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赤铁矿渣—煤泥铁碳基复合材料的制备及除Cr(Ⅵ)性能研究 被引量:1
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作者 杨慧芬 姜美苓 +3 位作者 高春庆 冯筱迪 周轶臣 李萱 《金属矿山》 CAS 北大核心 2023年第1期269-275,共7页
为探究赤铁矿渣和煤泥的高附加值利用途径,通过高温还原法制备铁碳基复合材料并将其用于Cr(Ⅵ)的吸附研究,利用SEM-EDS、XRD及XPS进行吸附机理研究。结果表明,所制材料主要含Fe、C、S 3种元素,其摩尔比为24∶62∶14。Fe、C元素构成铁碳... 为探究赤铁矿渣和煤泥的高附加值利用途径,通过高温还原法制备铁碳基复合材料并将其用于Cr(Ⅵ)的吸附研究,利用SEM-EDS、XRD及XPS进行吸附机理研究。结果表明,所制材料主要含Fe、C、S 3种元素,其摩尔比为24∶62∶14。Fe、C元素构成铁碳基复合材料的基本结构,FeO、FeS和Al_(2)O_(3)·SiO_(2)不均匀地镶嵌在复合材料的结构中。这种材料对水中Cr(Ⅵ)具有较好的去除性能。在Cr(Ⅵ)初始浓度100 mg/L、初始pH=2的溶液中,投加3 g/L铁碳基复合材料,25℃振荡反应60 min,水中Cr(Ⅵ)的去除率可达99.87%,材料的最大吸附量可达86.88 mg/g。水中Cr(Ⅵ)的去除,是因为Cr(Ⅵ)能与铁碳基材料表面的Fe发生还原反应生成Fe^(2+)和Cr(Ⅲ),再进一步与材料表面OH^(-)、S^(2-)结合生成稳定的FeCr_(2)O_(4)和FeCr_(2)S_(4),沉积在铁碳基材料表面。以上研究为赤铁矿渣和煤泥制备铁碳基复合材料及其应用提供了理论和技术指导。 展开更多
关键词 矿渣 煤泥 铁碳基复合材料 Cr(Ⅵ) 吸附机理
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Comparison of wear behaviour of LM13 Al−Si alloy based composites reinforced with synthetic(B_(4)C)and natural(ilmenite)ceramic particles 被引量:5
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作者 Rahul GUPTA Tarun NANDA O.P.PANDEY 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第12期3613-3625,共13页
Dry sliding wear behaviour of stir-cast aluminium matrix composites(AMCs)containing LM13 alloy as matrix and ceramic particles as reinforcement was investigated.Two different ceramic particle reinforcements were used ... Dry sliding wear behaviour of stir-cast aluminium matrix composites(AMCs)containing LM13 alloy as matrix and ceramic particles as reinforcement was investigated.Two different ceramic particle reinforcements were used separately:synthetic ceramic particles(B_(4)C),and natural ceramic particles(ilmenite).Optical micrographs showed uniform dispersion of reinforced particles in the matrix material.Reinforced particles refined the grain size of eutectic silicon and changed its morphology to globular type.B_(4)C reinforced composites(BRCs)showed maximum improvement in hardness of AMCs.Ilmenite reinforced composites(IRCs)showed maximum reduction in coefficient of friction values due to strong matrix−reinforcement interfacial bonding caused by the formation of interfacial compounds.Dry sliding wear behaviour of composites was significantly improved as compared to base alloy.The low density and high hardness of B_(4)C particles resulted in high dislocation density around filler particles in BRCs.On the other hand,the low thermal conductivity of ilmenite particles resulted in early oxidation and formation of a tribo-layer on surface of IRCs.So,both types of reinforcements led to the improvement in wear properties of AMCs,though the mechanisms involved were very different.Thus,the low-cost ilmenite particles can be used as alternative fillers to the high-cost B_(4)C particles for processing of wear resistant composites. 展开更多
关键词 aluminium matrix composites ILMENITE boron carbide PARTICLE-REINFORCEMENT wear test TRIBOLAYER XRD analysis SEM−EDS
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