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活性炭负载铁钴电催化氧化焦化废水生化尾水的研究 被引量:3
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作者 李飞贞 高康乐 +3 位作者 解迪 李雪 王海东 梁文艳 《环境污染与防治》 CAS CSCD 北大核心 2017年第4期356-361,共6页
采用浸渍-焙烧法制备了负载铁钴复合催化元素的活性炭(Fe-Co/GAC)粒子电极。X射线衍射、场发射扫描电子显微镜及能谱仪、N_2吸附脱附曲线等分析表明:负载的催化组分是Fe_3O_4和钴铁氧体(CoFe_2O_4)的混合晶型;Fe和Co元素在颗粒活性炭(G... 采用浸渍-焙烧法制备了负载铁钴复合催化元素的活性炭(Fe-Co/GAC)粒子电极。X射线衍射、场发射扫描电子显微镜及能谱仪、N_2吸附脱附曲线等分析表明:负载的催化组分是Fe_3O_4和钴铁氧体(CoFe_2O_4)的混合晶型;Fe和Co元素在颗粒活性炭(GAC)表面元素的质量分数分别为7.4%和3.2%;GAC负载前后吸附行为没发生明显变化。以Fe-Co/GAC作为粒子电极,使用两级串联电催化反应装置处理焦化废水生化尾水,结果表明,在两级反应装置水力停留时间都为20min、电流都为0.2A时,第一、二级反应装置出水COD分别在75.8~79.1、42.6~44.8mg/L,平均去除率分别达到54.4%和74.2%,处理效果相对于GAC提高了10.5百分点。同时,不同电流组合条件表明,两级反应装置的电流条件存在最佳匹配关系,适当降低第一级反应装置电流至0.2A,并适当增加第二级反应装置电流至0.6A,可获得较佳的COD去除效果,以及较低的能耗。 展开更多
关键词 电催化氧化 铁钴复合 粒子电极 活性炭 焦化废水
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Composite CoFe2O4/Bi3.1La0.9Ti3O12 Structures with Multiferroic Properties
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作者 Amanda Charris-Hemandez Arun Kumar Maharaj Tomar 《Journal of Chemistry and Chemical Engineering》 2014年第8期767-771,共5页
Chemical solution route was used to synthesize Bi3.1La0.9Ti3O12 and CoFe2O4. Alternate CoFe2O4/Bi3.1La0.9Ti3O12 layers were deposited on Pt substrate (Pt/TiO2/SiO2/Si) by spin coating. X-ray diffraction and SEM (sc... Chemical solution route was used to synthesize Bi3.1La0.9Ti3O12 and CoFe2O4. Alternate CoFe2O4/Bi3.1La0.9Ti3O12 layers were deposited on Pt substrate (Pt/TiO2/SiO2/Si) by spin coating. X-ray diffraction and SEM (scanning electron microscopy) studies show composite-like polycrystalline films. Films were studied for leakage current, dielectric response, ferroelectric and ferromagnetic properties. Leakage current was low (〈 10^-8 A) in electric field below 120 kV/cm, and the dielectric response shows relaxation. Dielectric loss (tan 8) reduces 〈 3% at 10^6 Hz. Two and four layer structures showed room temperature FE (ferroelectric) and FM (ferromagnetic) responses with FE Pr (polarization) 〉 25℃/cm2 and ferromagnetic Mr (memory) 〉 52 emu/cm3. Co-existence of FE and FM can be attributed to stress due to different crystal structures of the material involved in composite film structure. 展开更多
关键词 MULTIFERROIC CoFe2O4/Bi3.1La0.9Ti3O12 composite chemical route.
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