Ferroelectric materials were widely applied for actuators and sensors. Barium zirconate titanate Ba(Zr0.25Ti0.75)O3 thin film was grown on Pt/Ti/SiO2/Si(100) substrates by pulsed laser deposition. Structure and surfac...Ferroelectric materials were widely applied for actuators and sensors. Barium zirconate titanate Ba(Zr0.25Ti0.75)O3 thin film was grown on Pt/Ti/SiO2/Si(100) substrates by pulsed laser deposition. Structure and surface morphology of the thin film were studied by X-ray diffractometry(XRD) and scan electronic microscopy(SEM). The composition and chemical state near the film surface were obtained by X-ray photoelectron spectroscopy(XPS). On the sample surface,O 1s spectra can be assigned to those from the lattice and surface adsorbed oxygen ions,while C1s only result from surface contamination. The result shows that only one chemical state is found for each spectrum of Ba 3d,Zr 3d and Ti 2p photoelectron in the BZT thin film.展开更多
[SiO2/FePt]5/Ag thin films were deposited by RF magnetron sputtering on the glass substrates and post annealing at 550 ℃ for 30 min in vacuum. Vibrating sample magnetometer and X-ray diffraction analyser were applied...[SiO2/FePt]5/Ag thin films were deposited by RF magnetron sputtering on the glass substrates and post annealing at 550 ℃ for 30 min in vacuum. Vibrating sample magnetometer and X-ray diffraction analyser were applied to study the magnetic properties and microstructures of the films. The results show that without Ag underlayer [SiO2/FePt]5 films deposited onto the glass are FCC disordered; with the addition of Ag underlayer [SiO]FePt]5/Ag films are changed into L10 and （111） mixed texture. The variation of the SiO2 nonmagnetic layer thickness in [SiO2/FePt]5/Ag films indicates that SiO2-doping plays an important role in improving the order parameter and the perpendicular magnetic anisotropy, and reducing the grain size and intergrain interactions. By controlling SiO2 thickness the highly perpendicular magnetic anisotropy can be obtained in the [SiO2 （0.6 nm）/FePt （3 nm）]5/Ag （50 nm） films and highly （001）-oriented films can be obtained in the [SiO2 （2 nm）/FePt （3 nm）]5/Ag （50 nm） films.展开更多
Although perovskite solar cells(PSCs)have achieved encouraging efficiency,the photon loss at the substrate due to light reflection has not been well addressed.Light management is promising to reduce reflection loss an...Although perovskite solar cells(PSCs)have achieved encouraging efficiency,the photon loss at the substrate due to light reflection has not been well addressed.Light management is promising to reduce reflection loss and realize higher power conversion efficiency(PCE)of PSCs.Here,a bilayer antireflective coating(ARC)has been designed and coated onto the backside of the glass substrate of(FAPbI_(3))_(x)(MAPbBr_(3))_(1-x)PSCs to enhance photon harvesting and consequently the device efficiency.The bottom layer of the bilayer ARC is made from a silica polymer and the top layer is made from the mixture of hexamethyldisiloxane-modified mesoporous silica nanoparticles and a fluorinated silica polymer.By adjusting the refractive index and the film thickness of each layer according to a two-layer model,enhanced glass transmittance in a broadband wavelength range can be reached,with the maximum transmittance increasing from ca.90%to over 95%.With the bilayer ARC,the maximum short-circuit current density and PCE of(FAPbI_(3))_(x)(MAPbBr_(3))_(1-x)PSCs can be increased from 25.5 m A cm^(-2)and 22.7%to 26.5 mA cm^(-2)and 23.9%with negligible changes in fill factor and opencircuit voltage.This work presents a simple yet effective strategy to enhance the efficiency of solar cells employing bilayer antirefective coatings,which can be applied to other types of solar cells.展开更多
基金Project(05001825) supported by Guangdong Provincial Natural Science Foundation of Chinaproject(KF0707) supported by the Opening Project Program of Key Laboratory of Low Dimensional Materials and Application Technology (Xiangtan University), Ministry ofEducation, China
文摘Ferroelectric materials were widely applied for actuators and sensors. Barium zirconate titanate Ba(Zr0.25Ti0.75)O3 thin film was grown on Pt/Ti/SiO2/Si(100) substrates by pulsed laser deposition. Structure and surface morphology of the thin film were studied by X-ray diffractometry(XRD) and scan electronic microscopy(SEM). The composition and chemical state near the film surface were obtained by X-ray photoelectron spectroscopy(XPS). On the sample surface,O 1s spectra can be assigned to those from the lattice and surface adsorbed oxygen ions,while C1s only result from surface contamination. The result shows that only one chemical state is found for each spectrum of Ba 3d,Zr 3d and Ti 2p photoelectron in the BZT thin film.
基金Project(10574085) supported by the National Natural Science Foundation of ChinaProject(207020) supported by the Science Technology Key Project of the Ministry of Education, China
文摘[SiO2/FePt]5/Ag thin films were deposited by RF magnetron sputtering on the glass substrates and post annealing at 550 ℃ for 30 min in vacuum. Vibrating sample magnetometer and X-ray diffraction analyser were applied to study the magnetic properties and microstructures of the films. The results show that without Ag underlayer [SiO2/FePt]5 films deposited onto the glass are FCC disordered; with the addition of Ag underlayer [SiO]FePt]5/Ag films are changed into L10 and （111） mixed texture. The variation of the SiO2 nonmagnetic layer thickness in [SiO2/FePt]5/Ag films indicates that SiO2-doping plays an important role in improving the order parameter and the perpendicular magnetic anisotropy, and reducing the grain size and intergrain interactions. By controlling SiO2 thickness the highly perpendicular magnetic anisotropy can be obtained in the [SiO2 （0.6 nm）/FePt （3 nm）]5/Ag （50 nm） films and highly （001）-oriented films can be obtained in the [SiO2 （2 nm）/FePt （3 nm）]5/Ag （50 nm） films.
基金the Natural Science Foundation of Hubei Province(2019CFB575)the National Natural Science Foundation of China(51861145101)。
文摘Although perovskite solar cells(PSCs)have achieved encouraging efficiency,the photon loss at the substrate due to light reflection has not been well addressed.Light management is promising to reduce reflection loss and realize higher power conversion efficiency(PCE)of PSCs.Here,a bilayer antireflective coating(ARC)has been designed and coated onto the backside of the glass substrate of(FAPbI_(3))_(x)(MAPbBr_(3))_(1-x)PSCs to enhance photon harvesting and consequently the device efficiency.The bottom layer of the bilayer ARC is made from a silica polymer and the top layer is made from the mixture of hexamethyldisiloxane-modified mesoporous silica nanoparticles and a fluorinated silica polymer.By adjusting the refractive index and the film thickness of each layer according to a two-layer model,enhanced glass transmittance in a broadband wavelength range can be reached,with the maximum transmittance increasing from ca.90%to over 95%.With the bilayer ARC,the maximum short-circuit current density and PCE of(FAPbI_(3))_(x)(MAPbBr_(3))_(1-x)PSCs can be increased from 25.5 m A cm^(-2)and 22.7%to 26.5 mA cm^(-2)and 23.9%with negligible changes in fill factor and opencircuit voltage.This work presents a simple yet effective strategy to enhance the efficiency of solar cells employing bilayer antirefective coatings,which can be applied to other types of solar cells.
