铝碳陶瓷材料的摩擦磨损性能

以铝碳陶瓷材料作为研究对象,利用摩擦磨损实验机研究了铝碳陶瓷材料在干摩擦和固体润滑两种状态下的摩擦磨损性能,并采用有限元方法分析了两种摩擦状态下的应力分布情况。实验结果表明,干摩擦及润滑状态下试样的滑动摩擦系数随载荷的增加而减少;并且润滑状态下滑动摩擦系数仅是干摩擦状态下滑动摩擦系数的1/2左右;有限元分析结果表明,铝碳陶瓷材料干摩擦状态下最大剪切应力大于最大正应力,试样表面容易发生由微断裂引起的磨粒磨损。固体润滑状态下的接触应力很小,这是因为固体润滑状态下主要发生的是固体润滑涂层材料之间的内摩擦。

无压烧结制备Ti–Al–C系三元层状陶瓷

以TiC粉、Al粉、Ti粉为原料,采用无压烧结工艺制备高纯Ti–Al–C三元层状陶瓷,探究了烧结温度、烧结时间、烧结助剂等对Ti–Al–C系三元层状陶瓷制备的影响。结果表明:在一定范围内提高烧结温度和烧结时间能减少杂质相的产生,不添加助剂情况下在1 400℃下保温3 h能得到80%(质量分数)以上的Ti–Al–C系三元层状陶瓷,该条件下掺入少量Si粉或Sn粉能得到高纯Ti–Al–C系三元层状陶瓷。TiC、Al、Ti和Si质量比为2.0:1.2:1.0:0.1的原料粉末在1 400℃保温3 h能得到纯度99%以上的Ti3AlC2陶瓷,TiC、Al、Ti和Sn质量比为2.0:1.2:1.0:0.1与TiC、Al、Ti和Sn质量比为1.0:1.2:1.0:0.1的原料粉末在1 400℃保温3 h均能制备出纯度99%的以Ti3AlC2为主晶相的Ti3AlC2/Ti2AlC复相陶瓷。

Ultra-fast densification of CNTs reinforced alumina based on combustion reaction and quick pressing

An ultra-fast densification method based on high heating rate from the combustion reaction for producing carbon nanotubes （CNTs） reinforced alumina ceramics is reported. The heat generated by combustion reaction is adopted to act as a high temperature source to the sample, which results in a heating rate of 1660℃/min of the sample. Then a great mechanical pressure is applied to the sample when the sample gets the expected temperature. The densification process is finished in several minutes. The results indicate that the densification method is beneficial to protect the CNTs from destruction and creates good interracial combination between the nanotubes and the matrix. With the addition of 1 wt% CNTs, the fracture toughness of the ceramics prepared increases about 50%.