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鄂东南矿集区鸡冠嘴矽卡岩型金铜矿床含矿岩体中辉石和角闪石成分变化特征及其对岩浆演化和成矿的指示意义 被引量:8
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作者 段登飞 蒋少涌 《岩石学报》 SCIE EI CAS CSCD 北大核心 2017年第11期3507-3517,共11页
为了解长江中下游地区与金铜矿化有关的岩体在浅部的演化过程及其对成矿的作用,本文对鄂东南矿集区鸡冠嘴矽卡岩型金铜矿成矿岩体石英二长闪长斑岩进行了详细的岩相学观察,并利用电子探针(EMPA)分析了其中辉石和角闪石的主量成分。岩相... 为了解长江中下游地区与金铜矿化有关的岩体在浅部的演化过程及其对成矿的作用,本文对鄂东南矿集区鸡冠嘴矽卡岩型金铜矿成矿岩体石英二长闪长斑岩进行了详细的岩相学观察,并利用电子探针(EMPA)分析了其中辉石和角闪石的主量成分。岩相学特征显示辉石形成时间早于角闪石。辉石成分变化较小,而角闪石成分变化较大。角闪石可根据Al的含量分为高低两组,即高铝含量的自形角闪石以及低铝含量的半自形及他形角闪石。高铝角闪石又不同程度的被低铝角闪石交代。通过矿物温压计估算辉石形成的温度和压力为1055~1071℃(平均1060℃)和224~312MPa(平均255MPa)。高铝角闪石形成的温度和压力为809~864℃(平均833℃),108~193MPa(平均137MPa),低铝角闪石形成的温度和压力为721~766℃(平均741℃),48~67MPa(平均56MPa)。岩浆具有较高的氧逸度,并且从高铝角闪石到低铝角闪石,熔体的氧逸度从△NNO+0.6升高到△NNO+1.9。岩浆经历了连续的侵位历史,从9.6km到5.2km的岩浆房再到2.1km的浅地壳处就位。岩浆在9.6km处经历了辉石的分离结晶,在5.2km处经历了角闪石及少部分斜长石的分离结晶,在2.1km处经历由于降压引起的流体出溶。由于深部的分离结晶作用,熔体中的水含量增加,氧逸度升高。较高的水含量使岩浆更容易演化出成矿热液,较高的氧逸度使岩浆演化早期没有硫化物的分离结晶,从而阻止了成矿元素在岩浆演化早期亏损。鸡冠嘴岩体较浅的就位深度也更有利于成矿流体的析出。这些因素共同作用形成了鸡冠嘴金铜矿床。 展开更多
关键词 鸡冠嘴 分离结晶 铜金富集 流体出溶 角闪石
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Zinc and copper bioaccumulation in fi sh from Laizhou Bay, the Bohai Sea 被引量:1
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作者 刘金虎 曹亮 +2 位作者 黄伟 张传涛 窦硕增 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2014年第3期491-502,共12页
Abstract Zinc (Zn) and copper (Cu) concentrations were determined in the tissues (muscle, stomach, liver, gills, skin, and gonads) of five commercial fish species (mullet Liza haematocheilus, flathead Platyceph... Abstract Zinc (Zn) and copper (Cu) concentrations were determined in the tissues (muscle, stomach, liver, gills, skin, and gonads) of five commercial fish species (mullet Liza haematocheilus, flathead Platycephalus indicus, mackerel Scomberomorus niphonius, silver pomfret Pampus argenteus, and sea bass Lateolabrax japonicus) from Laizhou Bay in the Bohai Sea. Metal bioaccumulation was highest in the metabolically active tissues of the gonads and liver. Bioconcentration factors for Zn were higher in all tissues (gonads 44.35, stomach 7.73, gills 7.72, liver 5.61, skin 4.88, and muscle 1.63) than the corresponding values for Cu (gonads 3.50, stomach 3.00, gills 1.60, liver 5.43, skin 1.50, and muscle 0.93). Mackerel tissues accumulated metal to higher concentrations than did other fish species, but bioaccumulation levels were not significantly correlated with the trophic levels of the fish. Zn and Cu concentrations in the tissues were generally negatively correlated with fish length, except for a few tissues of sea bass. Risk assessment based on national and international permissible limits and provisional tolerances for weekly intake of Zn and Cu revealed that the concentrations of these two metals in muscle were relatively low and would not pose hazards to human health. 展开更多
关键词 zinc(Zn) and copper (Cu) metal bioaccumulation TISSUES bioconcentration factor fish growth Laizhou Bay
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