越城岭界牌矿区夕卡岩型铜钨矿石工艺矿物学研究

界牌铜钨多金属矿是南岭成矿带西段越城岭矿集区一典型的夕卡岩型铜钨共生矿床,为综合回收利用铜、钨资源,研究通过野外调查取样、室内光学显微镜观察、化学多元素分析、化学物相分析、扫描电镜及能谱分析等多种手段,对矿区夕卡岩型铜钨矿石的工艺矿物学进行了综合研究。研究表明:矿石中可回收利用的元素为Cu和W。铜主要以黄铜矿矿物形式存在,最高回收率为95.15 %;钨主要以白钨矿矿物形式存在,最高回收率可达95.64 %。

某铜钼钨矿石浮选分离试验研究

对某含铜钼钨矿石进行了浮选分离工艺研究。试样为钨重选毛砂,除钨矿物外,还富含铜、钼等有价金属硫化矿物。采用铜钼混合浮选-铜钼分离的浮选工艺,综合回收试样中的钨、铜、钼。铜钼混合浮选时,采用高效活化剂BK546,有利于降低钨精矿的硫含量,并提高铜钼回收率。闭路试验获得钼精矿含钼57.90%、铜0.68%、钼回收率96.44%;铜精矿含铜37.32%、铜回收率99.64%;钨精矿含WO368.12%、铜0.025%、钼0.005%、钨回收率97.30%。实现了矿石中钨、铜、钼的有效分离回收。

江西某铜钼钨多金属矿石选矿工艺研究

江西某铜钼钨矿矿石中有用矿物以黄铜矿、辉钼矿、黑钨矿为主,并伴生有磁黄铁矿.为了给该矿产资源的开发利用提供依据,对其进行了选矿试验研究.经试验比较,采用铜钼混浮-铜钼分离-尾矿脱硫-重选回收黑钨矿的联合工艺流程.获得了比较理想的铜精矿、钼精矿、钨精矿3种精矿产品,铜精矿品位为26.38%,回收率为91.35%;钼精矿品位为51.23%,回收率为83.54%;钨精矿品位为52.58%,回收率为65.49%.使矿石中的有价元素得到了较好的综合回收.

从钨重选粗精矿中浮选回收铜铋试验

粤北某高硫伴生铜、铋的钨矿选矿厂采用枱浮从重选钨粗精矿中回收硫化矿物,再采用抑铋浮铜—重选选铋工艺从硫化矿混合精矿中分离回收铜铋,不仅铜、铋回收率低,且铜精矿含铋高。为解决铜、铋的高效分离与回收问题,以现场重选钨粗精矿为试样,进行了铜、铋分离与回收试验。结果表明:WO_3、Cu、Bi、Ag品位分别为13.66%、3.32%、1.93%和308.50 g/t,主要铜矿物为黄铜矿和辉铜矿,主要铋矿物为辉铋矿,有用矿物粒度主要为0.64～0.04 mm,黑钨矿、白钨矿、黄铁矿嵌布粒度略粗,黄铜矿、辉铋矿粒度略细的试样,在棒磨至-0.2 mm的情况下,以石灰为调整剂、SY为铋抑制剂、Z-200为捕收剂1粗1精2扫流程抑铋浮铜,以GYC-1为铋活化剂、丁基黄药为铋捕收剂1粗2精2扫流程活化浮铋,最终获得铜品位为19.01%、铜回收率为93.51%、含铋0.81%的铜精矿,以及铋品位为21.39%、铋回收率为78.61%、含铜0.63%的铋精矿,与现场生产指标相比,铜精矿铜品位、铜回收率分别提高了10.48和9.19个百分点,含铋下降了1.85个百分点;铋精矿铋品位下降了5.23个百分点、铋回收率提高了33.25个百分点,含铜下降了1.68个百分点,较好地实现了铜、铋的分离与回收。

Geological characteristics and mineralization setting of the Zhuxi tungsten(copper) polymetallic deposit in the Eastern Jiangnan Orogen

The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contact zone between Yanshanian granites and Carboniferous-Permian limestone. Granites related to this mineralization mainly include equigranular, middle- to coarse-grained granites and granitic porphyries. There are two mineralization types: skarn scheelite(copper) and granite scheelite mineralization. The former is large scale and has a high content of scheelite, whereas the latter is small scale and has a low content of scheelite. In the Taqian-Fuchun Basin, its NW boundary is a thrust fault, and the SE boundary is an angular unconformity with Proterozoic basement. In Carboniferous-Permian rock assemblages, the tungsten and copper contents in the limestone are both very high. The contents of major elements in granitoids do not differ largely between the periphery and the inside of the Zhuxi ore deposit. In both areas, the values of the aluminum saturation index are A/CNK>1.1, and the rocks are classified as potassium-rich strongly peraluminous granites. In terms of trace elements, compared to granites on the periphery of the Zhuxi ore deposit, the granites inside the Zhuxi ore deposit have smaller d Eu values, exhibit a significantly more negative Eu anomaly, are richer in Rb, U, Ta, Pb and Hf, and are more depleted in Ba, Ce, Sr, La and Ti, which indicates that they are highly differentiated S-type granites with a high degree of evolution. Under the influence of fluids, mineralization of sulfides is evident within massive rock formations inside the Zhuxi ore deposit, and the mean SO_3 content is 0.2%. Compared to peripheral rocks, the d Eu and total rare earth element(REE) content of granites inside the Zhuxi ore deposit are both lower, indicating a certain evolutionary inheritance relationship between the granites on the periphery and the granites inside the Zhuxi ore deposit. For peripheral and ore district plutons, U-Pb zircon dating shows an age range of 152–148 Ma. In situ Lu-Hf isotope analysis of zircon in the granites reveals that the calculated e_(Hf)(t) values are all negative, and the majority range from -6 to -9. The T_(DM2) values are concentrated in the range of 1.50–1.88 Ga(peak at 1.75 Ga), suggesting that the granitic magmas are derived from partial melting of ancient crust. This paper also discusses the metallogenic conditions and ore-controlling conditions of the ore district from the perspectives of mineral contents, hydrothermal alteration, and ore-controlling structures in the strata and the ore-bearing rocks. It is proposed that the Zhuxi ore deposit went through a multistage evolution, including oblique intrusion of granitic magmas, skarn mineralization, cooling and alteration, and precipitation of metal sulfides. The mineralization pattern can be summarized as "copper in the east and tungsten in the west, copper at shallow-middle depths and tungsten at deep depths, tungsten in the early stage and copper in the late stage".