Fe_3O_4/GO MNPs were further used as an adsorbent to remove Rhodamine B.The effects of initial pH of the solution,the dosage of adsorbent,temperature,contact time and the presence of interfering dyes on adsorption performance were investigated as well.The adsorption equilibrium and kinetics data were fitted well with the Freundlich isotherm and the pseudosecond-order kinetic model respectively.The adsorption process followed intra-particle diffusion model with more than one process affecting the adsorption of Rhodamine B.And the adsorption process was endothermic in nature.Furthermore,the magnetic composite with a high adsorption capacity of Rhodamine B could be effectively and simply separated using an external magnetic field.And the used particles could be regenerated and recycled easily.The magnetic composite could find potential applications for the removal of dye pollutants.
基金Grant sponsor:National Natural Science Foundation of China,Grant number:30371830Grant sponsor:National Hi-tech research and development program of China,Grant number:2002AA302207+3 种基金 Grant sponsor:Natural Science Foundation of Jiangsu,Grant number:BK2001003Grant sponsor:Hi-tech research pro-gram of Jiangsu,Grant number:BG2001006 Grant sponsor:Key Project of Chinese Traditional Medicine of Jiangsu,Grant number:H027Grant sponsor:Sci-ence Foundation of Southeast University,Grant number:9223001162
文摘Objective：To evaluate the in vitro and in vivo toxicity of self-prepared nanosized Fe2O3, which has the potential implication in tumor hyperthermia. Methods： Fe2O3 nanoparticles were prepared by improving co-precipitation, which characterization was detected by TEM, XRD, CMIAS, EDS. MTT assay was used to evaluate the in vitro cytotoxicity test; hemolytic test was carried out to estimate whether it has blood toxicity; Fe2O3 suspended in sterile 0.9% NaCl was intraperitoneally injected into Kumning mouse to calculate the LD50 ; micronucleus （MN） were reckoned to identify whether it is genotoxic. Results：The nanoparticles are brown spherical particles with diameter ranging from 8 to 15 nm, which have good decentralization and stability. The experiments also showed that the toxicity of the material on mouse fibroblast （L-929） cell lines was 0 - 1 degree ; it has no hemolysis activity; LD50 arrived at 5.45 g/kg^-1 after intraperitoneal injection of 1 ml suspension; micronucleus test showed that it has no genotoxic effects either. Conclusion： The results showed that the Fe2O3 nanoparticles are prepared successfully, the self-prepared nanosized Fe2O3 is a kind of high biocompatibility materials and perhaps it is suitable for further application in tumor hyperthermia.
