The bonding interface of 7B52 Al alloy laminated composite (ALC) fabricated by hot rolling was investigated using optical microscopy (OM), transmission electron microscopy (TEM), scanning electron microscopy (...The bonding interface of 7B52 Al alloy laminated composite (ALC) fabricated by hot rolling was investigated using optical microscopy (OM), transmission electron microscopy (TEM), scanning electron microscopy (SEM), ultrasonic flaw detection (UFD), and bonding strength tests. The results show that metallurgical bonding is achieved at the interface after composite rolling. The TEM analysis and tensile tests indicate that the 7B52 ALC plate combines high strength of the hard individual layer and good toughness of the soft individual layer. However, UFD technology and SEM analysis prove that the defects (thick oxide films, acid washed residues, air, oil and coarse particles) existing in the bonding interface are harmful to the bonding strength. To sum up, the composite roiling process is suitable for 7B52 ALC plate, and the content and size of the defects should be controlled strictly. Advanced surface treatment of each individual layer would be beneficial to further improve the bonding quality.展开更多
The realization way of snake rolling was introduced. Flow velocity, strain and stress distribution of 7075 aluminum alloy plate during snake rolling and symmetrical rolling were analyzed in Deform 3D. Effects of veloc...The realization way of snake rolling was introduced. Flow velocity, strain and stress distribution of 7075 aluminum alloy plate during snake rolling and symmetrical rolling were analyzed in Deform 3D. Effects of velocity ratio, offset distance between two rolls and pass reduction on the distribution of equivalent strain and shear strain were analyzed. The results show that flow velocity and equivalent strain on the lower layer of the plate are larger than those of the upper layer because of the larger velocity of the lower roll and the gap is increased with the increase of velocity ratio and pass reduction. The shear strain of roiling direction in the center point is almost zero during symmetrical rolling, while it is much larger during snake rolling because of the existence of rub zone. The shear strain is increased with the increase of velocity ratio, offset distance and pass reduction. This additional shear strain is beneficial to improve the in_homogeneous strain distribution.展开更多
The microstructure and mechanical properties of the age hardening AA6061 Al alloy subjected to cryo-rolling(CR) and room temperature rolling(RTR) treatments were investigated. The rolled and aged alloys were analy...The microstructure and mechanical properties of the age hardening AA6061 Al alloy subjected to cryo-rolling(CR) and room temperature rolling(RTR) treatments were investigated. The rolled and aged alloys were analyzed by using DSC, EBSD, TEM, Vickers hardness analysis and tensile test. The results show that the cryo-rolled treatment has an effect on the precipitation sequence of AA6061 Al alloy. The ultrafine grain structures are formed to promote the fine second phase particles to disperse in the aluminum matrix after the peak aging, which is attributed to lots of dislocations tangled in the rolling process. Therefore, the strength and ductility of AA6061 Al alloy are simultaneously modified after the cryo-rolling and aging treatment compared with room temperature rolled one.展开更多
Asymmetric rolling (ASR), as one of severe plastic deformation (SPD) methods to make ultra-fine materials with enhanced performance is mainly used to prepare foil and thin strip. The asymmetrical rolling was achie...Asymmetric rolling (ASR), as one of severe plastic deformation (SPD) methods to make ultra-fine materials with enhanced performance is mainly used to prepare foil and thin strip. The asymmetrical rolling was achieved by adjusting the diameters of the upper roll and the bottom roll and was used to prepare hot-rolled thick plate of 5182 aluminium alloy. The shear deformation and plate shape control were experimentally studied. The experimental results show that asymmetrical rolling has a significant effect on metal deformation stream and can somehow refine microstructure and improve the uniformity of microstructure and properties. The asymmetrical rolling process can also reduce the rolling force. However, bending of rolling plate often happens during asymmetrical rolling process. The factors affecting the bending were discussed.展开更多
Under H2 atmosphere, the green strips were prepared from Al-5.8Zn-1.63Mg-2.22Cu-0.12Zr(mass fraction, %) powders by the semi-solid rolling process with a relative density from 76.1% to 88.0%. The role of temperature o...Under H2 atmosphere, the green strips were prepared from Al-5.8Zn-1.63Mg-2.22Cu-0.12Zr(mass fraction, %) powders by the semi-solid rolling process with a relative density from 76.1% to 88.0%. The role of temperature on microstructure and mechanical properties was investigated. With increasing rolling temperature from 580 to 610 °C, the disappearance of primary powder boundary and isolated pores, inter-diffusion of species and the change of grain boundary were accelerated. Moreover, the mechanism of microstructure evolution changes from the densification dominant regime to the coarsening dominant regime; the amount of η(MgZn2) phase decreased and more Al2 Cu particles precipitated at grain boundaries. The optimum temperature for semi-solid rolling of Al-5.8Zn-1.63Mg-2.22Cu-0.12 Zr powders was determined. The liquid fraction in the range of 53% to 67% corresponds with a high density level of green strips. The present experimental analysis suggests that semi-solid powder rolling can be optimized to manufacture strips with high mechanical properties.展开更多
The influence of cryorolling(CR),room temperature rolling(RTR)and post annealing on precipitation,microstructuralevolution(recovery,recrystallisation and grain growth),mechanical and corrosion behavior,was investigate...The influence of cryorolling(CR),room temperature rolling(RTR)and post annealing on precipitation,microstructuralevolution(recovery,recrystallisation and grain growth),mechanical and corrosion behavior,was investigated in the present work.The precipitation kinetics and microstructural morphology of CR,RTR,and post annealed samples were investigated by differentialscanning calorimetry(DSC),transmission electron microscopy(TEM),and electron back scattered diffraction(EBSD)to elucidatethe observed mechanical properties.After annealing at200°C,UTS and hardness of CR samples(345MPa and HV127)wereimproved as compared to RTR samples(320MPa and HV115).The increase in hardness and UTS of CR samples after annealing at200°C was due to precipitation ofβ''from Al matrix,which imparted higher Zener drag effect as compared to RTR samples.Theimprovement in corrosion and pitting potentials was observed for CR samples(?1.321V and?700mV)as compared to RTRsamples(?1.335V and?710mV).In CR samples,heavy dislocation density and dissolution of Mg4Al3Si4-precipitates in the Almatrix have improved corrosion resistance of the alloy through formation of protective passive layer and suppression of galvanic cell,respectively.展开更多
The effect of rolling to a total effective strain of 2 at the liquid nitrogen temperature and subsequent natural and artificial aging on the structure and service properties of the pre-quenched hot-pressed 2024 alumin...The effect of rolling to a total effective strain of 2 at the liquid nitrogen temperature and subsequent natural and artificial aging on the structure and service properties of the pre-quenched hot-pressed 2024 aluminum alloy was investigated.Using optical and electron microscopy,and X-ray analysis,it was found that the cryorolling did not qualitatively change the type of the initial coarse-fibered microstructure,but produced a well-developed nanocell substructure inside fibers.Further aging led to decomposition of the preliminary supersaturated and work-hardened aluminum solid solution and precipitation of strengthening phases in the statically recovered and/or recrystallized matrix.As a result,the rolled and naturally aged alloy demonstrated the yield and ultimate tensile strengths(YS=590 MPa,UTS=640 MPа)much higher than those in the pressed andТ6-heat treated alloy at equal elongation to failure(El^6%).Artificial aging at a temperature less than conventional T6 route could provide the extra alloy strengthening and the unique balance of mechanical properties,involving enhanced strength(YS=610 MPa,UTS=665 MPа)and ductility(El^10%),and good static crack resistance(the specific works for crack formation and growth were 42 and 18 k J/m^2,respectively)and corrosion resistance(the intensity and depth of intercrystalline corrosion were 23%and 50μm,respectively).展开更多
Ultra-high strength Al alloy system was developed by cryorolling and the contribution of various strengthening mechanisms to the overall yield strength of the system was evaluated. Cryorolling of Al-4%Cu-3%TiB2 in sit...Ultra-high strength Al alloy system was developed by cryorolling and the contribution of various strengthening mechanisms to the overall yield strength of the system was evaluated. Cryorolling of Al-4%Cu-3%TiB2 in situ composite followed by short annealing at 175 ℃ and ageing at 125℃ resulted in an ultra-high yield strength of about 800 MPa with 9%total elongation. The strengthening contributions form solid solution strengthening, grain refinement, dislocation strengthening, precipitation hardening and dispersion strengthening were evaluated using standard equations. It was estimated that the maximum contribution was from grain refinement due to cryorolling followed by precipitation and dispersion strengthening.展开更多
An Al−3.6Cu−1Li alloy was subjected to room temperature rolling and cryorolling to investigate their effects on microstructure evolution and mechanical properties.The microstructure and aging characteristics of the ro...An Al−3.6Cu−1Li alloy was subjected to room temperature rolling and cryorolling to investigate their effects on microstructure evolution and mechanical properties.The microstructure and aging characteristics of the room temperature-rolled and the cryorolled alloys with 70%and 90%of thickness reductions were studied by microstructure analysis and mechanical tests.The samples subjected to cryorolling with 90%of thickness reduction have high strength and good toughness.This is mainly due to the inhibition of dynamic recovery and the accumulation of high-density dislocations in cryorolled samples.In addition,the artificial aging reveals that the temperature at which peak hardness is attained is inversely proportional to the deformation amount and directly proportional to the rolling temperature.Moreover,bright field images of cryorolled samples after aging indicate the existence of T1(Al2CuLi)precipitates.This suggests that the high stored strain energy enhances the aging kinetics of the alloy,which further promotes the nucleation of T1 phases.展开更多
The extrusion preform of the spray-formed5A12Al alloy was hot rolled using high reduction rolling technology.By means of transmission electron microscopy(TEM),electron backscatter diffraction(EBSD)and energy dispersiv...The extrusion preform of the spray-formed5A12Al alloy was hot rolled using high reduction rolling technology.By means of transmission electron microscopy(TEM),electron backscatter diffraction(EBSD)and energy dispersive spectroscopy(EDS),the microstructure evolution was studied and the strengthening and toughening mechanism was thereby proposed.The results indicate that discontinuous and continuous dynamic recrystallization occurred during the hot rolling deformation of the spray-formed5A12Al alloy.The grain size was significantly refined and the micro-scale grains formed.Partial dynamic recrystallization leads to a significant increase of dislocation density and cellular structure.The Mg atoms were distributed in the Al matrix mainly in the presence of solid solution rather than the formation of precipitate.High solid solution of Mg atoms not only hindered the dislocation motion and increased the density of dislocation,but also exhibited a remarkable solid solution strengthening effect,which contributes to the high strength and high toughness of the as-rolled sheets.The tensile strength and elongation of spray formed5A12Al alloy at room temperature after3passes hot rolling were622MPa and20%,respectively.展开更多
A comparative study of the structure and mechanical behavior of an Al-5 Mg-0.18 Mn-0.2 Sc-0.08 Zr-0.01 Fe-0.01 Si(wt.%)alloy ingot subjected to multidirectional isothermal forging(MIF)to a strain of 12 or equal-channe...A comparative study of the structure and mechanical behavior of an Al-5 Mg-0.18 Mn-0.2 Sc-0.08 Zr-0.01 Fe-0.01 Si(wt.%)alloy ingot subjected to multidirectional isothermal forging(MIF)to a strain of 12 or equal-channel angular pressing(ECAP)to a strain of 10 at 325℃,and subsequent warm and cold rolling(WR and CR)at 325 and 20℃,was performed.The results showed that the MIF process of ultrafine-grained structure with a(sub)grain size dUFG=2μm resulted in enhanced room-temperature ductility and superplastic elongation up to 2800%.Further grain refinement under WR as well as development of a heavily-deformed microstructure with high dislocation density by subsequent CR resulted in a yield/ultimate tensile strength increase from 235/360 MPa after MIF to 315/460 and 400/515 MPa after WR and CR,respectively.Simultaneously,WR led to improved superplastic elongation up to 4000%,while after CR the elongation remained sufficiently high(up to 1500%).Compared with MIF,ECAP resulted in more profound grain refinement(dUFG=1μm),which promoted higher strength and superplastic properties.However,this effect smoothed down upon WR,ensuring equal properties of the processed sheets.CR of the ECAPed alloy,in contrast,led to higher strengthening and slightly better superplastic behavior than those after CR following MIF.展开更多
The mechanical properties and microstructure of Al-Cu-Li alloy sheets subjected to cryorolling(-100 ° C,-190 ℃) or hot rolling(400 ℃) and subsequent aging at 160 ℃ for different times were investigated. The dy...The mechanical properties and microstructure of Al-Cu-Li alloy sheets subjected to cryorolling(-100 ° C,-190 ℃) or hot rolling(400 ℃) and subsequent aging at 160 ℃ for different times were investigated. The dynamic precipitation and dislocation characterizations were examined via transmission electron microscopy and X-ray diffraction. The grain morphologies and the fracture-surface morphologies were studied via optical microscopy and scanning electron microscopy. Samples subjected to cryorolling followed by aging exhibited relatively high dislocation densities and a large number of precipitates compared with hot-rolled samples. The samples cryorolled at-190 ℃ and then aged for 15 h presented the highest ultimate tensile strength(586 MPa), while the alloy processed via hot rolling followed by 10 h aging exhibited the highest uniform elongation rate(11.5%). The size of precipitates increased with the aging time, which has significant effects on the interaction mechanism between dislocations and precipitates. Bowing is the main interaction method between the deformation-induced dislocations and coarsened precipitates during tensile tests, leading to the decline of the mechanical properties of the alloy during overaging. These interesting findings can provide significant insights into the development of materials possessing both excellent strength and high ductility.展开更多
The exfoliation morphologies and electrochemical impedance spectroscopy (EIS) features of as received rolled AA8090 Al Li alloy in EXCO solution were studied. The EIS was simulated using an equivalent circuit. The res...The exfoliation morphologies and electrochemical impedance spectroscopy (EIS) features of as received rolled AA8090 Al Li alloy in EXCO solution were studied. The EIS was simulated using an equivalent circuit. The results show that once the exfoliation occurs, the EIS is composed of two capacitive arcs at high frequency and mediate low frequency; among them, the capacitance corresponding to high frequency ( C 1) is originated from original flat alloy surface, while the capacitance corresponding to mediate low frequency ( C 2) from new interface exposed to EXCO solution due to the exfoliation and the ratio of C 2 to C 1 increases with exfoliation degree. It is advanced that the exfoliation degree can be quantitatively judged through this ratio.展开更多
基金Project(51312JQ08)supported by the Pre-Research Foundation of China General Equipment DepartmentProject(NBPJ2013-4)supported by the Postdoctoral Science Foundation of Ningbo Branch of China Academy of Ordnance Science+1 种基金Project(bsh1402073)supported by the Postdoctoral Science Foundation of Zhejiang Province,ChinaProject(2014A610051)supported by the Ningbo Natural Science Foundation of China
文摘The bonding interface of 7B52 Al alloy laminated composite (ALC) fabricated by hot rolling was investigated using optical microscopy (OM), transmission electron microscopy (TEM), scanning electron microscopy (SEM), ultrasonic flaw detection (UFD), and bonding strength tests. The results show that metallurgical bonding is achieved at the interface after composite rolling. The TEM analysis and tensile tests indicate that the 7B52 ALC plate combines high strength of the hard individual layer and good toughness of the soft individual layer. However, UFD technology and SEM analysis prove that the defects (thick oxide films, acid washed residues, air, oil and coarse particles) existing in the bonding interface are harmful to the bonding strength. To sum up, the composite roiling process is suitable for 7B52 ALC plate, and the content and size of the defects should be controlled strictly. Advanced surface treatment of each individual layer would be beneficial to further improve the bonding quality.
基金Projects(2012CB619505,2010CB731703)supported by the National Basic Research Program of ChinaProject(CX2013B065)supported by Hunan Provincial Innovation Foundation for Postgraduate,ChinaProject(117308)supported by Postdoctoral Science Foundation of Central South University,China
文摘The realization way of snake rolling was introduced. Flow velocity, strain and stress distribution of 7075 aluminum alloy plate during snake rolling and symmetrical rolling were analyzed in Deform 3D. Effects of velocity ratio, offset distance between two rolls and pass reduction on the distribution of equivalent strain and shear strain were analyzed. The results show that flow velocity and equivalent strain on the lower layer of the plate are larger than those of the upper layer because of the larger velocity of the lower roll and the gap is increased with the increase of velocity ratio and pass reduction. The shear strain of roiling direction in the center point is almost zero during symmetrical rolling, while it is much larger during snake rolling because of the existence of rub zone. The shear strain is increased with the increase of velocity ratio, offset distance and pass reduction. This additional shear strain is beneficial to improve the in_homogeneous strain distribution.
基金Project(zzyjkt2013-07B) supported by the State Key Laboratory of High Performance Complex Manufacturing,Central South University,China
文摘The microstructure and mechanical properties of the age hardening AA6061 Al alloy subjected to cryo-rolling(CR) and room temperature rolling(RTR) treatments were investigated. The rolled and aged alloys were analyzed by using DSC, EBSD, TEM, Vickers hardness analysis and tensile test. The results show that the cryo-rolled treatment has an effect on the precipitation sequence of AA6061 Al alloy. The ultrafine grain structures are formed to promote the fine second phase particles to disperse in the aluminum matrix after the peak aging, which is attributed to lots of dislocations tangled in the rolling process. Therefore, the strength and ductility of AA6061 Al alloy are simultaneously modified after the cryo-rolling and aging treatment compared with room temperature rolled one.
基金Projects(51104043,51374067)supported by the National Natural Science Foundation of ChinaProject(2012CB619506)supported by the National Basic Research Program of ChinaProject(N120409002)supported by the Fundamental Research Funds for the Central Universities,China
文摘Asymmetric rolling (ASR), as one of severe plastic deformation (SPD) methods to make ultra-fine materials with enhanced performance is mainly used to prepare foil and thin strip. The asymmetrical rolling was achieved by adjusting the diameters of the upper roll and the bottom roll and was used to prepare hot-rolled thick plate of 5182 aluminium alloy. The shear deformation and plate shape control were experimentally studied. The experimental results show that asymmetrical rolling has a significant effect on metal deformation stream and can somehow refine microstructure and improve the uniformity of microstructure and properties. The asymmetrical rolling process can also reduce the rolling force. However, bending of rolling plate often happens during asymmetrical rolling process. The factors affecting the bending were discussed.
基金Projects(50774035,51274107)supported by the National Natural Science Foundation of China
文摘Under H2 atmosphere, the green strips were prepared from Al-5.8Zn-1.63Mg-2.22Cu-0.12Zr(mass fraction, %) powders by the semi-solid rolling process with a relative density from 76.1% to 88.0%. The role of temperature on microstructure and mechanical properties was investigated. With increasing rolling temperature from 580 to 610 °C, the disappearance of primary powder boundary and isolated pores, inter-diffusion of species and the change of grain boundary were accelerated. Moreover, the mechanism of microstructure evolution changes from the densification dominant regime to the coarsening dominant regime; the amount of η(MgZn2) phase decreased and more Al2 Cu particles precipitated at grain boundaries. The optimum temperature for semi-solid rolling of Al-5.8Zn-1.63Mg-2.22Cu-0.12 Zr powders was determined. The liquid fraction in the range of 53% to 67% corresponds with a high density level of green strips. The present experimental analysis suggests that semi-solid powder rolling can be optimized to manufacture strips with high mechanical properties.
文摘The influence of cryorolling(CR),room temperature rolling(RTR)and post annealing on precipitation,microstructuralevolution(recovery,recrystallisation and grain growth),mechanical and corrosion behavior,was investigated in the present work.The precipitation kinetics and microstructural morphology of CR,RTR,and post annealed samples were investigated by differentialscanning calorimetry(DSC),transmission electron microscopy(TEM),and electron back scattered diffraction(EBSD)to elucidatethe observed mechanical properties.After annealing at200°C,UTS and hardness of CR samples(345MPa and HV127)wereimproved as compared to RTR samples(320MPa and HV115).The increase in hardness and UTS of CR samples after annealing at200°C was due to precipitation ofβ''from Al matrix,which imparted higher Zener drag effect as compared to RTR samples.Theimprovement in corrosion and pitting potentials was observed for CR samples(?1.321V and?700mV)as compared to RTRsamples(?1.335V and?710mV).In CR samples,heavy dislocation density and dissolution of Mg4Al3Si4-precipitates in the Almatrix have improved corrosion resistance of the alloy through formation of protective passive layer and suppression of galvanic cell,respectively.
文摘The effect of rolling to a total effective strain of 2 at the liquid nitrogen temperature and subsequent natural and artificial aging on the structure and service properties of the pre-quenched hot-pressed 2024 aluminum alloy was investigated.Using optical and electron microscopy,and X-ray analysis,it was found that the cryorolling did not qualitatively change the type of the initial coarse-fibered microstructure,but produced a well-developed nanocell substructure inside fibers.Further aging led to decomposition of the preliminary supersaturated and work-hardened aluminum solid solution and precipitation of strengthening phases in the statically recovered and/or recrystallized matrix.As a result,the rolled and naturally aged alloy demonstrated the yield and ultimate tensile strengths(YS=590 MPa,UTS=640 MPа)much higher than those in the pressed andТ6-heat treated alloy at equal elongation to failure(El^6%).Artificial aging at a temperature less than conventional T6 route could provide the extra alloy strengthening and the unique balance of mechanical properties,involving enhanced strength(YS=610 MPa,UTS=665 MPа)and ductility(El^10%),and good static crack resistance(the specific works for crack formation and growth were 42 and 18 k J/m^2,respectively)and corrosion resistance(the intensity and depth of intercrystalline corrosion were 23%and 50μm,respectively).
基金the Department of Science & Technology (DST) for their financial support for carrying out this research through Fast Track Scheme (DST Sanction No: SR/FT/ET-005/2008)Technical Education Quality Improvement Programme (TEQIP)
文摘Ultra-high strength Al alloy system was developed by cryorolling and the contribution of various strengthening mechanisms to the overall yield strength of the system was evaluated. Cryorolling of Al-4%Cu-3%TiB2 in situ composite followed by short annealing at 175 ℃ and ageing at 125℃ resulted in an ultra-high yield strength of about 800 MPa with 9%total elongation. The strengthening contributions form solid solution strengthening, grain refinement, dislocation strengthening, precipitation hardening and dispersion strengthening were evaluated using standard equations. It was estimated that the maximum contribution was from grain refinement due to cryorolling followed by precipitation and dispersion strengthening.
基金Project(2019YFB2006500)supported by the National Key Research and Development Program of ChinaProject(51674303)supported by the National Natural Science Foundation of China+2 种基金Project(2018RS3015)supported by the Huxiang High-Level Talent Gathering Project of Hunan Province,ChinaProject(2019CX006)supported by the Innovation Driven Program of Central South University,ChinaProject supported by the Research Fund of the Key Laboratory of High Performance Complex Manufacturing at Central South University,China。
文摘An Al−3.6Cu−1Li alloy was subjected to room temperature rolling and cryorolling to investigate their effects on microstructure evolution and mechanical properties.The microstructure and aging characteristics of the room temperature-rolled and the cryorolled alloys with 70%and 90%of thickness reductions were studied by microstructure analysis and mechanical tests.The samples subjected to cryorolling with 90%of thickness reduction have high strength and good toughness.This is mainly due to the inhibition of dynamic recovery and the accumulation of high-density dislocations in cryorolled samples.In addition,the artificial aging reveals that the temperature at which peak hardness is attained is inversely proportional to the deformation amount and directly proportional to the rolling temperature.Moreover,bright field images of cryorolled samples after aging indicate the existence of T1(Al2CuLi)precipitates.This suggests that the high stored strain energy enhances the aging kinetics of the alloy,which further promotes the nucleation of T1 phases.
基金Project(2017JJ2073) supported by the Natural Science Foundation of Hunan Province,ChinaProject(15B063) supported by the Youth Research Foundation of Education Bureau of Hunan Province,China
文摘The extrusion preform of the spray-formed5A12Al alloy was hot rolled using high reduction rolling technology.By means of transmission electron microscopy(TEM),electron backscatter diffraction(EBSD)and energy dispersive spectroscopy(EDS),the microstructure evolution was studied and the strengthening and toughening mechanism was thereby proposed.The results indicate that discontinuous and continuous dynamic recrystallization occurred during the hot rolling deformation of the spray-formed5A12Al alloy.The grain size was significantly refined and the micro-scale grains formed.Partial dynamic recrystallization leads to a significant increase of dislocation density and cellular structure.The Mg atoms were distributed in the Al matrix mainly in the presence of solid solution rather than the formation of precipitate.High solid solution of Mg atoms not only hindered the dislocation motion and increased the density of dislocation,but also exhibited a remarkable solid solution strengthening effect,which contributes to the high strength and high toughness of the as-rolled sheets.The tensile strength and elongation of spray formed5A12Al alloy at room temperature after3passes hot rolling were622MPa and20%,respectively.
基金financial supports from the Russian Science Foundation under grant No.16-19-10152P(the alloy MIF processing and room-temperature mechanical testing)by the Ministry of Science and Higher Education of Russia under the state assignment of IMSP RAS(ECAP and analysis of superplasticity).
文摘A comparative study of the structure and mechanical behavior of an Al-5 Mg-0.18 Mn-0.2 Sc-0.08 Zr-0.01 Fe-0.01 Si(wt.%)alloy ingot subjected to multidirectional isothermal forging(MIF)to a strain of 12 or equal-channel angular pressing(ECAP)to a strain of 10 at 325℃,and subsequent warm and cold rolling(WR and CR)at 325 and 20℃,was performed.The results showed that the MIF process of ultrafine-grained structure with a(sub)grain size dUFG=2μm resulted in enhanced room-temperature ductility and superplastic elongation up to 2800%.Further grain refinement under WR as well as development of a heavily-deformed microstructure with high dislocation density by subsequent CR resulted in a yield/ultimate tensile strength increase from 235/360 MPa after MIF to 315/460 and 400/515 MPa after WR and CR,respectively.Simultaneously,WR led to improved superplastic elongation up to 4000%,while after CR the elongation remained sufficiently high(up to 1500%).Compared with MIF,ECAP resulted in more profound grain refinement(dUFG=1μm),which promoted higher strength and superplastic properties.However,this effect smoothed down upon WR,ensuring equal properties of the processed sheets.CR of the ECAPed alloy,in contrast,led to higher strengthening and slightly better superplastic behavior than those after CR following MIF.
基金Project(2019YFB2006500) supported by the National Key Research and Development Program,ChinaProject(51674303) supported by the National Natural Science Foundation of China+3 种基金Project(2020GK2032) supported by Hunan High-tech Industry Science and Technology Innovation Leading Plan,ChinaProject (2018RS3015) supported by the Huxiang High-level Talent Gathering Project of Hunan Province,ChinaProject(2017YFA0700700) supported by the Ministry of Science&Technology of ChinaProject(2019CX006) supported by Innovation Driven Program of Central South University,China。
文摘The mechanical properties and microstructure of Al-Cu-Li alloy sheets subjected to cryorolling(-100 ° C,-190 ℃) or hot rolling(400 ℃) and subsequent aging at 160 ℃ for different times were investigated. The dynamic precipitation and dislocation characterizations were examined via transmission electron microscopy and X-ray diffraction. The grain morphologies and the fracture-surface morphologies were studied via optical microscopy and scanning electron microscopy. Samples subjected to cryorolling followed by aging exhibited relatively high dislocation densities and a large number of precipitates compared with hot-rolled samples. The samples cryorolled at-190 ℃ and then aged for 15 h presented the highest ultimate tensile strength(586 MPa), while the alloy processed via hot rolling followed by 10 h aging exhibited the highest uniform elongation rate(11.5%). The size of precipitates increased with the aging time, which has significant effects on the interaction mechanism between dislocations and precipitates. Bowing is the main interaction method between the deformation-induced dislocations and coarsened precipitates during tensile tests, leading to the decline of the mechanical properties of the alloy during overaging. These interesting findings can provide significant insights into the development of materials possessing both excellent strength and high ductility.
文摘The exfoliation morphologies and electrochemical impedance spectroscopy (EIS) features of as received rolled AA8090 Al Li alloy in EXCO solution were studied. The EIS was simulated using an equivalent circuit. The results show that once the exfoliation occurs, the EIS is composed of two capacitive arcs at high frequency and mediate low frequency; among them, the capacitance corresponding to high frequency ( C 1) is originated from original flat alloy surface, while the capacitance corresponding to mediate low frequency ( C 2) from new interface exposed to EXCO solution due to the exfoliation and the ratio of C 2 to C 1 increases with exfoliation degree. It is advanced that the exfoliation degree can be quantitatively judged through this ratio.