Copper(Ⅱ) complexes Cu(C6H6N2)2(ClO4)2 (1) and Cu2(OAc)4(C5H5ClN2)2 (2) with amino pyridine derivatives ligands have been synthesized and characterized by elemental analysis and IR spectrum. Their crystal structures ...Copper(Ⅱ) complexes Cu(C6H6N2)2(ClO4)2 (1) and Cu2(OAc)4(C5H5ClN2)2 (2) with amino pyridine derivatives ligands have been synthesized and characterized by elemental analysis and IR spectrum. Their crystal structures are determined by X ray diffraction method. Compound 1, C12H16Cl2CuN4O8, Mr=478.73, triclinic, space <IMG SRC="IMAGE/04170000.JPG" HEIGHT=14 WIDTH=16>group , a=0.7641(1)nm, b=0.7987(1)nm, c=0.7990(1)nm, α =106.78(1)° ,β =95.71(1)° , γ =108.85(1)° , V=0.4317(1)nm3, Z=1, Dc=1.841g· cm- 3, μ =1.627mm- 1, F(000) =243,R1=0.0264, ω R2=0.0641 (I >2σ (I)). In 1, the center metal ion Cu? possesses distorted octahedral geometry. Compound 2, C18H22C12Cu2N4O8, Mr=620.38,monoclinic, space group C2/c, a=1.9888(3), b=0.9158(1), c=1.4241(2)nm, β =115.89(1)° , V=2.3336(5)nm3, Z=4, Dc=1.766mg· cm- 3, μ =2.104mm- 1, F(000)=1256, R1=0.0263, wR2=0.0676 (I >2σ (I)). Compound 2 is dinuclear structure, in which each Cu? adopts five coordinated distorted square pyramid geometry. CCDC: 193109; 193110.展开更多
On-line Cu （II） ion concentration detection in bioleaching system was achieved by anodic stripping differential pulse voltammetry （ASDPV）. Good linearity between Cu （II） concentration and oxidation peak current ...On-line Cu （II） ion concentration detection in bioleaching system was achieved by anodic stripping differential pulse voltammetry （ASDPV）. Good linearity between Cu （II） concentration and oxidation peak current was obtained when Cu （II） existed in 0K media in the concentration range of 1μmol/L （64μg/L） to 1 mmol/L （64 mg/L）. Moreover, when 0.2 mol/L KCl was added into this media, the linear detection range could be extended from 1 mmol/L to 100 mmol/L （6.4 g/L）. The reduction of Cu （II） to metallic copper was shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion （Cu＋） was complexed by chloride to form the dichlorocuprous anion （CuCl-）. In addition, interference effect was also investigated when Fe3＋existed in the media, which was the common situation in the copper bioleaching system. The results showed no interference effect once the concentration of Fe3＋was less than 100 mmol/L （5.6 g/L）.展开更多
文摘Copper(Ⅱ) complexes Cu(C6H6N2)2(ClO4)2 (1) and Cu2(OAc)4(C5H5ClN2)2 (2) with amino pyridine derivatives ligands have been synthesized and characterized by elemental analysis and IR spectrum. Their crystal structures are determined by X ray diffraction method. Compound 1, C12H16Cl2CuN4O8, Mr=478.73, triclinic, space <IMG SRC="IMAGE/04170000.JPG" HEIGHT=14 WIDTH=16>group , a=0.7641(1)nm, b=0.7987(1)nm, c=0.7990(1)nm, α =106.78(1)° ,β =95.71(1)° , γ =108.85(1)° , V=0.4317(1)nm3, Z=1, Dc=1.841g· cm- 3, μ =1.627mm- 1, F(000) =243,R1=0.0264, ω R2=0.0641 (I >2σ (I)). In 1, the center metal ion Cu? possesses distorted octahedral geometry. Compound 2, C18H22C12Cu2N4O8, Mr=620.38,monoclinic, space group C2/c, a=1.9888(3), b=0.9158(1), c=1.4241(2)nm, β =115.89(1)° , V=2.3336(5)nm3, Z=4, Dc=1.766mg· cm- 3, μ =2.104mm- 1, F(000)=1256, R1=0.0263, wR2=0.0676 (I >2σ (I)). Compound 2 is dinuclear structure, in which each Cu? adopts five coordinated distorted square pyramid geometry. CCDC: 193109; 193110.
基金Projects(2012CB933303,2011CB707505)supported by the National Basic Research Program of ChinaProject(2012BAK08B05)supported by the National Key Technology R&D Program of China+1 种基金Projects(11391901900,11530700800,10391901600,201101042,11CH-15)supported by Science and Technology Commission of Shanghai Municipality,ChinaProject supported by Funding from CSIRO CEO Science Leader Program
文摘On-line Cu （II） ion concentration detection in bioleaching system was achieved by anodic stripping differential pulse voltammetry （ASDPV）. Good linearity between Cu （II） concentration and oxidation peak current was obtained when Cu （II） existed in 0K media in the concentration range of 1μmol/L （64μg/L） to 1 mmol/L （64 mg/L）. Moreover, when 0.2 mol/L KCl was added into this media, the linear detection range could be extended from 1 mmol/L to 100 mmol/L （6.4 g/L）. The reduction of Cu （II） to metallic copper was shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion （Cu＋） was complexed by chloride to form the dichlorocuprous anion （CuCl-）. In addition, interference effect was also investigated when Fe3＋existed in the media, which was the common situation in the copper bioleaching system. The results showed no interference effect once the concentration of Fe3＋was less than 100 mmol/L （5.6 g/L）.
