Composite ceramics of 0.7BaO·0.3SrO·(1-y)TiO2·yNb2O5 (BSTN) with coexistence of barium strontium titanate, Ba1-xSrxTiO3 (BST), and strontium barium niobate, SrxBa1-xNb2O6 (SBN) phases were successfully ...Composite ceramics of 0.7BaO·0.3SrO·(1-y)TiO2·yNb2O5 (BSTN) with coexistence of barium strontium titanate, Ba1-xSrxTiO3 (BST), and strontium barium niobate, SrxBa1-xNb2O6 (SBN) phases were successfully prepared in situ by controlling excess components according to a specially designed formula of 0.7BaO·0.3SrO·(1-y)TiO2·yNb2O5 and by using a traditional ceramic process. X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersion spectrometer (EDS) were used to characterize the phase composition, morphology and the micro-area chemical composition of the composite ceramics. The results showed that the SBN tungsten bronze phase appeared and coexisted stably with the BST perovskite phase when the excess content of Nb2O5 was >6mol%, whereas the BST perovskite phase formed and coexisted stably with the SBN tungsten bronze phase when the excess content of TiO2 was >5.3mol%. In the case of the two phases being equivalent to each other in BSTN composite ceramics, Nb2O5 was hard to be resolved into the perovskite phase, however, a few of TiO2 was easy to be resolved in the tungsten bronze phase. The microstructure of the composite ceramics were consisted of two kinds of grains. The smaller polygonal grains were belonged to the BST phase, and the larger ones to the SBN phase. The coexistence of the two phases inhibited the growth of the BST crystal. The density of microstructure of the composite ceramic was higher than that of both the pure BST and SBN calcined at the same temperature for the same time.展开更多
利用镀膜技术和硅平面工艺在经过干氧氧化的硅衬底上制备一层钛铌酸锶(Sr NbxTi1-xO3)薄膜,然后制备成平面型薄膜光敏传感器。对钛铌酸锶薄膜的吸收光谱进行测定,得到其禁带宽度为2. 70 e V,对可见光有良好的敏感性。样品在稳定光照下,...利用镀膜技术和硅平面工艺在经过干氧氧化的硅衬底上制备一层钛铌酸锶(Sr NbxTi1-xO3)薄膜,然后制备成平面型薄膜光敏传感器。对钛铌酸锶薄膜的吸收光谱进行测定,得到其禁带宽度为2. 70 e V,对可见光有良好的敏感性。样品在稳定光照下,光电流随照度的增大而增大;温度对光敏特性影响很大,本传感器适用于稳定光照和室温下使用。展开更多
文摘Composite ceramics of 0.7BaO·0.3SrO·(1-y)TiO2·yNb2O5 (BSTN) with coexistence of barium strontium titanate, Ba1-xSrxTiO3 (BST), and strontium barium niobate, SrxBa1-xNb2O6 (SBN) phases were successfully prepared in situ by controlling excess components according to a specially designed formula of 0.7BaO·0.3SrO·(1-y)TiO2·yNb2O5 and by using a traditional ceramic process. X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersion spectrometer (EDS) were used to characterize the phase composition, morphology and the micro-area chemical composition of the composite ceramics. The results showed that the SBN tungsten bronze phase appeared and coexisted stably with the BST perovskite phase when the excess content of Nb2O5 was >6mol%, whereas the BST perovskite phase formed and coexisted stably with the SBN tungsten bronze phase when the excess content of TiO2 was >5.3mol%. In the case of the two phases being equivalent to each other in BSTN composite ceramics, Nb2O5 was hard to be resolved into the perovskite phase, however, a few of TiO2 was easy to be resolved in the tungsten bronze phase. The microstructure of the composite ceramics were consisted of two kinds of grains. The smaller polygonal grains were belonged to the BST phase, and the larger ones to the SBN phase. The coexistence of the two phases inhibited the growth of the BST crystal. The density of microstructure of the composite ceramic was higher than that of both the pure BST and SBN calcined at the same temperature for the same time.
文摘利用镀膜技术和硅平面工艺在经过干氧氧化的硅衬底上制备一层钛铌酸锶(Sr NbxTi1-xO3)薄膜,然后制备成平面型薄膜光敏传感器。对钛铌酸锶薄膜的吸收光谱进行测定,得到其禁带宽度为2. 70 e V,对可见光有良好的敏感性。样品在稳定光照下,光电流随照度的增大而增大;温度对光敏特性影响很大,本传感器适用于稳定光照和室温下使用。
基金Project (2008RFQXG070) supported by the Science and Technology Innovation Special Foundation of Harbin City,ChinaProject (F200927) supported by Natural Science Foundation of Heilongjiang Province,China
