KTiOPO_(4)晶体中Cr离子的光谱特性

通过实验测得ＫＴｉＯＰＯ４：Ｃｒ晶体的室温吸收谱、激发谱，室温和液氮温度下激光诱导荧光谱及各发射带的荧光寿命，进而计算得到了Ｃｒ离子的晶场参数、吸收截面、发射截面及量子效率。结果表明Ｃｒ离子受晶场的影响较弱，但具有较强的电子－声子耦合。室温下较大的无辐射跃迁几率导致了较低的量子效率。实验上没有观察到四配位Ｃｒ离子的光谱特征。最后，对上述结果结合Ｃｒ离子配位情况进行了讨论。

Pressure Effects on Spectra of Tunable Laser Crystal GSGG： Cr^3＋ IV： Pressure—Induced Shifts of R1 Line, R2 Line, and U Band at 300 K

By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R1 line, R2 line, and U band of GSGG:Cr3+ at 300 K have been calculated, respectively. The calculated results are in good agreement with all the experimental data. Their physical origins have also been explained. It is found that the mixing-degree of and base-wavefunctions in the wavefunctions of R1 level of GSGG:Cr3+ at 300 K is remarkable under normal pressure, and the mixing-degree rapidly decreases with increasing pressure. The change of the mixing-degree with pressure plays a key role not only for the 'pure electronic' PS of R1 line and R2 line but also the PS of R1 line and R2 line due to EPI. The pressure-dependent behaviors of the 'pure electronic' PS of R1 line (or R2 line) and the PS of R1 line (or R2 line) due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R1 line (or R2 line). In the range of about 15 kbar ~ 45 kbar, the mergence and/or order-reversal between levels and levels take place, which cause the fluctuation of the rate of PS for with pressure. At 300 K, both the temperature-dependent contribution to R1 line (or R2 line or U band) from EPI and the temperature-independent one are important.