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β沸石中铝的状态及归属 被引量:5
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作者 杨春 须沁华 《物理化学学报》 SCIE CAS CSCD 北大核心 1998年第2期169-173,共5页
用FTIR方法对β沸石中铝的状态进行了研究.结果表明,在脱除模板剂的β沸石中存在着三种状态的铝,即骨架铝、非骨架铝和过度态铝.铝的存在状态与平衡阳离子的性质密切相关,当平衡阳离子为高电子亲和性的H+时,β沸石的骨架发生扭曲... 用FTIR方法对β沸石中铝的状态进行了研究.结果表明,在脱除模板剂的β沸石中存在着三种状态的铝,即骨架铝、非骨架铝和过度态铝.铝的存在状态与平衡阳离子的性质密切相关,当平衡阳离子为高电子亲和性的H+时,β沸石的骨架发生扭曲而具有较大的张力,使得Al-O键断裂,铝经过渡态移出骨架,成为非骨架铝.当H+被Na+等离子取代后,骨架形变得以缓解,过渡态铝重又恢复骨架四面体配位,而阳离子态的非骨架铝物种则被交换进入溶液. 展开更多
关键词 Β沸石 铝状态 归属 FTIR 沸石
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我国南方某类稀土矿中铝的赋存状态 被引量:12
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作者 田君 池汝安 +2 位作者 朱国才 张志庚 徐盛明 《有色金属》 CSCD 2000年第3期58-60,共3页
以改进的连续分级提取方法,分别以去高于水、4%(NH4)2SO4水溶液、0.20mol·L-1HCl溶液、0.20mol·L-1 NH2OH·HCL+2.0mol·L-1HCl溶液、 0.33mol·... 以改进的连续分级提取方法,分别以去高于水、4%(NH4)2SO4水溶液、0.20mol·L-1HCl溶液、0.20mol·L-1 NH2OH·HCL+2.0mol·L-1HCl溶液、 0.33mol·L-1柠檬酸钠溶液和0.50mol·L-1NaOH溶液为提取剂,将南方某类稀土矿中可 提取的非晶态铝相应区分为:水溶态铝(Sol Al)、交换态铝(Ex Al)、吸附态无机羟基铝(Hy Al)、层间相铝(In Al)和非 晶态铝硅酸盐(Nc Al);剩下的为层状铝硅酸盐矿物态铝(Min Al)。其相应各状态铝含量分别为某中重稀土矿:2.06 ×10-5%,0.030%,0.24%,0.41%,1.19%,35.8%和62.4%。某重稀土矿:2.24×10-4%,5.73×10-3%,0.106%,0.577%,0.611%,11.3%, 85.1%。且Min Al>Nc Al>In Al>DCB Al>Hy Al>Ex Al>Sol Al.在稀土矿浸出工艺中,进入浸出液的是 Sol AI和Ex AI. 展开更多
关键词 稀土矿 赋存状态 连续分级提取
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利用核磁共振对矿物聚合材料中硅铝存在状态的研究 被引量:3
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作者 聂轶苗 夏茂辉 +2 位作者 牛福生 刘淑贤 李凤久 《材料导报(纳米与新材料专辑)》 EI 2009年第2期216-219,222,共5页
矿物聚合材料具有良好的性能,可用来代替部分硅酸盐水泥制品。利用变高岭石制备得矿物聚合材料制品,根据核磁共振测试分析,研究了该材料固化过程中硅、铝2种元素的存在状态。结果表明,变高岭石原料中的Si以Q^4(0Al)为主;随固化时间的延... 矿物聚合材料具有良好的性能,可用来代替部分硅酸盐水泥制品。利用变高岭石制备得矿物聚合材料制品,根据核磁共振测试分析,研究了该材料固化过程中硅、铝2种元素的存在状态。结果表明,变高岭石原料中的Si以Q^4(0Al)为主;随固化时间的延长,Q^4(0Al)的含量逐渐减少,而Q^2(1Al)和Q^4(2Al)开始出现,且其含量逐渐增加,然后Q^2(1Al)和Q^4(2Al)含量相对降低,Q^4(0Al)含量增加;变高岭石原料中的Al有四次配位也有六次配位,且六次配位的峰比四次配位的峰高而尖锐,随着反应的进行,四次配位的峰逐渐变高;固化28天制品中的Si主要以Q4(2Al)形式存在,Al则以四次配位为主。实验结果为进一步揭示矿物聚合材料的形成机理、改善制品的性能奠定了良好基础。 展开更多
关键词 矿物聚合材料 核磁共振 存在状态
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用固体核磁方法研究MCM-22分子筛中的Al状态 被引量:13
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作者 罗晴 程谟杰 邓风 《波谱学杂志》 CAS CSCD 北大核心 2001年第2期143-148,共6页
用固体NMR技术研究了新型分子筛MCM 2 2在不同水合状态下的2 7Al谱和1 H谱 .并用新的1 H/2 7Al双共振方法TRAPDOR对MCM 2 2分子筛的各种铝状态进行了研究 ,得到了样品脱水后B酸位 (Bronsted)、L酸位 (Lewis)以及非骨架Al(OH)的四极耦合... 用固体NMR技术研究了新型分子筛MCM 2 2在不同水合状态下的2 7Al谱和1 H谱 .并用新的1 H/2 7Al双共振方法TRAPDOR对MCM 2 2分子筛的各种铝状态进行了研究 ,得到了样品脱水后B酸位 (Bronsted)、L酸位 (Lewis)以及非骨架Al(OH)的四极耦合常数 . 展开更多
关键词 TRAPDOR 酸位 MCM-22分子筛 铝状态 固体核磁共振 四极耦合常数 MAS
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中低合金钢中全铝及状态铝的光谱分析
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作者 邹本仁 《齐厂科技》 1997年第4期32-35,共4页
本文应用DV-4直读光谱仪,探讨职低合金网中全铝及状态铝的测定方法,在试验中采用了二次积分曝光的方法,选择了最佳的一次曝光和二次曝光分析参数。绘制了酸溶铝和全铝的校正工作曲线,曲线的百分相关系数和均方误差都十分满意,... 本文应用DV-4直读光谱仪,探讨职低合金网中全铝及状态铝的测定方法,在试验中采用了二次积分曝光的方法,选择了最佳的一次曝光和二次曝光分析参数。绘制了酸溶铝和全铝的校正工作曲线,曲线的百分相关系数和均方误差都十分满意,经过分析精度的测试和分析结果的对照,完全可以用宇实际主产检验工作。应用此方法,分析数据准确、操作简便,可同时测定全铝、酸溶铝和酸学溶铝的含量。 展开更多
关键词 中低合金钢 合金钢 状态 光谱分析
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铝电解废旧阴极的工艺矿物学研究 被引量:2
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作者 袁威 金自钦 杨毅 《云南冶金》 2012年第6期64-68,共5页
研究了铝电解废旧阴极炭块的矿物学特征。使用X射线衍射仪查明了废旧阴极炭块的主要物质组成为碳、金属铝、氧化铝和冰晶石;用光学显微镜查明了其嵌布特征、嵌布粒度以及碳、铝的赋存状态。
关键词 废旧阴极 工艺矿物学 赋存状态
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以固体硅胶为硅源的β沸石晶化过程的研究 被引量:1
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作者 谢在库 张成芳 +2 位作者 陈庆龄 陈波 孔德金 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2000年第3期33-37,共5页
研究了以固体硅胶为硅源的 β沸石在 80 h以内晶化过程的变化规律。结果表明 ,晶化时间从 0增加到 80h,合成的 β沸石晶胞略有收缩 ,IR谱中 ,1 2 0 9cm- 1振动峰向高频方向位移 8cm- 1,1 0 75 cm- 1振动峰向低频方向位移 5 cm- 1。晶化... 研究了以固体硅胶为硅源的 β沸石在 80 h以内晶化过程的变化规律。结果表明 ,晶化时间从 0增加到 80h,合成的 β沸石晶胞略有收缩 ,IR谱中 ,1 2 0 9cm- 1振动峰向高频方向位移 8cm- 1,1 0 75 cm- 1振动峰向低频方向位移 5 cm- 1。晶化时间在 3 0 h内 ,β沸石存在 A与 B两种不同的结晶位。晶化时间大于 5 0 h后 ,β沸石出现典型的双环与开孔 IR特征峰。当晶化时间从 0增加到 80 h,2 9Si NMR谱表征的骨架硅铝比逐渐增大 ,2 7Al NMR谱表征的非骨架铝逐渐增多。 展开更多
关键词 沸石 晶化 晶粒粒度 结构 铝状态
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Numerical simulation of liquid aluminum leakage in casting process 被引量:2
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作者 Ling-yu KONG Xiao-zhen LIU +3 位作者 Zhong-ning SHI Tuo-fu LI Zhao-wen WANG Ai-min LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第1期297-305,共9页
A model was built to simulate liquid aluminum leakage during the casting process,including transient trough flow,orifice outflow,and spread,to prevent the explosion.A comparison between the simulation data and the the... A model was built to simulate liquid aluminum leakage during the casting process,including transient trough flow,orifice outflow,and spread,to prevent the explosion.A comparison between the simulation data and the theoretical calculation results verifies that the model has remarkable adaptability and high accuracy.Although the height of liquid aluminum in the mixing furnace and outlet radius are changed,the molten aluminum will not leak during the casting process.The aluminum in the trough moves forward in a wave-like motion and causes a leakage.The spread of the leaked aluminum resembles a long strip on the ground.The leakage amount and spread area of liquid aluminum increase with increasing the height of liquid aluminum in the mixing furnace. 展开更多
关键词 liquid aluminum leakage explosion leakage state spread pattern numerical simulation volume of fluid(VOF)model
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Influence of heat treatment conditions on bending characteristics of 6063 aluminum alloy sheets 被引量:6
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作者 Zhi-wen LIU Luo-xing LI +3 位作者 Jie YI Shi-kang LI Zhen-hu WANG Guan WANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第7期1498-1506,共9页
Bending deformation behaviors of solution treated(ST),natural aged(NA)and T6tempered6063aluminum alloy sheetswere studied by three-point bending tests.The changes of bending force,interior angle,bending radius and she... Bending deformation behaviors of solution treated(ST),natural aged(NA)and T6tempered6063aluminum alloy sheetswere studied by three-point bending tests.The changes of bending force,interior angle,bending radius and sheet thickness in thefillet region were analyzed by experimental measurements and numerical simulations.The results showed that the bendingcharacteristics were strongly dependent on the heat treatment conditions.The T6alloy sheets were bent more sharply and localplastic deformation occurred severely in the fillet region.However,the ST and NA alloy sheets exhibited relatively uniform bendingdeformation and large bending radius.The bending force of T6alloy was the highest,followed by the NA alloy and that of the STalloy was minimum.After unloading,as compared with the ST and NA alloys,the springback of T6alloys was markedly larger.Theaging time showed a positive sensitivity on the springback and non-uniform bending deformability.The bending characteristics areattributed to the combined effects of yield strength,yield ratio and coefficient of neutral layer. 展开更多
关键词 6063 aluminum alloy three-point bending heat treatment conditions bending characteristic yield ratio simulation
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XPS Investigation on Surface and Interface Electronic States of Alq_3/ITO
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作者 ZHANG Fu jia, ZHENG Dai shun, WANG Yan yong, HU Hai bing (Dept. of Phys., Lanzhou University, Lanzhou 730000, CHN) 《Semiconductor Photonics and Technology》 CAS 2001年第3期143-149,共7页
The surface and interface electronic states of tris (8 hydroxyquinoline) aluminum (Alq 3)/indium tin oxide (ITO) were measured and analyzed by X ray photoelectron spectroscopy (XPS). The results indicated that, in Alq... The surface and interface electronic states of tris (8 hydroxyquinoline) aluminum (Alq 3)/indium tin oxide (ITO) were measured and analyzed by X ray photoelectron spectroscopy (XPS). The results indicated that, in Alq 3 molecule, the binding energy ( E b) of Al atoms is 70.7 eV and 75.1 eV, corresponding to Al(O) and Al(Ⅲ), respectively; The binding energy of C is 285.8 eV, 286.3 eV, and 286.8 eV, corresponding to C of C-C group, C-O, and C-N bond, respectively. N is the main peak locating at 401.0 eV, corresponding to N atom of C-N=C. O atoms mainly bond to H atom, with the binding energy of 533.2 eV. As the sputtering time of Ar + ion beam increases, Al 2p , C 1s , N 1s , O 1s , In 3d 5/2 and Sn 3d 5/2 peaks slightly shift towards lower binding energy, and Al 2p , C 1s and N 1s peaks get weaker, which contributes to diffusing the oxygen, indium and tin in ITO into Alq 3 layer. 展开更多
关键词 XPS Alq 3/ITO Surface state Interface state
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Semi-solid near-net shape rheocasting of heat treatable wrought aluminum alloys 被引量:10
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作者 U.A.C URLE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第9期1719-1724,共6页
Flexibility of the CSIR-RCS, induction stirring with simultaneous air cooling process, in combination with high pressure die casting is successfully demonstrated by semi-solid rheocasting of plates performed on commer... Flexibility of the CSIR-RCS, induction stirring with simultaneous air cooling process, in combination with high pressure die casting is successfully demonstrated by semi-solid rheocasting of plates performed on commercial 2024, 6082 and 7075 wrought aluminum alloys. Tensile properties were measured for the above mentioned rheocast wrought aluminum alloys in the T6 condition. The results showed that tensile properties were close to or even in some cases exceeded the minimum specifications. The yield strength and elongation of rheocast 2024-T6 exceeded the minimum requirements of the wrought alloy in the T6 condition but the ultimate tensile strength achieved only 90% of the specification because the Mg content of the starting alloy was below the commercial alloy specification. The strengths of rheocast 6082-T6 exceeded all of the wrought alloy T6 strength targets but the elongation only managed 36% of the required minimum due to porosity, caused by incipient melting during solution heat treatment, and the presence of fine intermetallie needles in the eutectic. The yield strength of rheocast 7075 exceeded the required one and the ultimate tensile strength also managed 97% of the specification; while the elongation only reached 46% of the minimum requirement also due to incipient melting porosity caused during the solution heat treatment process. 展开更多
关键词 high pressure die casting (HPDC) aluminum alloys as-cast condition T6 treatment incipient melting
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High Density Plasma Nitriding of Al-Cu Alloys for Automotive Parts
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作者 Tatsuhiko Aizawa Shinji Muraishi Yoshio Sugita 《Journal of Physical Science and Application》 2014年第4期255-261,共7页
Duralumin alloys have been utilized as structural components and parts for aircrafts, train-cars and so forth. Their high specific strength was attractive to those applications; however, their little corrosion resista... Duralumin alloys have been utilized as structural components and parts for aircrafts, train-cars and so forth. Their high specific strength was attractive to those applications; however, their little corrosion resistance and low wear endurance became a fatal demerit in practical applications. In order to overcome these issues of high strength aluminum alloys, high density plasma nitriding is proposed as an effective surface treatment for duralumin. This process has a capability to control the RF- and DC-plasmas independently for nitriding. This enables us to temporally control and describe the plasma state by in-situ plasma diagnosis. This plasma diagnosis was instrumented to search for optimum processing condition to plasma nitriding the duralumin alloys of type A2011. Both type A2011 aluminum alloy plates and pipes were employed to describe the inner nitriding behavior for hardening the duralumin alloys by the present plasma nitriding. 展开更多
关键词 Duralumin alloys A2011 high density plasma nitrding AIN precipitation HARDENING PLATES PIPES heat sink.
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Combustion characteristics of nanofluid fuels in a half-opening slot tube 被引量:2
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作者 LIU GuanNan LIU Dong 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第7期1075-1087,共13页
Combustion characteristics of nanofluid fuels containing aluminum nanoparticles were investigated in half-opening slot tubes from the fundamental view. The effects of particle loading rates(0.25% and 2.5% by weight), ... Combustion characteristics of nanofluid fuels containing aluminum nanoparticles were investigated in half-opening slot tubes from the fundamental view. The effects of particle loading rates(0.25% and 2.5% by weight), type of base fuels(ethanol and butanol),and fuel flow rates(0.2, 0.6, and 1 mL/min) were studied in details. The combustion characteristics of the nanofluid fuels and pure based fuels were also examined to provide a comparison. Flame was unstable with reignition, stable state, nearly extinguishment repeatedly at low flow rate. At medium flow rate, flame height was increased and flame tended to be stable. At high flow rate,flame became unstable and was disturbed by the droplet forming and dripping significantly. Al atoms inside the oxide layer should be melted before the particles combustion, while Al oxide layer should be melted before the particles aggregates combustion. The effects of particles on the combustion characteristics, especially on the evaporation rate of base fuel, were discussed. The reasons for various combustion phenomena of nanofluid fuels were given, which can provide the useful guidance for the experimental research and practical applications of nanofluid fuels. 展开更多
关键词 nanofluid fuel combustion aluminum ethanol butanol
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Effect of the geometric shapes of specimens on impact tensile tests 被引量:2
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作者 Wei-fang XU Xi-cheng HUANG +2 位作者 Zhi-ming HAO Yang WANG Yuan-ming XIA 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2010年第10期817-821,共5页
The geometric shapes of specimens are important in impact tensile tests because geometric shapes determine the stress states of the specimens, and precise geometric shapes can obtain proper material properties without... The geometric shapes of specimens are important in impact tensile tests because geometric shapes determine the stress states of the specimens, and precise geometric shapes can obtain proper material properties without non-material factors. The aim of this study was to investigate the 1D form of the stress by changing the length-to-diameter (L/D) ratios of specimens. The experiments were carried out on a split Hopkinson tensile bar (SHTB)-rotating disk indirect bar-bar tensile impact apparatus. The L/D ratios of the LY12CZ specimens used in the test ranged from 1 to 5. Results show that the specimens can be used to obtain exact parameters of materials under the proposed conditions when the L/D ratio is greater than 2. This is because the longer length will reduce or eliminate the effects of the interfaces. 展开更多
关键词 Impact tensile Split Hopkinson tensile bar (SHTB) Length-to-diameter (L/D) ratios
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