粉末冶金铝钨合金热变形行为与应变补偿型本构模型

采用Gleeble-1500热模拟实验机,在变形温度450-570℃、应变速率0.001-1s-1、最大变形量60%的变形条件下,对铝钨合金粉末冷、热压制备的试样进行等温恒应变速率压缩试验,研究了该粉末合金的高温流动应力变化规律,建立了应变补偿的材料热变形Arrhenius本构关系模型,并将经模型计算得到的流动应力结果与热模拟实验数据进行了对比,结果比较吻合。考虑应变对流动应力的影响,确定了峰值应力、变形温度和应变速率之间的关系,并获得了变形激活能和本构方程中材料常数随应变的变化规律。

铝钨合金高温流变行为及神经网络本构关系模型

采用Gleeble-1500热模拟实验机研究铝钨合金在变形温度为450℃-540℃、应变速率为0.001s-1-1s-1下单道次压缩过程的高温流变行为。基于BP神经网络建立铝钨合金本构关系模型。在该模型中,输入变量为应变、应变速率和变形温度,输出变量为流变应力。与传统方法相比,该本构关系模型的测试数据可以为描述整个变形过程提供一个很好的代表性,也为开发铝钨合金本构关系提供方便和有效的途径。

铝钨合金挤压数值模拟与试验研究

提出热挤压方法挤压铝钨合金棒材,并建立材料力学模型。利用Deform-3D软件模拟铝钨合金在不同挤压参数下的挤压过程,获得等效应力分布、等效应变分布和载荷变化规律。使用6 300 kN四工位组合快速成形油压机进行试验并与模拟结果对比分析,确立铝钨合金热挤压工艺。采用电子万能弯曲试验机对成形件力学性能进行分析。结果表明,铝钨合金经过热挤压成形,材料的力学性能得到提升。

电感耦合等离子体原子发射光谱法测定铝钨合金中钨

以盐酸和过氧化氢溶解样品,电感耦合等离子体原子发射光谱法（ICP-AES）测定了铝钨合金中钨.着重研究样品的溶解条件,确定了先加入盐酸至铝基质颗粒反应完全后再加入10 mL过氧化氢的试剂加入顺序.过氧化氢用量随着样品中钨含量的不同而不同,但对于溶解钨含量为0.10％～15％铝钨合金样品,过氧化氢加入量在100mL以下对测定结果无影响.钨的质量浓度在500mg/L内校准曲线的线性关系良好,相关系数为0.999 5.基体铝对测定的影响采用基体匹配方法消除.方法应用钨质量分数不同的铝钨中间合金分析,钨的测定值与辛可宁重量法测定值一致,回收率在98％～102％之间,相对标准偏差（RSD,n=9）为2.8％～5.1％.方法能满足科研与生产的快速检测需要.

铝钨粉末合金涡旋定盘挤压成形工艺研究

利用Gleeble-1500热模拟机测试了钨铝粉末合金在变形温度为420、450、480、510、540℃,应变速率分别为0.001、0.01、0.1、1 s-1条件下的流变力学行为。通过有限元软件对涡旋定盘挤压成形过程进行了数值模拟,确定了合理的挤压成形工艺,并通过试验进行了验证。比较了零件不同部位的微观组织,最终获得了合格的挤压件。

GH3536高温合金表面等离子喷涂镍铝钨涂层的微观结构与性能

采用大气等离子喷涂在GH3536高温合金基体上制备了NiAlW涂层,对其显微结构、物相组成、孔隙率、结合强度、显微硬度和高温摩擦磨损行为进行了表征。结果表明,由于大气等离子喷涂NiAlW粉末颗粒熔化充分,因此涂层截面呈典型的层状结构且较致密,与基体结合良好,在600°C下的耐磨性能明显优于基体。

铝-钨粉末合金涡旋定盘热挤压成形工艺研究

试验研究了铝-钨合金粉末的冷压、热压制坯成形工艺,确定主要挤压工艺参数。该合金涡旋定盘挤压件致密度达到99%左右。利用Gleeble-1500热模拟机测试了该合金在变形温度为450℃~540℃,应变速率为（10-3~1）s-1条件下的流变力学行为。采用Fields-Backofen本构模型实现了对该材料应力-应变曲线的拟合。通过引入一个＂软化因子＂,更好地描述了变形温度、应变速率和应变对流变应力的影响,进一步完善了流变应力本构模型。通过有限元模拟对涡旋定盘挤压件成形进行数值模拟,确定合理的挤压成形工艺,并通过试验进行验证,最终获得了合格的涡旋定盘挤压件。

钨含量对钴-铝-钨合金中γ′强化相的影响

为了解元素钨含量对新型钴-铝-钨合金中γ′强化相的影响,用燃烧合成法制备了不同钨含量的合金,通过SEM、XRD、EPMA、DSC等方法分析了钨含量对合金中γ′强化相形貌、数量以及稳定性的影响。结果表明:钴-铝-钨合金显微组织是由富钴基体及其γ′-Co3(Al,W)强化相和少量碳化物组成;γ′-Co3(Al,W)强化相比Co3Al具有更好的稳定性,随着钨含量的增加,合金的液相线温度升高,强化相的数量也增加;当钨质量分数为26.36%时合金中γ′强化相的稳定性最好。

铝钨粉末合金挤压成形工艺研究

设计了铝钨粉末合金冷压、热压模具,并给出各项模具参数。确定了铝钨粉末合金冷压、热压过程中的压制压力、加压速度、保温时间以及挤压温度等工艺参数,挤压件致密度达到99%以上。研究了变形温度450～570℃、应变速率0.001～1s^-1、最大变形程度60%的条件下铝钨粉末合金热压缩的流动应力变化规律,并结合金相图进行了组织分析。结果能为制定铝钨合金塑性成形工艺提供理论依据。

铝钨粉末合金挤压成形与本构模型的建立研究

本文针对铝钨粉末合金挤压成形与本构模型的建立,结合理论实践,先分析了铝钨粉末合金发展现状,接着探讨了铝钨粉末合金挤压成型的关键技术,最后研究了本构模型的建立方法。研究结果表明,铝钨粉末合金具有良好的性能,应用范围比较广,但制备过程比较复杂,需要严格控制挤压成型过程并建立本构模型,才能最大限度上提升铝钨粉末合金制备性能,满足使用的要求,值得高度重视。

硫氰酸盐分光光度法测定铝钼钨钛合金中钼、钨

试样经过硫、磷混酸及硝酸加热溶解后,在硫酸介质中以氯化亚锡还原钼,不同质量的钼与硫氰酸盐形成橙色络合物,符合朗伯比尔定律。在先弱碱后强盐酸环境中,以氯化亚锡还原钼,以三氯化钛再次还原钼,并还原钨,消除钼显色干扰,同时使不同含量的钨与硫氰酸盐形成的黄绿色络合物,符合朗伯比尔定律。

Fracture behavior of double-pass TIG welded 2219-T8 aluminum alloy joints under transverse tensile test

2219-T8 aluminum alloys were butt welded by the double-pass tungsten inert gas （TIG） arc welding process. The transverse tensile test of the joint showed that the fracture mainly occurred in the partially melted zone （PMZ）. Effects of the PMZ on the fracture behavior were systematically studied. Continuous intergranular eutectics were observed in the PMZ close to the fusion line. Away from the fusion line, the intergranular eutectics in the PMZ became discontinuous. The fracture morphology and the microhardness distribution of the joint showed that the PMZ was gradient material with different mechanical properties, which strongly affected the fracture process. It was observed that the crack initiated in the PMZ near the front weld toe, and propagated in the PMZ away from the fusion line. Then, the crack tip was blunt when it propagated into the PMZ with higher plasticity. Finally, the rest part of the joint was shear fractured.

Effect of welding processes on AA2219 aluminium alloy joint properties

AA2219 aluminium alloy square butt joints without filler metal addition were fabricated using gas tungsten arc welding （GTAW）, electron beam welding （EBW） and friction stir welding （FSW） processes. The effects of three welding processes on the tensile, fatigue and corrosion behaviour were studied. Microstructure analysis was carried out using optical and electron microscopes. The results show that the FSW joints exhibit superior tensile and fatigue properties compared to EBW and GTAW joints. It is also found that the friction stir welds show lower corrosion resistance than EB and GTA welds. This is mainly due to the presence of finer grains and uniform distribution of strengthening precipitates in the weld metal of FSW joints.

Microstructure analysis and mechanical characteristics of tungsten inert gas and metal inert gas welded AA6082-T6 tubular joint: A comparative study

The present study is aimed to compare the microstructure characteristics and mechanical properties of AA6082 in T6 condition of tubular joints fabricated by tungsten inert gas welding （TIG） and metal inert gas welding （MIG） processes. The effect of welding processes was analysed based on optical microscopy image, tensile testing, and Vickers micro-hardness measurements. The results showed that the tensile strengths of the TIG-welded joints were better than those of the MIG-welded joints, due to the contribution of fine equiaxed grains formation with narrower spacing arms. In terms of joint efficiency, the TIG process produced more reliable strength, which was about 25% higher compared to the MIG-joint. A significant decay of hardness was recorded in the adjacent of the weld bead zone, shown in both joints, related to phase transformation, induced by high temperatures experienced by material. A very low hardness, which was about 1.08 GPa, was recorded in the MIG-weldcd specimens. The extent of the heat-affected-zone （HAZ） in the MIG-welded joints was slightly wider than those of the TIG-welded specimens, which corresponded with a higher heat input per unit length.

Mechanical behaviors of NiAl-Cr(Mo)-based near eutectic alloy with Ti, Hf, Nb and W additions

Effects of Ti, Hf, Nb and W alloying elements addition on the microstructure and the mechanical behaviors of NiAl-Cr（Mo） intermetallic alloy were investigated by means of XRD, SEM, EDX and compression tests. The results show that Ni-31Al-30Cr-4Mo-2（Ti, Hf, Nb, W） alloy consists of four phases： NiAl, ？？Cr solid solution, Cr2Nb and Ni2Al（Ti, Hf）. The mechanical properties are improved significantly compared with the base alloy. The compression yield strength at 1 373 K is 467 MPa and the room temperature compression ductility is 17.87% under the strain rate of 5.56？？0-3 s-1, due to the existence of Cr2Nb and Ni2Al（Ti, Hf） phases for strengthening and Ti solid solution in NiAl matrix and coarse Cr（Mo, W） solid solution phase at cellular boundaries for ductility. The elevated temperature compression deformation behavior of the alloy can be properly described by power-law equation： ε=0.898 σ8.47exp[-615/（RT）].

Microstructural evolution and its effect on mechanical properties in different regions of 2219-C10S aluminum alloy TIG-welded joint

Microstructural evolution and its effect on mechanical properties in different regions of 2219-C10S aluminum alloy tungsten inert gas(TIG)welded joint were analyzed in detail.In weld zone(WZ),α+θeutectic structure formed at grain boundaries with no precipitates inside the grains.In partially melted zone(PMZ),symbiotic eutectic or divorced eutectic formed at grain boundaries and needle-likeθ′phases appeared in the secondary heated zone.In over aged zone(OAZ),the coarsening and dissolution ofθ′phases occurred and mostθ′phases transformed intoθphases.In general heat affected zone(HAZ),θ′phases coarsened.Factors such as the strengthening phases,the grain size,the Cu content in matrix and the dislocation density can affect the mechanical properties in different regions of the joint.Moreover,a model describing the relationship between mechanical properties of the material and the volume fraction of precipitates,the average diameter of precipitates and the concentration of soluble elements was proposed.

Effect of post weld heat treatment on microstructure and mechanical properties of gas tungsten arc welded AA6061-T6 alloy

Double-V butt TIG welding process was performed on two plates of AA6061-T6 using ER5356 filler. The microstructure,mechanical and nanomechanical properties of the joint were evaluated in as-welded and after post weld heat treatment (PWHT) usingXRD, FESEM, EBSD, nanoindentation and tensile tests. The results show that PWHT led to microstructural recovery of the heataffected zone (HAZ) in addition to the appearance of β-phase (Al3Mg2) at the grain boundaries of weld zone. The hardness (Hnano) inall zones increased after PWHT while the elastic modulus (Enano) was improved from 69.93 GPa to 81 GPa in weld area. All resultsindicate that PWHT has created a homogenous microstructure in the weld zone in addition to outstanding improvement inmechanical properties for the weld zone which surpass the base metal.

Al-W二元合金机械合金化扩展固溶度研究

用行星式高能球磨机对成分为Al1-xWx(x =0 .1 ,0 .2 ,0 .5 ,0 .9)的粉末进行了不同时间的研磨 ,用X射线衍射法和电镜对球磨后的粉末的结构和形貌进行了研究 .实验结果表明 ,球磨后Al在W中的固溶度大大扩展 ,可超过 5 0 % (原子分数 ) .用嵌入原子理论和机械合金化扩展固溶度的理论对实验结果进行了分析 。

Electronic Structure ofTiAl-2M(M=V,Nb,Ta,Cr,Mo,W,Mn) Alloy

The electronic structures of TiAl-2M(M=V, Nb, Ta, Cr, Mo, W,Mn) alloy have been investigated using EHT band calculation method. Their bandstructures and average prperties have been obtained. The results show that doping thetransition metal elements can effectively change the band structure and enable the alloysystem to show the stronger metallic feature. The dopants of V, Cr and Mn increase s-orbital component of Ti and Al in bonding orbital, therefore, there is more sphericalelectronic clound and weakly directional bonds in the crystal, which improve the duictil-ity of the alloy, Nb or Ta makes stronger bonding with Ti and Al, which improvestrength and oxidation resistance of the alloy.