NbC-Sn composite powder was successfully prepared from SnO2,Nb2O5and carbon by electrochemical reduction andcarbonization in CaCl2-NaCl molten salt at900°C.The reaction pathway was investigated by terminating ele...NbC-Sn composite powder was successfully prepared from SnO2,Nb2O5and carbon by electrochemical reduction andcarbonization in CaCl2-NaCl molten salt at900°C.The reaction pathway was investigated by terminating electrochemicalexperiments for various durations.The influence of carbon on the final products was considered.NbC particles were obtained byleaching the composite with acid.The results showed that the aggregated NbC-Sn composite powdev contained NbC particles about50-100nm and Sn particles about200nm.SnO2was reduced to Sn in the sintering process.Nb2O5was electrochemically reduced toNb in molten salt,experiencing some intermediate products of calcium niobates and niobium suboxides.Nb metal obtained wasconverted to NbC with assistance of carbon.The reduction of Nb oxides may be incomplete and Nb3Sn would be formed if carbon isinsufficient in the cathodic pellet.NbC with good dispersity is produced by leaching NbC-Sn with HCl.展开更多
Development of high-voltage electrolytes with non-flammability is significantly important for future energy storage devices.Aqueous electrolytes are inherently non-flammable,easy to handle,and their electrochemical st...Development of high-voltage electrolytes with non-flammability is significantly important for future energy storage devices.Aqueous electrolytes are inherently non-flammable,easy to handle,and their electrochemical stability windows(ESWs)can be considerably expanded by increasing electrolyte concentrations.However,further breakthroughs of their ESWs encounter bottlenecks because of the limited salt solubility,leading to that most of the high-energy anode materials can hardly function reversibly in aqueous electrolytes.Here,by introducing a non-flammable ionic liquid as co-solvent in a lithium salt/water system,we develop a"water in salt/ionic liquid"(WiSIL)electrolyte with extremely low water content.In such WiSIL electrolyte,commercial niobium pentoxide(Nb2O5)material can operate at a low potential(-1.6 V versus Ag/AgCl)and contribute its full capacity.Consequently,the resultant Nb2O5-based aqueous lithium-ion capacitor is able to operate at a high voltage of 2.8 V along with long cycling stability over 3000 cycles,and displays comparable energy and power performance(51.9 Wh kg^-1 at 0.37 kW kg^-1 and 16.4 Wh kg^-1 at 4.9 kW kg^-1)to those using non-aqueous electrolytes but with improved safety performance and manufacturing efficiency.展开更多
基金the National Natural Science Foundation of China (Grants No.21303074)Natural Science Foundation of Jiangsu Province (Grant No.BK20141304)Special Financial Grant from the China Postdoctoral (Grant No.2015T80500)~~
基金Projects(51404057,50874026)supported by the National Natural Science Foundation of ChinaProject(N150204014)supported by Fundamental Research Funds for the Central Universities,China
文摘NbC-Sn composite powder was successfully prepared from SnO2,Nb2O5and carbon by electrochemical reduction andcarbonization in CaCl2-NaCl molten salt at900°C.The reaction pathway was investigated by terminating electrochemicalexperiments for various durations.The influence of carbon on the final products was considered.NbC particles were obtained byleaching the composite with acid.The results showed that the aggregated NbC-Sn composite powdev contained NbC particles about50-100nm and Sn particles about200nm.SnO2was reduced to Sn in the sintering process.Nb2O5was electrochemically reduced toNb in molten salt,experiencing some intermediate products of calcium niobates and niobium suboxides.Nb metal obtained wasconverted to NbC with assistance of carbon.The reduction of Nb oxides may be incomplete and Nb3Sn would be formed if carbon isinsufficient in the cathodic pellet.NbC with good dispersity is produced by leaching NbC-Sn with HCl.
基金supported by the National Natural Science Foundations of China(21573265 and 21673263)the Zhaoqing Municipal Science and Technology Bureau(2019K038)+2 种基金the Key Cultivation Projects of the Institute in 13th Five-Yearthe Instruments Function Development&Technology Innovation Project of Chinese Academy of Sciences(2020g105)the Western Young Scholars Foundations of Chinese Academy of Sciences。
文摘Development of high-voltage electrolytes with non-flammability is significantly important for future energy storage devices.Aqueous electrolytes are inherently non-flammable,easy to handle,and their electrochemical stability windows(ESWs)can be considerably expanded by increasing electrolyte concentrations.However,further breakthroughs of their ESWs encounter bottlenecks because of the limited salt solubility,leading to that most of the high-energy anode materials can hardly function reversibly in aqueous electrolytes.Here,by introducing a non-flammable ionic liquid as co-solvent in a lithium salt/water system,we develop a"water in salt/ionic liquid"(WiSIL)electrolyte with extremely low water content.In such WiSIL electrolyte,commercial niobium pentoxide(Nb2O5)material can operate at a low potential(-1.6 V versus Ag/AgCl)and contribute its full capacity.Consequently,the resultant Nb2O5-based aqueous lithium-ion capacitor is able to operate at a high voltage of 2.8 V along with long cycling stability over 3000 cycles,and displays comparable energy and power performance(51.9 Wh kg^-1 at 0.37 kW kg^-1 and 16.4 Wh kg^-1 at 4.9 kW kg^-1)to those using non-aqueous electrolytes but with improved safety performance and manufacturing efficiency.
