钢芯铝块中铁铝比例和铝纯度的测定

利用钢铁和铝的熔点不同的特性,将钢芯铝块置于设定的温度下,使铝熔化与钢芯铁棒分离、冷却,分别称量钢芯铁棒和铝的重量计算铁和铝的比例。铝的纯度的测定,在熔化冷却的铝块上钻取试样,以氢氧化钠溶解酸化定容,取部分试液用氟化铵取代-EDTA 间接滴定法测定铝的含量。

Alcan公司的废旧铝饮料罐再生系统

位于美国纽约州 Oswego 市的 Alcan 轧制厂于1995年5月投产了一套新的现代化的废旧铝饮料罐(UBC)再生设备,称做'Ⅱ号再生系统',总投资2300万美元。从1995年投产开始,经过 Oswego 厂的管理与工程技术小组、AlcanInt Arvida 及原工程项目小组的积极改进不断地完善。

Segregation in fusion weld of 2219 aluminum alloy and its influence on mechanical properties of weld

Three kinds of welds were made using low frequency pulse current variable polarity tungsten inter gas （LPVPTIG） with argon shielding, direct current TIG （DCTIG） with helium shielding and high frequency pulse current variable polarity TIG （HPVPTIG） with argon shielding, respectively. It was found that macrosegregation bands with large amount of thick continuous eutectics and microporosities formed in the LPVPTIG weld due to the fluctuation of the pulse varied heat input. Only microsegregation existed in the DCTIG weld and HPVPTIG weld. However,the HPVPTIG weld had lower extent of Cu microsegregation since its welding speed was slower. The tensile results indicated that the mechanical properties of the weld decreased with the increase of the segregation extent of Cu and porosities, and LPVPTIG weld had lower tensile properties in the longitudinal direction than those in the transverse direction due to the macrosegregation bands.

Preparation and characterization of aluminum foams with ZrH_2 as foaming agent

Aluminum foams were fabricated by melt-based route using ZrH2 as a foaming agent. The factors which affected the foaming of aluminum foams during casting process were investigated. The powdered zirconium hydride with content of 0.6%-1.4% （mass fraction） was added to the molten pure aluminum and the foaming condition was controlled in a temperature range from 933 to 1 013 K, Ca amount of 1.5%-3.0% （mass fraction）, stirring time of 0.5-2.5 min and holding time of 1.5-4.0 min to obtain homogeneous aluminum foams. The fabricated aluminum foams were characterized by XRD, SEM and Image-pro plus. The mechanical properties of the aluminum foams with different relative density were tested. The result indicates that the foaming agent （ZrH2） is suitable for the preparation of small aperture aluminum foams with average pore diameter of 1 mm. Inter-metallic compounds and Al2O3 have effect on the melt viscosity. The aluminum foams experience linear elastic, platforms and densification process and had a higher efficiency of energy absorption.

Corrosion resistance of 91W-6Ni-3Fe refractory metal,TiAl compound and iron based alloys in molten aluminum

The corrosion behaviors of 91W-6Ni-3Fe （91W） refractory alloy, TiAl intermetallic compound and two types of iron based alloys （QT700 and H13 tool steel） in a liquid aluminum were investigated. Corrosion experiments or static immersion-tests were carried out in pure molten aluminum at 750 ℃. The surface micro-topographies, corrosion interfaces and phase compositions of the immersed samples were investigated by 3D optical microscopy, SEM, EDS and XRD. The results show that 91W exhibits the best corrosion resistance, followed by QT700, H13 and TiAl alloy, consequently. The corrosion mass loss of the four metallic materials adheres to parabolic criterion, and the corrosion rate trends to be stable after initial acceleration. The diffusion-reaction mechanism is proposed for the dissolution of materials in molten aluminum, and the diffusion process is the rate-determining step during the dissolution of 91W in molten aluminum, while the low activation energy for the reaction between TiAl-（TiAl3）-Al couple results in poor corrosion resistance of TiAl alloy in molten aluminum.

Separation of inclusions from aluminum melt using alternating electromagnetic field

Effects of processing variables such as frequency of imposed magnetic field, imposed magnetic flux density, processing time, diameter of inclusions, and value of r 1/δ on the electromagnetic separating(EMS) removal efficiency were analyzed theoretically. The higher the frequency, the wider the range of r 1/δ will be. Removal efficiency reaches the maximum while r 1/δ ranges from 1.5 to 2. And the experimental results on aluminum melt show that higher frequency and magnetic flux density make for higher removal efficiency, matching well with the theoretical results. When f is 15.6 kHz, B e is 0.1 T , and imposed time is 10 s, more than 80% inclusion particles with 6 μm diameter can be removed.

Melting purification process and refining effect of 5083 Al-Mg alloy

To improve the poor stability of casting process of Al alloy with high Mg content, which leads to poor final product quality, the melting purification process and the influences of the refiner on the microstructure and defect of 5083 alloy were studied. The results show that the optimized process for the rotary impeller degassing of 5083 alloy is as follows： a rotary speed of 250-400 r/min; a gas flow of 1.2-2.0 L/s, a refining time of 10-15 min. This optimized process can reduce the gas content in the solid alloy to 2× 10^-3 mL/g or lower. Due to the addition of grain refiner, the cast microstructure of 5083 alloy is refined. The Al-5Ti-IB wire shows the best refining effect among all the refiners. The refining effect is improved with the increase of grain refiner addition amount. And the refinement effects become stable when Ti content reaches 0.1% or higher. The surface crinkling defect of the billet can be easily found in the alloy refined with Al-5Ti-IB wire compared with the alloys refined with other refiners.

Fracture behavior of double-pass TIG welded 2219-T8 aluminum alloy joints under transverse tensile test

2219-T8 aluminum alloys were butt welded by the double-pass tungsten inert gas （TIG） arc welding process. The transverse tensile test of the joint showed that the fracture mainly occurred in the partially melted zone （PMZ）. Effects of the PMZ on the fracture behavior were systematically studied. Continuous intergranular eutectics were observed in the PMZ close to the fusion line. Away from the fusion line, the intergranular eutectics in the PMZ became discontinuous. The fracture morphology and the microhardness distribution of the joint showed that the PMZ was gradient material with different mechanical properties, which strongly affected the fracture process. It was observed that the crack initiated in the PMZ near the front weld toe, and propagated in the PMZ away from the fusion line. Then, the crack tip was blunt when it propagated into the PMZ with higher plasticity. Finally, the rest part of the joint was shear fractured.

MICROTHERM型高性能隔热材料

介绍了以最小颗粒直径由7纳米(nm)构成的球状极其超细二氧化硅颗粒为主要成分,再混合微粉状辐射热遮蔽材料和增加强度用无机纤维状物质,经加压成型制作的MICROTHERM(商品名)型高性能隔热材料的性能。探讨了这种隔热材料在民用蓄热取暖设备、工业用渗碳炉、烧结等热处理炉、玻璃窑、铝熔化保温炉、钢铁、水泥、石油化工、原子能发电、燃料电池、特殊用飞行自动记录仪、防火墙等方面的应用及其使用效果。

Electromagnetic separation of primary iron-rich phases from aluminum-silicon melt

The difference of conductivity between primary iron-rich phases and aluminum melt has been used to separate them by electromagnetic force (EMF) which is induced by imposing a direct electric current and a steady magnetic field in molten Al-Si alloy. Theoretical analysis and experiments on self-designed electromagnetic separation indicates that primary needle-like β phases are difficult to separate; while primary α iron-rich phases can be separated by electromagnetic separation. Primary iron-rich phases have been removed from the melt successfully when the molten metal flows horizontally through separation channel. The iron content is reduced from 1.13% to 0.41%.

A review of particulate-reinforced aluminum matrix composites fabricated by selective laser melting

Selective laser melting(SLM)is an emerging layer-wise additive manufacturing technique that can generate complex components with high performance.Particulate-reinforced aluminum matrix composites(PAMCs)are important materials for various applications due to the combined properties of Al matrix and reinforcements.Considering the advantages of SLM technology and PAMCs,the novel SLM PAMCs have been developed and researched in recent years.Therefore,the current research progress about the SLM PAMCs is reviewed.Firstly,special attention is paid to the solidification behavior of SLM PAMCs.Secondly,the important issues about the design and fabrication of high-performance SLM PAMCs,including the selection of reinforcement,the influence of parameters on the processing and microstructure,the defect evolution and phase control,are highlighted and discussed comprehensively.Thirdly,the performance and strengthening mechanism of SLM PAMCs are systematically figured out.Finally,future directions are pointed out on the advancement of high-performance SLM PAMCs.

Densification,microstructural features and tensile properties of selective laser melted AlMgSiScZr alloy from single track to block specimen

The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good corrosion resistance and high mechanical performance.In this paper,an Al-14.1Mg-0.47Si-0.31Sc-0.17Zr alloy was fabricated via SLM.The characteristics of single track at different process parameters,and the influence of hatch spacing on densification,microstructural features and tensile properties of block specimens were systematically studied.The hatch spacing has an influence on the overlap ratio of single track,and further affects the internal forming quality of printed specimen.At a laser power of 160 W and scanning speed of 400 mm/s,the densification of block specimen increased first and then decreased with the increase of hatch spacing.The nearly full dense specimen(98.7%)with a tensile strength of 452 MPa was fabricated at a hatch spacing of 80μm.Typical characteristics of dimple and cleavage on the tensile fracture of the AlMgSiScZr alloy showed the mixed fracture of ductility and brittleness.

Fatigue life prediction of gas metal arc welded crucifrom joints of AA7075 aluminium alloy failing from root region

Empirical relationship was developed to predict the fatigue life of gas metal arc welded （GMAW） cruciform joints failing from root region. High strength, age hardenable aluminium alloy of AA7075-T6 grade was used as the base material. The design of experiments concept was used to optimize the required number of fatigue testing experiments. Fatigue experiment was conducted in a servo hydraulic controlled fatigue testing machine under constant amplitude loading. The empirical relationship was developed. By using the developed empirical relationship, the fatigue life of GMAW cruciform joints failing from root region was predicted at 95% confidence level. The effect of cruciform joint dimensions on fatigue life was discussed in detail.

Microstructural evolution during semisolid state strain induced melt activation process of aluminum 7075 alloy

The effects of compression ratio on the microstructure evolution of semisolid 7075 Al alloy produced by the strain induced melt activation （SIMA） process were investigated. The samples were cold deformed by compression into the different heights up to 40% reduction. The isothermal holding treatments were carried out at 625 ℃ for predetermined time intervals. The results reveal that the average grain size is gradually reduced with the increase of the compression ratio. When the compression ratio surpasses 30%, the above descending trend is not as evident as that below 30% reduction. During the subsequent heat treatments, the recrystallization is induced in the deformed samples by the increasingly accumulated strain energy. The grain growth mechanisms and the microstructural coarsening of the SIMA processed 7075 Al alloy were discussed and confirmed.

Effect of platform temperature on microstructure and corrosion resistance of selective laser melted Al-Mg-Sc alloy plate

The Al-3.40Mg-1.08Sc alloy plates were manufactured by selective laser melting(SLM) at platform temperatures of 35 ℃ and 200 ℃, respectively, and the corrosion performance of them was studied along height direction. The results show that the corrosion resistance of the alloy plate built at platform temperature of 35 ℃ along height direction is basically the same due to a uniform microstructure;While the corrosion resistance of the alloy plate built at platform temperature of 200 ℃ along height direction is different. The evolution of microstructure and the distribution of secondary phases are investigated, and the results show that the Cu-rich phases in alloy play a key role on corrosion performance. At higher platform temperature, the cooling rate is relative slow and a certain degree of in situ ageing leads to the significantly different distribution of Cu-rich phases along grain boundary. Specimens built at the platform temperature of 200 ℃ are inclined to locate at the crossed grain boundary, rather than continuous segregation of Cu-rich phases along grain boundary that is built at platform temperature of 35 ℃. Therefore, the corrosion resistance of Al-3.40Mg-1.08Sc alloy plate manufactured at platform temperature of 200 ℃ is higher, and presents a gradually decreasing trend along height direction.

新型高纯气体提纯用吸附剂的研制

利用镓和铟在接近室温时能同铝形成共晶熔化的特点,在净化提纯装置中,使受净化气体通过鼓泡溶液时发生氧气和水蒸气与铝的反应,从而使烷类溶液鼓泡而达到气体的提纯。

Dissolution rate determination of alumina in molten cryolite-based aluminum electrolyte

Determination of dissolution rate of alumina is one of the classical problems in aluminum electrolysis. A novel method which can measure the dissolution rate of alumina was presented. Effect of factors on dissolution rate of alumina was studied intuitively and roundly using transparent quartz electrobath and image analysis techniques. Images about dissolution process of alumina were taken at an interval of fixed time from transparent quartz electrobath of double rooms. Gabor wavelet transforms were used for extracting and describing the texture features of each image. After subsampling several times, the dissolution rate of alumina was computed using these texture features in local neighborhood of samples. Regression equation of the dissolution rate of alumina was obtained using these dissolution rates. Experiments show that the regression equation of the dissolution rate of alumina is y=-0.000 5x^3＋0.024 0x^2-0.287 3x＋ 1.276 7 for Na3AIF6-AIF3-Al2O3-CaF2-LiF- MgF2 system at 920 ℃.

Electrochemical nucleation and growth of aluminum nanoparticles and leaf-like flat microstructures from reline deep eutectic solvent: Effect of temperature and angular speed of working electrode

The main objective of this work was to use reline deep eutectic solvent,containing Al(III)ions,for the electrochemical study of the nucleation and growth of aluminum onto a glassy carbon electrode at different temperatures and angular speeds(ω)of the working electrode.In order to fulfill this,electrochemical and surface characterization techniques were used.It was found that as temperature increased,the onset of the Al(III)DES reduction occurred at less negative potentials while the current peak of the voltammograms increased.These indicate that Al deposition thermodynamics and kinetics were favored.Practically,no anodic current was detected due to Al passivation by Al(OH)_(3)(s)andγ-Al_(2)O_(3)(s).Atω=0 r/min,the Al deposition chronoamperograms were analyzed by a theoretical model comprising Al 3D diffusion-controlled nucleation and growth and residual water reduction.However,those recorded at different angular speeds were analyzed with a theoretical model where adsorption−desorption and diffusion-controlled nucleation−growth occurred simultaneously.The deposits were characterized by SEM,EDX,XPS and XRD.Atω=0 r/min,formation of well distributed nanoparticles((78.1±9.5)nm)was observed,while atω=900 r/min the deposit was formed by multiple 10μm diameter leaf-like flat microstructures,composed by Al,Al(OH)_(3)(s)andγ-A2O3(s).

雾化装置的改进

位于塔斯马尼岛上的卡玛尔库(Camalco)铝粉厂是澳大利亚唯一的生产铝粉、铝球粒和铝粉糊的工厂。每年从BellBay附近的冶炼厂用3t坩埚运进约1万t熔化铝,倒入保温炉中。这一过程易于溅射和易于产生浮渣。现在已用虹吸系统取代这种倾倒系统。将直径200mm的铸铁管插入熔化的铝中,用真空系统将坩埚中的铝吸入保温炉。