Dysprosium composite cobalt ferrite ionic magnetic fluids were prepared by precipitation in the presence of Tri-sodium citrate. Influence of dysprosium modification on magnetic property is studied. The result shows th...Dysprosium composite cobalt ferrite ionic magnetic fluids were prepared by precipitation in the presence of Tri-sodium citrate. Influence of dysprosium modification on magnetic property is studied. The result shows that magnetic response toward exterior magnetic field can be improved by adding Dy3+. Studies also show that the increase of reaction temperature may improve the modification effect of dysprosium. By adding dysprosium ions, the average diameter of the magnetic nanoparticles will be decreased evidently. It is clear that the particles appear as balls. Cobalt ferrite with sizes of 12-15 nm, rare earth composite cobalt ferrite with sizes of 6-8 nm.展开更多
Water-based rare-earth ferrite (Re xFe 3- xO 4)magnetic fluids were prepared by chemical co-precipitation method. The result shows that saturation magnetic intensity of ferrite magnetic fluids can be improved by addin...Water-based rare-earth ferrite (Re xFe 3- xO 4)magnetic fluids were prepared by chemical co-precipitation method. The result shows that saturation magnetic intensity of ferrite magnetic fluids can be improved by adding Dy 3+ and the saturation magnetic intensity will reach the highest if n(Fe)∶n(Dy 3+ )=30∶1. The modification and formation mechanism of Re xFe 3- xO 4 particles is discussed in detail. The physicochemical properties are investigated by the Gouy magnetic balance, IR, TEM, XRD, and EDX, etc.展开更多
In order to obtain magnetorheological （MR） elastomers with high magnetorheological effect, a family of anisotropic rubber-based MR elastomers was developed using a new form of chemical modification. Three different ...In order to obtain magnetorheological （MR） elastomers with high magnetorheological effect, a family of anisotropic rubber-based MR elastomers was developed using a new form of chemical modification. Three different kinds of surfactants, i.e. anionic, nonionic and compound surfactants, were employed separately to modify iron particles. The MR effect was evaluated by measuring the dynamic shear modulus of MR elastomer with a magneto-combined dynamic mechanical analyzer. Results show that the relative MR effect can be up to 188% when the iron particles are modified with 15% Span 80. Besides the surface activity of Span 80, however, such high modifying effect is partly due to the plasticizing effect of Span 80. Compared with the single surfactant, the superior surface activity of compound surfactant makes the relative MR effect reach 77% at a low content of 0.4%. Scanning electron microscope observation shows that the modification of compound surfactant results in perfect compatibility between particles and rubber matrix and special self-assembled structure of particles. Such special structure has been proved beneficial to the improvement of the relative MR effect.展开更多
Gelatincarbonyl iron composite particle was prepared by micro emulsion method. The analysis of scanning electron microscope(SEM) shows that the ultrafine particles are spheroids coated by gelatin, and the average size...Gelatincarbonyl iron composite particle was prepared by micro emulsion method. The analysis of scanning electron microscope(SEM) shows that the ultrafine particles are spheroids coated by gelatin, and the average sizes of particles are 310μm. The specific saturation magnetization σ_s is 130.9A·m2/kg, coercivity H_c is 0.823A/m, and residual magnetism r is 4.98Am2/kg for the composite particles. It is shown that the particles possess properties of soft magnetic. The yield stress of magnetorheological fluid(MRF) with composite particle reaches 70kPa at 0.5T magnetic induction. Magnetorheological effects are superior in lower magnetic field intensity and the subsidence stability of the MRF is excellent compared with pure carbonyl iron powder.展开更多
文摘Dysprosium composite cobalt ferrite ionic magnetic fluids were prepared by precipitation in the presence of Tri-sodium citrate. Influence of dysprosium modification on magnetic property is studied. The result shows that magnetic response toward exterior magnetic field can be improved by adding Dy3+. Studies also show that the increase of reaction temperature may improve the modification effect of dysprosium. By adding dysprosium ions, the average diameter of the magnetic nanoparticles will be decreased evidently. It is clear that the particles appear as balls. Cobalt ferrite with sizes of 12-15 nm, rare earth composite cobalt ferrite with sizes of 6-8 nm.
文摘Water-based rare-earth ferrite (Re xFe 3- xO 4)magnetic fluids were prepared by chemical co-precipitation method. The result shows that saturation magnetic intensity of ferrite magnetic fluids can be improved by adding Dy 3+ and the saturation magnetic intensity will reach the highest if n(Fe)∶n(Dy 3+ )=30∶1. The modification and formation mechanism of Re xFe 3- xO 4 particles is discussed in detail. The physicochemical properties are investigated by the Gouy magnetic balance, IR, TEM, XRD, and EDX, etc.
基金ACKNOWLEDGMENTS This work was supported by the Natioal Natural Science Foundation of China （No.10672154） and the Specialized Research Fund for the Doctoral Program of Higher Education （No.20050358010）. The Scholarship BRJH funding of Chinese Academy of Sciences is also appreciated.
文摘In order to obtain magnetorheological （MR） elastomers with high magnetorheological effect, a family of anisotropic rubber-based MR elastomers was developed using a new form of chemical modification. Three different kinds of surfactants, i.e. anionic, nonionic and compound surfactants, were employed separately to modify iron particles. The MR effect was evaluated by measuring the dynamic shear modulus of MR elastomer with a magneto-combined dynamic mechanical analyzer. Results show that the relative MR effect can be up to 188% when the iron particles are modified with 15% Span 80. Besides the surface activity of Span 80, however, such high modifying effect is partly due to the plasticizing effect of Span 80. Compared with the single surfactant, the superior surface activity of compound surfactant makes the relative MR effect reach 77% at a low content of 0.4%. Scanning electron microscope observation shows that the modification of compound surfactant results in perfect compatibility between particles and rubber matrix and special self-assembled structure of particles. Such special structure has been proved beneficial to the improvement of the relative MR effect.
文摘Gelatincarbonyl iron composite particle was prepared by micro emulsion method. The analysis of scanning electron microscope(SEM) shows that the ultrafine particles are spheroids coated by gelatin, and the average sizes of particles are 310μm. The specific saturation magnetization σ_s is 130.9A·m2/kg, coercivity H_c is 0.823A/m, and residual magnetism r is 4.98Am2/kg for the composite particles. It is shown that the particles possess properties of soft magnetic. The yield stress of magnetorheological fluid(MRF) with composite particle reaches 70kPa at 0.5T magnetic induction. Magnetorheological effects are superior in lower magnetic field intensity and the subsidence stability of the MRF is excellent compared with pure carbonyl iron powder.
基金Supported by the National Natural Science Foundation of China (NNSFC, No.20476065)the Scientific Research Foundation for ROCS of State Education Ministry (SRF for ROCS, SEM)+2 种基金the Key Lab. of Multiphase Reaction of the Chinese Academy of Sciences (No.2003-5)the State Key Lab. of Coal Conversion of CAS(No.2006-902)the Key Lab. of Organic Synthesis of Jiangsu Prov., Foundation of Chemical Experiment Center of Soochow Univ. and R&D Foundation of Nanjing Medical Univ. (NY0586).~~
