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攀枝花钛渣氧化焙烧试验研究 被引量:1
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作者 叶恩东 《中国有色冶金》 CAS 2019年第3期88-94,共7页
采用XRD、扫描电镜等检测方法对攀枝花钛渣进行深度分析,得出钛渣主要由铁黑钛石相和硅酸盐相组成。通过差热热重试验确定了氧化焙烧参数,完成了不同温度焙烧试验研究,并对氧化后钛渣进行了Raman、XRD、SEM分析。研究表明氧化焙烧过程中... 采用XRD、扫描电镜等检测方法对攀枝花钛渣进行深度分析,得出钛渣主要由铁黑钛石相和硅酸盐相组成。通过差热热重试验确定了氧化焙烧参数,完成了不同温度焙烧试验研究,并对氧化后钛渣进行了Raman、XRD、SEM分析。研究表明氧化焙烧过程中,攀枝花钛渣主要含钛物相依次发生低价钛氧化物-锐钛型TiO2-金红石转化,铁黑钛石相转化成金红石和板钛矿相,随着温度升高,氧化速度加快。在强氧化过程中,黑钛石固溶体产生了大量的细小孔洞和微裂纹,在850~1100℃区间内,氧化温度越高,形成的表面微裂纹及内部小孔洞越多,黑钛石固溶体晶格的破坏程度就越大。 展开更多
关键词 攀枝花 氧化 铁黑钛石 金红
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Appropriate titanium slag composition during smelting of vanadium titanomagnetite metallized pellets 被引量:4
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作者 Shuai WANG Yu-feng GUO +5 位作者 Tao JIANG Feng CHEN Fu-qiang ZHENG Min-jun TANG Ling-zhi YANG Guan-zhou QIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第12期2528-2537,共10页
The suitable titanium slag composition with high titanium content for electric furnace smelting of vanadium titanomagnetite was investigated through thermodynamics and related phase diagram analysis.According to the t... The suitable titanium slag composition with high titanium content for electric furnace smelting of vanadium titanomagnetite was investigated through thermodynamics and related phase diagram analysis.According to the thermodynamic results,low-melting-point regions and MgTi2O5primary phase area in the phase diagrams,the suggested titanium slag composition for the present vanadium titanomagnetite metallized pellets should consist of50%TiO2,8%-12%MgO and13%Al2O3(mass fraction)with a binary basicity of0.8-1.2.Finally,the verified smelting experiments were conducted and successful separation of the molten iron from the titanium slag is obtained.The obtained vanadium-containing molten iron contains0.681%V and0.267%Ti,and the obtained titanium slag contains52.21%TiO2(mass fraction),in which MgTi2O5is the primary phase.The titanium resource in the final titanium slag production could be used to produce TiO2pigment by acid leaching methods. 展开更多
关键词 vanadium titanomagnetite electric furnace BASICITY MgO MgTi2O5 titanium slag composition
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