Photocatalytic reduction method using TiO2 suspension for removal as well as possibly recovery of silver （Ag（I）） in the presence of Cu（II） is examined. The photocatalytic reduction was performed by batch techniq...Photocatalytic reduction method using TiO2 suspension for removal as well as possibly recovery of silver （Ag（I）） in the presence of Cu（II） is examined. The photocatalytic reduction was performed by batch technique in a closed reactor equipped with UV lamp. The concentration of unreduced Ag（I） was analyzed by atomic absorption spectrophotometry method. The research results indicate that Ag（I） in the solution can be removed and recovered effectively as silver metal Ag（0） deposited on the surface of TiO2 for photocatalytic reduction. In addition, the presence of Cu（II） ion with increasing concentration leads to a proportional decline in Ag（I） photoreduction due to the prominent competition in the adsorption on the surface of TiO2. The effectiveness of Ag（I） ion photoreduction in the presence of Cu（II） ion is strongly influenced by solution pH and the highest photoreduction is obtained at pH 5 - 8, which is related with the speciation ofAg（I）, TiO2 surface as well as Cu（II） in the solution.展开更多
文摘Photocatalytic reduction method using TiO2 suspension for removal as well as possibly recovery of silver （Ag（I）） in the presence of Cu（II） is examined. The photocatalytic reduction was performed by batch technique in a closed reactor equipped with UV lamp. The concentration of unreduced Ag（I） was analyzed by atomic absorption spectrophotometry method. The research results indicate that Ag（I） in the solution can be removed and recovered effectively as silver metal Ag（0） deposited on the surface of TiO2 for photocatalytic reduction. In addition, the presence of Cu（II） ion with increasing concentration leads to a proportional decline in Ag（I） photoreduction due to the prominent competition in the adsorption on the surface of TiO2. The effectiveness of Ag（I） ion photoreduction in the presence of Cu（II） ion is strongly influenced by solution pH and the highest photoreduction is obtained at pH 5 - 8, which is related with the speciation ofAg（I）, TiO2 surface as well as Cu（II） in the solution.
