An organic-magnesium complex conversion(OMCC)coating on AZ91D magnesium alloy was obtained by treating in a solution containing organic compounds.SEM,FESEM and XPS were used to examine the surface morphology,thickness...An organic-magnesium complex conversion(OMCC)coating on AZ91D magnesium alloy was obtained by treating in a solution containing organic compounds.SEM,FESEM and XPS were used to examine the surface morphology,thickness and structure of the conversion coatings.The results show that the continuous and uniform conversion coating is deposited on AZ91D alloy and the main component of the coatings is organic compound containing benzene ring,which forms a chemical bond with magnesium.The polarization measurement and salt spray test show that the corrosion resistance of the conversion coating is much higher than that of traditional chromate conversion coating.展开更多
An ODS (oxide dispersion strengthened) steels are one of the most notable structural materials being developed for future high-temperature energy production technologies, and several studies have been devoted to the...An ODS (oxide dispersion strengthened) steels are one of the most notable structural materials being developed for future high-temperature energy production technologies, and several studies have been devoted to the development of ODS materials for such applications. However, only little paper focuses on corrosion behavior of F/M (ferritic martensictic) and ODS steels. The corrosion behavior of 11% Cr F/M steel and 15% Cr ODS steel were evaluated using electrochemical methods in borate buffer and 1 kmol m"3 HNO3 with or without NaCI and also in boiling 60% nitric acid. The corrosion resistance results clearly indicated the influences of steel alloys composition and chloride ions. The XPS (X-ray photo-electron spectroscopy) results of the pre-passivated surface revealed that the oxide formed were composed predominantly of Fe203 along with Cr203, and Y203 layers in ODS steel. The corrosion rate measured in boiling nitric acid for 48 h for both the steels shows high corrosion rate in boiling condition. The SEM (scanning electron microscopy) observation of the pit morphology after corrosion tests appears with shallow pit in both steel surfaces The corrosion degradation behavior in relation to the composition of the passive oxide film in different electrolytic solutions is discussed in this paper.展开更多
基金Project(50871046)supported by the National Natural Science Foundation of ChinaProject(2007KZ09)supported by the 2007 Scienceand Technology Support Plan of Changchun City,China
文摘An organic-magnesium complex conversion(OMCC)coating on AZ91D magnesium alloy was obtained by treating in a solution containing organic compounds.SEM,FESEM and XPS were used to examine the surface morphology,thickness and structure of the conversion coatings.The results show that the continuous and uniform conversion coating is deposited on AZ91D alloy and the main component of the coatings is organic compound containing benzene ring,which forms a chemical bond with magnesium.The polarization measurement and salt spray test show that the corrosion resistance of the conversion coating is much higher than that of traditional chromate conversion coating.
文摘An ODS (oxide dispersion strengthened) steels are one of the most notable structural materials being developed for future high-temperature energy production technologies, and several studies have been devoted to the development of ODS materials for such applications. However, only little paper focuses on corrosion behavior of F/M (ferritic martensictic) and ODS steels. The corrosion behavior of 11% Cr F/M steel and 15% Cr ODS steel were evaluated using electrochemical methods in borate buffer and 1 kmol m"3 HNO3 with or without NaCI and also in boiling 60% nitric acid. The corrosion resistance results clearly indicated the influences of steel alloys composition and chloride ions. The XPS (X-ray photo-electron spectroscopy) results of the pre-passivated surface revealed that the oxide formed were composed predominantly of Fe203 along with Cr203, and Y203 layers in ODS steel. The corrosion rate measured in boiling nitric acid for 48 h for both the steels shows high corrosion rate in boiling condition. The SEM (scanning electron microscopy) observation of the pit morphology after corrosion tests appears with shallow pit in both steel surfaces The corrosion degradation behavior in relation to the composition of the passive oxide film in different electrolytic solutions is discussed in this paper.