The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to...The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3 064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.033 2, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.展开更多
The novel bismuth?complex with dithiotetrahydropyrrolocarbamate, [Bi(S2CNC4H8 )3]2 has been synthesized. The crystal structure has been determined by X-ray s ingle crystal diffraction. The crystal belongs to monoclini...The novel bismuth?complex with dithiotetrahydropyrrolocarbamate, [Bi(S2CNC4H8 )3]2 has been synthesized. The crystal structure has been determined by X-ray s ingle crystal diffraction. The crystal belongs to monoclinic with space group C2 /c, a=1.6356(9) nm, b=1.1875(6) nm, c=2.3954(13) nm, β=100.741(8)°, Z=4, V=4.5 71(4) nm3, Dx=1.882g·cm-3,μ=8.267mm-1, F(000)=2512, R=0.0404, wR=0.0622. In this binuclear complex, each Bi?is seven coordinate with a distorted pentagonal bipyramidal geometry. CCDC: 179924.展开更多
文摘The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3 064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.033 2, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.
文摘The novel bismuth?complex with dithiotetrahydropyrrolocarbamate, [Bi(S2CNC4H8 )3]2 has been synthesized. The crystal structure has been determined by X-ray s ingle crystal diffraction. The crystal belongs to monoclinic with space group C2 /c, a=1.6356(9) nm, b=1.1875(6) nm, c=2.3954(13) nm, β=100.741(8)°, Z=4, V=4.5 71(4) nm3, Dx=1.882g·cm-3,μ=8.267mm-1, F(000)=2512, R=0.0404, wR=0.0622. In this binuclear complex, each Bi?is seven coordinate with a distorted pentagonal bipyramidal geometry. CCDC: 179924.
