Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were...Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were reanalyzed. The new quantitative analysis results show that when cryolite ratio（CR） is less than 2, AlF4- is the dominant anion in the melts, and its mole fraction is about 0.70 for melts with CR=1.5 and 0.50 for melts with CR=2. When CR is more than 2.5, the mole fraction of AlF6^3- is relatively large, which is around 0.45 for melts with CR=2.5. Ionic structure of Na3AlF6-Al2O3 melts was investigated by UV-Raman spectroscopy. Octahedral AlF6^3- and tetrahedral AlF4- are proved to exist with possible partial replacement of F- by O^2-. Al2O2F4^2- with a large scattering coefficient also exists in the melts in which alumina concentration is more than 4% （mass fraction）. The increase of temperature causes blue-shift of the bands in the Raman spectra.展开更多
The Navier-Stokes equation with the "k-ε" two-equation turbulence model was employed to describe three-dimension flow of melt in aluminum electrolysis cells. For a 160 kA cell with two current risers, the s...The Navier-Stokes equation with the "k-ε" two-equation turbulence model was employed to describe three-dimension flow of melt in aluminum electrolysis cells. For a 160 kA cell with two current risers, the source, i.e. the electromagnetic force, in the momentum equations was solved based on the simulation results of magnetic and temperature fields. Numerical simulation on the three-dimension steady-state flow of melt was carried out. The results obtained about the velocities of molten metal on different planes, the metal/bath interface shape and the electromagnetic force distribution, were analyzed. An iron rod dissolution technique, which is based on the rate of dissolution of iron rods inserted into the melt, was used to measure the velocities of metal pad. The simulation and measurement show that there are two interaction vortexes in horizontal direction. The predictions are in well agreement with the measured results for flow pattern and velocities. It is worthwhile that in the three-dimension simulation, there is also a little change of metal velocities from level to level due to the difference of horizontal current on each level.展开更多
The standard k-ε model was adopted to simulate the flow field of molten metal in three aluminum electrolysis cells with different anode risers. The Hartman number, Reynolds number and the turbulent Reynolds number of...The standard k-ε model was adopted to simulate the flow field of molten metal in three aluminum electrolysis cells with different anode risers. The Hartman number, Reynolds number and the turbulent Reynolds number of molten metal were calculated quantitatively. The turbulent Reynolds number is in the order of 103 , and Reynolds number is in the order of 104 if taking the depth of molten metal as the characteristic length. The results show that the molten metal flow is the turbulence of high Reynolds number, the turbulent Reynolds number is more appropriate than Reynolds number to be used to describe the turbulent characteristic of molten metal, and Hartman number displays very well that electromagnetic force inhibits turbulent motion of molten metal.展开更多
基金Project (51004034) supported by the National Natural Science, ChinaProject(N090302009) supported by the Fundamental Research Funds for the Central Universities, China
文摘Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were reanalyzed. The new quantitative analysis results show that when cryolite ratio（CR） is less than 2, AlF4- is the dominant anion in the melts, and its mole fraction is about 0.70 for melts with CR=1.5 and 0.50 for melts with CR=2. When CR is more than 2.5, the mole fraction of AlF6^3- is relatively large, which is around 0.45 for melts with CR=2.5. Ionic structure of Na3AlF6-Al2O3 melts was investigated by UV-Raman spectroscopy. Octahedral AlF6^3- and tetrahedral AlF4- are proved to exist with possible partial replacement of F- by O^2-. Al2O2F4^2- with a large scattering coefficient also exists in the melts in which alumina concentration is more than 4% （mass fraction）. The increase of temperature causes blue-shift of the bands in the Raman spectra.
文摘The Navier-Stokes equation with the "k-ε" two-equation turbulence model was employed to describe three-dimension flow of melt in aluminum electrolysis cells. For a 160 kA cell with two current risers, the source, i.e. the electromagnetic force, in the momentum equations was solved based on the simulation results of magnetic and temperature fields. Numerical simulation on the three-dimension steady-state flow of melt was carried out. The results obtained about the velocities of molten metal on different planes, the metal/bath interface shape and the electromagnetic force distribution, were analyzed. An iron rod dissolution technique, which is based on the rate of dissolution of iron rods inserted into the melt, was used to measure the velocities of metal pad. The simulation and measurement show that there are two interaction vortexes in horizontal direction. The predictions are in well agreement with the measured results for flow pattern and velocities. It is worthwhile that in the three-dimension simulation, there is also a little change of metal velocities from level to level due to the difference of horizontal current on each level.
文摘The standard k-ε model was adopted to simulate the flow field of molten metal in three aluminum electrolysis cells with different anode risers. The Hartman number, Reynolds number and the turbulent Reynolds number of molten metal were calculated quantitatively. The turbulent Reynolds number is in the order of 103 , and Reynolds number is in the order of 104 if taking the depth of molten metal as the characteristic length. The results show that the molten metal flow is the turbulence of high Reynolds number, the turbulent Reynolds number is more appropriate than Reynolds number to be used to describe the turbulent characteristic of molten metal, and Hartman number displays very well that electromagnetic force inhibits turbulent motion of molten metal.
