Effect of direct current electric field （DCEF） on corrosion behaviour of copper printed circuit board （PCB-Cu）, Cl-ion migration behaviour, dendrites growth under thin electrolyte layer was investigated using pote...Effect of direct current electric field （DCEF） on corrosion behaviour of copper printed circuit board （PCB-Cu）, Cl-ion migration behaviour, dendrites growth under thin electrolyte layer was investigated using potentiodynamic polarization and scanning electron microscopy （SEM） with energy dispersive spectrometer （EDS）. Results indicate that DCEF decreases the corrosion of PCB-Cu;Cl-ions directionally migrate from the negative pole to the positive pole, and enrich on the surface of the positive pole, which causes serious localized corrosion; dendrites grow on the surface of the negative pole, and the rate and scale of dendrite growth become faster and greater with the increase of external voltage and exposure time, respectively.展开更多
Copper is susceptible to producing corrosion problems in corrosive environments, which leads to serious safety problems. Thus, investigating the corrosion behavior of copper is of great significance. The effects of ro...Copper is susceptible to producing corrosion problems in corrosive environments, which leads to serious safety problems. Thus, investigating the corrosion behavior of copper is of great significance. The effects of rotating electromagnetic field on corrosion behavior of T2 copper in 3.5% sodium chloride solution with electrochemical measurements were investigated. The results showed that rotating electromagnetic field changed properties of 3.5% sodium chloride solution by increasing the values of temperature and pH and decreasing the values of conductivity and dissolved oxygen. The rotating electromagnetic field improved the corrosion resistance of T2 copper. The corrosion products of T2 copper in treated 3.5% sodium chloride solution were composed of Cu20 and CuCl. The low corrosion rate of T2 copper was resulted from the decrease of dissolved oxygen in 3.5% sodium chloride solution treated by rotating electromagnetic field.展开更多
The corrosion behavior of pure copper exposed to the atmosphere of Nansha Islands for 21 months was studied by mass loss method,composition analysis,morphology observation and electrochemical measurements.The results ...The corrosion behavior of pure copper exposed to the atmosphere of Nansha Islands for 21 months was studied by mass loss method,composition analysis,morphology observation and electrochemical measurements.The results showed that the average corrosion rate of copper exposed for one year was approximately 7.85μm/a,implying that Nansha Islands was classified as a corrosion category of CX.The structure and properties of the corrosion product layer generated on the front and back sides of the exposed sample differed significantly.The inner corrosion product layer(Cu2O)on the front side was relatively thick and dense,whereas the outer product layer(Cu2Cl(OH)3)was extremely thin.However,the outer product layer on the back side was thicker than the inner layer.Electrochemical measurements indicated that the protection afforded by the corrosion product layer on the front side was improved gradually,while that on the back side was deteriorated.展开更多
A pin-on-disc wear apparatus was used to carry out the tribological experiment of brass to investigate the effect of a magnetorheological （MR） fluid on the interfacial surface with and without magnetic field. A seri...A pin-on-disc wear apparatus was used to carry out the tribological experiment of brass to investigate the effect of a magnetorheological （MR） fluid on the interfacial surface with and without magnetic field. A series of tests were performed at the loads of 20-100 N and rotating speeds of 127-425 r/min for 2 h. The friction coefficient and wear rate were monitored by the wear apparatus, while the microstructures of the worn surfaces were observed by scanning electron microscope （SEM）. In addition, the chemical composition of worn surfaces was analyzed by energy dispersive X-ray spectroscopy （EDS）. Test results show different friction and wear performance of the MR fluid with and without magnetic field. At the same time, the effects of various normal loads and rotating speeds on the tribological behavior were investigated. Through the investigation of the morphologies of the wom surfaces under the magnetic field, it is found that the MR particles are clearly evident on the wom surface and the plastic flow of ridges causes the lateral extrusion. This directly indicates that abrasive wear is the predominant wear mechanism observed with MR fluid.展开更多
Research on information spillover effects between financial markets remains active in the economic community. A Granger-type model has recently been used to investigate the spillover between London Metal Exchange(LME)...Research on information spillover effects between financial markets remains active in the economic community. A Granger-type model has recently been used to investigate the spillover between London Metal Exchange(LME) and Shanghai Futures Exchange(SHFE) ,however,possible correlation between the future price and return on different time scales have been ignored. In this paper,wavelet multiresolution decomposition is used to investigate the spillover effects of copper future returns between the two markets. The daily return time series are decomposed on 2n(n=1,…,6) frequency bands through wavelet mul-tiresolution analysis. The correlation between the two markets is studied with decomposed data. It is shown that high frequency detail components represent much more energy than low-frequency smooth components. The relation between copper future daily returns in LME and that in SHFE are different on different time scales. The fluctuations of the copper future daily returns in LME have large effect on that in SHFE in 32-day scale,but small effect in high frequency scales. It also has evidence that strong effects exist between LME and SHFE for monthly responses of the copper futures but not for daily responses.展开更多
基金Project(50871044)supported by the National Natural Science Foundation of ChinaProject(2012M511207)supported by the Postdoctoral Science Foundation of ChinaProject(10122011)supported by the Science Research Foundation of Wuhan Institute Technology,China
文摘Effect of direct current electric field （DCEF） on corrosion behaviour of copper printed circuit board （PCB-Cu）, Cl-ion migration behaviour, dendrites growth under thin electrolyte layer was investigated using potentiodynamic polarization and scanning electron microscopy （SEM） with energy dispersive spectrometer （EDS）. Results indicate that DCEF decreases the corrosion of PCB-Cu;Cl-ions directionally migrate from the negative pole to the positive pole, and enrich on the surface of the positive pole, which causes serious localized corrosion; dendrites grow on the surface of the negative pole, and the rate and scale of dendrite growth become faster and greater with the increase of external voltage and exposure time, respectively.
基金Projects(51207031,51177022)supported by the National Natural Science Foundation of ChinaProject(2013M541368)supported by the China Postdoctoral Science Foundation+1 种基金Project(BS2011NJ002)supported by the Promotive Research Fund for Excellent Young and Middle-Aged Scientists of Shandong Province,ChinaProject(2008DFR60340)supported by the International Science and Technology Cooperation of China
文摘Copper is susceptible to producing corrosion problems in corrosive environments, which leads to serious safety problems. Thus, investigating the corrosion behavior of copper is of great significance. The effects of rotating electromagnetic field on corrosion behavior of T2 copper in 3.5% sodium chloride solution with electrochemical measurements were investigated. The results showed that rotating electromagnetic field changed properties of 3.5% sodium chloride solution by increasing the values of temperature and pH and decreasing the values of conductivity and dissolved oxygen. The rotating electromagnetic field improved the corrosion resistance of T2 copper. The corrosion products of T2 copper in treated 3.5% sodium chloride solution were composed of Cu20 and CuCl. The low corrosion rate of T2 copper was resulted from the decrease of dissolved oxygen in 3.5% sodium chloride solution treated by rotating electromagnetic field.
基金The authors are grateful for the financial supports from National Natural Science Foundation of China(51671197)Strategic Priority Research Program of Chinese Academy of Sciences(13040502).
文摘The corrosion behavior of pure copper exposed to the atmosphere of Nansha Islands for 21 months was studied by mass loss method,composition analysis,morphology observation and electrochemical measurements.The results showed that the average corrosion rate of copper exposed for one year was approximately 7.85μm/a,implying that Nansha Islands was classified as a corrosion category of CX.The structure and properties of the corrosion product layer generated on the front and back sides of the exposed sample differed significantly.The inner corrosion product layer(Cu2O)on the front side was relatively thick and dense,whereas the outer product layer(Cu2Cl(OH)3)was extremely thin.However,the outer product layer on the back side was thicker than the inner layer.Electrochemical measurements indicated that the protection afforded by the corrosion product layer on the front side was improved gradually,while that on the back side was deteriorated.
基金Project (2010-0015090) supported by the National Research Foundation of Korea
文摘A pin-on-disc wear apparatus was used to carry out the tribological experiment of brass to investigate the effect of a magnetorheological （MR） fluid on the interfacial surface with and without magnetic field. A series of tests were performed at the loads of 20-100 N and rotating speeds of 127-425 r/min for 2 h. The friction coefficient and wear rate were monitored by the wear apparatus, while the microstructures of the worn surfaces were observed by scanning electron microscope （SEM）. In addition, the chemical composition of worn surfaces was analyzed by energy dispersive X-ray spectroscopy （EDS）. Test results show different friction and wear performance of the MR fluid with and without magnetic field. At the same time, the effects of various normal loads and rotating speeds on the tribological behavior were investigated. Through the investigation of the morphologies of the wom surfaces under the magnetic field, it is found that the MR particles are clearly evident on the wom surface and the plastic flow of ridges causes the lateral extrusion. This directly indicates that abrasive wear is the predominant wear mechanism observed with MR fluid.
文摘Research on information spillover effects between financial markets remains active in the economic community. A Granger-type model has recently been used to investigate the spillover between London Metal Exchange(LME) and Shanghai Futures Exchange(SHFE) ,however,possible correlation between the future price and return on different time scales have been ignored. In this paper,wavelet multiresolution decomposition is used to investigate the spillover effects of copper future returns between the two markets. The daily return time series are decomposed on 2n(n=1,…,6) frequency bands through wavelet mul-tiresolution analysis. The correlation between the two markets is studied with decomposed data. It is shown that high frequency detail components represent much more energy than low-frequency smooth components. The relation between copper future daily returns in LME and that in SHFE are different on different time scales. The fluctuations of the copper future daily returns in LME have large effect on that in SHFE in 32-day scale,but small effect in high frequency scales. It also has evidence that strong effects exist between LME and SHFE for monthly responses of the copper futures but not for daily responses.
