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SHS—离心法制备铁-铬-镍合金的耐蚀性能 被引量:7
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作者 段辉平 魏延平 +1 位作者 殷声 赖和怡 《粉末冶金技术》 CAS CSCD 北大核心 1998年第3期178-182,共5页
利用SHS—离心法制备铁-铬-镍合金内衬复合钢管,系统研究内衬层的耐蚀性能。结果表明,含碳量较低的SHS耐蚀合金在硫酸中的耐蚀性优于lCr18Ni9不锈钢,具有优异的抗点蚀和抗均匀腐蚀性能,但抗晶间腐蚀性能较差,也不... 利用SHS—离心法制备铁-铬-镍合金内衬复合钢管,系统研究内衬层的耐蚀性能。结果表明,含碳量较低的SHS耐蚀合金在硫酸中的耐蚀性优于lCr18Ni9不锈钢,具有优异的抗点蚀和抗均匀腐蚀性能,但抗晶间腐蚀性能较差,也不耐盐酸腐蚀。 展开更多
关键词 离心法 铁-铬-镍合金 耐蚀性能 燃烧合成
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电沉积制备铁-镍-铬纳米晶合金箔工艺的正交设计 被引量:8
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作者 邓姝皓 龚竹青 +2 位作者 易丹青 蔡桂华 苏玉长 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2005年第6期938-943,共6页
运用正交设计研究影响电沉积铁-镍-铬合金箔质量的主要工艺因素,分析电流密度、溶液温度和溶液的pH值等各因素对合金成分和电流效率的影响,通过综合评分的方法确定最佳工艺条件,并对最佳工艺条件下获得的合金箔材的微观形貌、结构、物... 运用正交设计研究影响电沉积铁-镍-铬合金箔质量的主要工艺因素,分析电流密度、溶液温度和溶液的pH值等各因素对合金成分和电流效率的影响,通过综合评分的方法确定最佳工艺条件,并对最佳工艺条件下获得的合金箔材的微观形貌、结构、物理和化学性能进行研究。研究结果表明制备的合金箔材成分为60%~65%Fe,34%~36%Ni,1%~2%Cr,厚度均匀,表面光滑,结晶细致。扫描电镜观察和X衍射结果表明其晶粒尺寸在纳米范围内,合金箔的抗拉强度和延展率分别为658MPa和6%以上,电阻率超过90μΩ.cm,磁感应强度为1.25T,最大导磁率为1.096×10-2H.m-1,矫顽力为357.53A.m-1;箔材具有优异的耐腐蚀性能。 展开更多
关键词 电沉积 纳米晶 --合金 正交设计
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电沉积纳米晶镍-铁-铬合金 被引量:15
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作者 邓姝皓 龚竹青 陈文汩 《电镀与涂饰》 CAS CSCD 2002年第4期4-8,共5页
采用直流和脉冲电沉积方式从三价铬的氯化物镀液中沉积出镍 -铁 -铬纳米合金镀层。利用扫描电镜分析镀层形貌及晶粒尺寸 ,研究了沉积速率、电流效率、三价铬浓度及pH值随沉积时间的变化关系。结果表明 ,脉冲电沉积所得镀层的结构和性能... 采用直流和脉冲电沉积方式从三价铬的氯化物镀液中沉积出镍 -铁 -铬纳米合金镀层。利用扫描电镜分析镀层形貌及晶粒尺寸 ,研究了沉积速率、电流效率、三价铬浓度及pH值随沉积时间的变化关系。结果表明 ,脉冲电沉积所得镀层的结构和性能均优于直流电沉积 ,这是由于脉冲电沉积存在断电时间 。 展开更多
关键词 电沉积 纳米晶 --合金 直流 脉冲电沉积方式
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脉冲电沉积纳米晶镍铁铬合金(Ⅰ)——电沉积工艺 被引量:11
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作者 龚竹青 邓姝皓 陈文汨 《中国有色金属学报》 EI CAS CSCD 北大核心 2003年第2期511-516,共6页
在恒电位脉冲的条件下,pH控制在0.8~1,阴极电流密度为12~20A·dm-2,周期为25ms,占空比为0.3,镀液温度维持在20~30℃,采用循环镀液的方法以避免二价铬离子的干扰,从含三价铬离子的镀液中电沉积出镍 铁 铬合金。X射线衍射结果表明... 在恒电位脉冲的条件下,pH控制在0.8~1,阴极电流密度为12~20A·dm-2,周期为25ms,占空比为0.3,镀液温度维持在20~30℃,采用循环镀液的方法以避免二价铬离子的干扰,从含三价铬离子的镀液中电沉积出镍 铁 铬合金。X射线衍射结果表明沉积的镀层为晶体结构,存在较强的(111)织构。能谱和扫描电镜的结果显示电沉积出的镍 铁 铬合金镀层中含有少量的硫,其晶粒尺寸小于100nm。通过这种方法可以获得厚镀层。电化学分析表明随着电流密度的增大,镀层的耐蚀性相应增强。 展开更多
关键词 --合金 电沉积 脉冲 纳米晶 电流密度
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分光光度法测定Fe-Ni-Cr三元合金镀层中的铬 被引量:1
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作者 王蓉 邹时英 《福建分析测试》 CAS 2009年第4期67-69,共3页
本文研究了二苯羰酰二肼(DPC)光度法测定铁-镍-铬三元合金镀层中铬含量的方法。在对显色条件、共存离子干扰等研究基础上,进行了相关指标的测定。该方法灵敏度为4.02×104L·mol-1.cm-1,铬的质量浓度在0.0~80μg/50mL范围内服... 本文研究了二苯羰酰二肼(DPC)光度法测定铁-镍-铬三元合金镀层中铬含量的方法。在对显色条件、共存离子干扰等研究基础上,进行了相关指标的测定。该方法灵敏度为4.02×104L·mol-1.cm-1,铬的质量浓度在0.0~80μg/50mL范围内服从比尔定律。经用于样品分析,结果满意。 展开更多
关键词 分光光度法 二苯羰酰二肼 --三元合金镀层
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Characteristics of Inconel Powders for Powder-Bed Additive Manufacturing 被引量:14
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作者 Quy Bau Nguyen Mui Ling Sharon Nai +3 位作者 Zhiguang Zhu Chen-Nan Sun Jun wei Wei Zhou 《Engineering》 SCIE EI 2017年第5期695-700,共6页
In this study, the flow characteristics and behaviors of virgin and recycled Inconel powder for powder-bed additive manufacturing (AM) were studied using different powder characterization techniques. The results rev... In this study, the flow characteristics and behaviors of virgin and recycled Inconel powder for powder-bed additive manufacturing (AM) were studied using different powder characterization techniques. The results revealed that the particle size distribution (PSD) for the selective laser melting (SLM) process is typically in the range from 15 μm to 63 μm. The flow rate of virgin Inconel powder is around 28 s·(50 g)^-1. In addition, the packing density was found to be 60%. The rheological test results indicate that the virgin powder has reasonably good flowability compared with the recycled powder. The inter-relation between the powder characteristics is discussed herein. A propeller was successfully printed using the powder. The results suggest that Inconel powder is suitable for AM and can be a good reference for researchers who attempt to pro- duce AM powders. 展开更多
关键词 Additive manufacturing Powder characteristics Gas atomization MICROSTRUCTURE INCONEL
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Effect of nickel oxide additive on smelting mechanism of chromium-bearing vanadium titanomagnetite pellets 被引量:1
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作者 Gong-jin CHENG Wei-dong TANG Xiang-xin XUE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第8期2501-2510,共10页
The effect of nickel oxide additive on the smelting behaviors of chromium-bearing vanadium titanomagnetite pellets(CVTP)was investigated while analyzing the transfer behavior of nickel in iron and slag.The results sho... The effect of nickel oxide additive on the smelting behaviors of chromium-bearing vanadium titanomagnetite pellets(CVTP)was investigated while analyzing the transfer behavior of nickel in iron and slag.The results show that when NiO added to CVTP increases from 0 to 6 wt.%,softening start temperature increases from 1148 to 1212℃,and the softening end temperature increases from 1280 to 1334℃;the melting start temperature increases from 1318 to 1377℃,and the dripping temperature decreases from 1558 to 1521℃.The pig iron comprises a compound of Fe-Ni-C.The slag structure depolymerizes with increasing nickel addition.The softening-melting behaviors of CVTP,the reduction of nickel into pig iron,and the depolymerization of slag structure indicate the feasibility of producing nickel-iron alloy through the blast furnace process. 展开更多
关键词 nickel-iron alloy chromium-bearing vanadium titanomagnetite pellets smelting mechanism slag structure
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耐应力腐蚀的铁-镍-铬合金
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《不锈》 2010年第1期50-50,共1页
位于美国西弗吉尼亚Hungington的特殊金属公司(Special Metal Corp.)开发出了一种镍基沉淀硬化合金,该合金称之为Incoloy 945,合金的最低屈服强度为860MPa(125ksi),并具有良好的冲击韧性。该合金是一种时效硬化镍-铁-铬合金,... 位于美国西弗吉尼亚Hungington的特殊金属公司(Special Metal Corp.)开发出了一种镍基沉淀硬化合金,该合金称之为Incoloy 945,合金的最低屈服强度为860MPa(125ksi),并具有良好的冲击韧性。该合金是一种时效硬化镍-铁-铬合金,在该合金中添加了钼,铜,铌,钛和铝。 展开更多
关键词 --合金 -合金 应力腐蚀 METAL 弗吉尼亚 沉淀硬化 屈服强度 冲击韧性
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Fretting wear and friction oxidation behavior of 0Cr20Ni32AlTi alloy at high temperature 被引量:6
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作者 张晓宇 任平弟 +2 位作者 钟发春 朱旻昊 周仲荣 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第4期825-830,共6页
The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and ... The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and X-ray photoelectron spectroscopy.The results show that the friction logs are mixed fretting regime and gross slip regime with the magnitudes of displacement of 10 and 20 μm,respectively.Severe wear and friction oxidation occur on the material surface.A large number of granular debris produced in the fretting process can be easily congregated and adhered at the contact zone after repeated crushes.The resultant of friction oxidation is mainly composed of Fe3O4,Fe2O3,Cr2O3 and NiO.Temperature and friction are the major factors affecting the oxidation reaction rate.The fretting friction effect can enhance the oxidation reaction activity of surface atoms of 0Cr20Ni32AlTi alloy and reduce the oxidation activation energy.As result,the oxidation reaction rate is accelerated. 展开更多
关键词 high temperature nickel chrome-iron alloy fretting wear friction oxidation activation energy
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Effect of standard heat treatment on microstructure and properties of borided Inconel 718 被引量:3
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作者 邓德伟 王春光 +1 位作者 刘倩倩 牛婷婷 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第2期437-443,共7页
Boronizing was applied to Inconel 718. In order to obtain the optimal combination of strength and ductility, the borided Inconel 718 was subjected to standard heat treatment. This consists of solution treatment and th... Boronizing was applied to Inconel 718. In order to obtain the optimal combination of strength and ductility, the borided Inconel 718 was subjected to standard heat treatment. This consists of solution treatment and then a two-step aging treatment. The borided layer is composed of the compound layer and the boron diffusion zone. Because of the superior hardness of borides, the borided Inconel 718 exhibits a significant reduction in its wear rate and relatively low coefficient of friction (COF) compared with the unborided Inconel 718. The standard heat treatment efficiently promotes the diffusion of boron into the interior of the material and the generation of new borides (Fe2B, CrB). The borided layer with standard heat treatment shows much better wear resistance due to the thicker borided layer (313.76 μm). 展开更多
关键词 BORONIZING Inconel 718 standard heat treatment wear resistance corrosion resistance
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氯化铬浓度对Ni–Fe–Cr–P合金电镀层性能的影响
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作者 许乔瑜 朱勇毅 《电镀与涂饰》 CAS CSCD 北大核心 2013年第9期14-17,共4页
在由CrCl3·6H2O 150 g/L、FeSO4·7H2O 5 g/L、NiSO4·6H2O20 g/L、NaBr 10 g/L、NH4Cl 50 g/L、H3BO330 g/L、HCOOH35 g/L、DMF 30 mL/L、C6H5Na3O780 g/L、NaH2PO2·H2O 10 g/L、C7H5O3NS 0.5 g/L和CH3(CH2)10CH2OSO... 在由CrCl3·6H2O 150 g/L、FeSO4·7H2O 5 g/L、NiSO4·6H2O20 g/L、NaBr 10 g/L、NH4Cl 50 g/L、H3BO330 g/L、HCOOH35 g/L、DMF 30 mL/L、C6H5Na3O780 g/L、NaH2PO2·H2O 10 g/L、C7H5O3NS 0.5 g/L和CH3(CH2)10CH2OSO3Na 0.06 g/L组成的Ni–Fe–Cr–P合金基础电镀液的基础上,采用扫描电镜、能谱和X射线衍射研究了镀液中CrCl3质量浓度对镀层表面微观形貌、成分和结构的影响,采用贴滤纸法、电化学极化和电化学阻抗谱研究了不同CrCl3质量浓度时所得镀层的耐蚀性。结果表明,镀液中CrCl3浓度过高或过低都会导致合金镀层中Cr含量的降低,而随着镀层中Cr含量降低,镀层中球状颗粒变粗,致密度下降并出现微裂纹。当镀液中CrCl3质量浓度为150 g/L时,获得的镀层光滑致密,为非晶态结构,其孔隙率最小,电化学阻抗和极化电阻最大,腐蚀电流密度最小,耐蚀性能最好。 展开更多
关键词 ---合金 电镀 氯化 化学成分 孔隙率 耐蚀性 电化学
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Inconel 617 and Stellite 6 alloys for tooling in thixoforming of steels 被引量:18
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作者 Y.BI ROL 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第9期1656-1662,共7页
Thermal fatigue and high temperature wear are the two principle failure mechanisms for thixoforming dies. Samples of Inconel 617 and Stellite 6 alloys were submitted to thermal cycling under conditions which approxima... Thermal fatigue and high temperature wear are the two principle failure mechanisms for thixoforming dies. Samples of Inconel 617 and Stellite 6 alloys were submitted to thermal cycling under conditions which approximate thixoforming of steels and to sliding wear tests at 750 ℃. The experimental results thus obtained were compared with those of the X32CrMoV33 hot work tool steel. The Inconel 617 and Stellite 6 samples are much more resistant to oxidation and to softening than the hot work tool steel, providing a superior resistance to thermal fatigue cracking. The wear resistance of the Inconel 617 and Stellite 6 alloys at 750 ℃ is also markedly superior. The adhesive oxides growing slowly on Inconel 617 and Stellite 6 alloys sustain the wear action without spalling and are claimed to be responsible for the superior wear resistance of these alloys at 750 ℃. 展开更多
关键词 steel THIXOFORMING TOOLING thermal fatigue WEAR
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