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树枝状银微纳结构的表面增强拉曼散射效应研究 被引量:2
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作者 陈韶云 王圆 +3 位作者 刘辉 胡成龙 刘学清 刘继延 《分析化学》 SCIE EI CAS CSCD 北大核心 2017年第3期374-380,共7页
利用两电极电化学沉积法制备出一种树枝状银微纳结构基体。扫描电子显微镜(SEM)的表征结果证实所制备的银基体呈现出完整的树枝状结构,具有对称性的树枝和树干,且树叶清晰可见。实验结果表明,树枝状银微纳结构的表面增强拉曼散射(Surfac... 利用两电极电化学沉积法制备出一种树枝状银微纳结构基体。扫描电子显微镜(SEM)的表征结果证实所制备的银基体呈现出完整的树枝状结构,具有对称性的树枝和树干,且树叶清晰可见。实验结果表明,树枝状银微纳结构的表面增强拉曼散射(Surface-enhanced Raman scattering,SERS)可以检测到超低浓度的罗丹明6G(Rhodamine 6G,R6G,10^(-10)mol/L)光谱信号,即树枝状银微纳结构作为SERS基体表现出较好的灵敏性;当R6G的浓度在10^(-5)~10^(-10)mol/L范围依次降低一个数量级时,谱带610 cm^(-1)处的拉曼散射强度的相对标准偏差分别为12.1%,12.0%,11.7%,10.9%,13.2%和14.3%,表明所制备银基体的SERS"热点"(Hot spots)分布较均一,树枝状银微纳结构作为SERS基体具有较好的重现性;当低SERS活性的3-巯基丙酸(3-Mercaptopropionic acid,3MPA)的检测浓度为10^(-5)mol/L时,利用树枝状银基体能检测到3MPA的SERS光谱,说明所制备的银基体对低活性物质也具有较好的SERS灵敏性。 展开更多
关键词 表面增强拉曼散射 银微纳结构 电化学沉积 层级结构
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飞秒激光光镊直写银微纳结构 被引量:12
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作者 陈忠贇 方淦 +4 位作者 曹良成 付芸 曹洪忠 姜肇国 段宣明 《中国激光》 EI CAS CSCD 北大核心 2018年第4期178-183,共6页
利用800nm飞秒激光光镊捕获了水中分散的银纳米颗粒,在玻璃基片表面直写银线,通过调控激光参数研究了激光功率对银线线宽及表面形貌的影响,实现了线宽为378nm的银线直写。经过测试,直写的银线电阻率为固体银的19.88倍。此外,还利用该方... 利用800nm飞秒激光光镊捕获了水中分散的银纳米颗粒,在玻璃基片表面直写银线,通过调控激光参数研究了激光功率对银线线宽及表面形貌的影响,实现了线宽为378nm的银线直写。经过测试,直写的银线电阻率为固体银的19.88倍。此外,还利用该方法制备了银二维网格结构,体现了该技术在二维结构直写方面的良好加工能力。 展开更多
关键词 激光技术 激光直写 光镊 飞秒激光 银微纳结构
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银纳米粒子构筑树枝状微纳结构用于表面增强拉曼散射的研究 被引量:1
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作者 胡成龙 刘继延 +2 位作者 彭湘红 刘学清 蔡少君 《江汉大学学报(自然科学版)》 2013年第1期14-18,共5页
通过简便的电化学沉积法制备出一种新颖的由树干、树枝和树叶构筑的树枝状银微纳结构。采用SEM和XRD等技术对所制备的银微纳结构进行结构表征,并结合其结构特点对树枝状银微纳结构的形成机制进行了初步探讨,制备的树枝状纳银具有极强的... 通过简便的电化学沉积法制备出一种新颖的由树干、树枝和树叶构筑的树枝状银微纳结构。采用SEM和XRD等技术对所制备的银微纳结构进行结构表征,并结合其结构特点对树枝状银微纳结构的形成机制进行了初步探讨,制备的树枝状纳银具有极强的对称性的结构。单分子检测实验表明,由于树枝银的高纵横比、众多的间隙结构和纳米尺寸的单晶树叶状银等结构特点,所制备的树枝状银微纳结构作为表面增强拉曼散射(Surface-enhanced Raman Scattering,SERS)的基底具有优异的SERS活性,可用于超低浓度的单分子检测。 展开更多
关键词 表面增强拉曼散射(SERS) 层级结构 银微纳结构
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药片状纳米银基体的合成及其表面增强拉曼散射的研究 被引量:1
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作者 胡成龙 陈韶云 +1 位作者 刘学清 刘继延 《江汉大学学报(自然科学版)》 2014年第3期9-12,共4页
通过电化学沉积法制备出一种药片状银微纳结构。采用SEM和XRD等技术对所制备的银微纳结构进行了结构表征,并结合其结构特点对药片状银微纳结构的形成机制进行了初步探讨。单分子检测实验可知超低浓度的罗丹明6G(Rhodamine 6G,R6G),即10-... 通过电化学沉积法制备出一种药片状银微纳结构。采用SEM和XRD等技术对所制备的银微纳结构进行了结构表征,并结合其结构特点对药片状银微纳结构的形成机制进行了初步探讨。单分子检测实验可知超低浓度的罗丹明6G(Rhodamine 6G,R6G),即10-10mol/L都可以检测到光谱信号,表明这种结构的纳米银可以作为良好的表面增强拉曼散射(surface-enhanced Raman scattering,SERS)的基底,其原因在于药片状纳米银具有层级结构,其表观自相似性赋予其良好的SERS活性。 展开更多
关键词 表面增强拉曼散射 药片状 银微纳结构
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Flexible and transparent capacitive pressure sensor with patterned microstructured composite rubber dielectric for wearable touch keyboard application 被引量:29
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作者 Ruilong Shi Zheng Lou +1 位作者 Shuai Chen Guozhen Shen 《Science China Materials》 SCIE EI CSCD 2018年第12期1587-1595,共9页
The development of pressure sensors with highly sensitivity, fast response and facile fabrication technique is desirable for wearable electronics. Here, we successfully fabricated a flexible transparent capacitive pre... The development of pressure sensors with highly sensitivity, fast response and facile fabrication technique is desirable for wearable electronics. Here, we successfully fabricated a flexible transparent capacitive pressure sensor based on patterned microstructured silver nanowires(AgNWs)/polydimethylsiloxane(PDMS) composite dielectrics. Compared with the pure PDMS dielectric layer with planar structures, the patterned microstructured sensor exhibits a higher sensitivity(0.831 kPa^-1, <0.5 kPa), a lower detection limit,good stability and durability. The enhanced sensing mechanism about the conductive filler content and the patterned microstructures has also been discussed. A 5×5 sensor array was then fabricated to be used as flexible and transparent wearable touch keyboards systems. The fabricated pressure sensor has great potential in the future electronic skin area. 展开更多
关键词 silver nanowires capacitive pressure sensor FLEXIBLE TRANSPARENT wearable electronics e-skin
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Effects of Silver Nanoparticles on Soil Microbial Communities and Bacterial Nitrification in Suburban Vegetable Soils 被引量:5
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作者 WANG Juan SHU Kunhui +1 位作者 ZHANG Li SI Youbin 《Pedosphere》 SCIE CAS CSCD 2017年第3期482-490,共9页
Silver nanoparticles (AgNPs) are widely used antimicrobial compounds; however, they may pose a threat to non-targeted bacteria in the environment. In this study high-throughput sequencing was used to investigate the... Silver nanoparticles (AgNPs) are widely used antimicrobial compounds; however, they may pose a threat to non-targeted bacteria in the environment. In this study high-throughput sequencing was used to investigate the effects of different concentrations of AgNPs (10, 50, and 100 mg kg-1) on soil microbial community structure during short-term (7 d) exposure. The amounts of Acidobacteria, Actinobacteria, Cyanobacteria, and Nitrospirae significantly decreased with increasing AgNP concentration; meanwhile, several other phyla (e.g., Proteobacteria and Planctomycetes) increased and dominated. Nitrosomonas europaea, a well-characterized ammonia- oxidizing bacterium, was used to study the sensitivity of bacteria to AgNPs and ionic silver (Ag+). Flow cytometry was used to monitor the toxicity of low (1 mg L-l), middle (10 mg L-l), and high concentrations (20 mg L-1) of AgNPs, as well as Ag+ (1 mg L-1) released into the medium from 20 mg L-1 concentration of AgNPs, towards N. europaea. After 12 h of exposure, the survival rate of N. europaea treated with 1 mg L-1 Ag+ was significantly lower than those treated with low (1 mg L-1) and middle concentrations (10 mg L-1) of AgNPs, but the survival rate in the treatment with high concentration (20 mg L-1) of AgNPs was much lower. Additionally, necrosis rates were higher in the treatment with 20 mg L-1 AgNPs. Electron microscopy showed that Ag+ caused serious damage to the cell wall of N. europaea, disintegrated the nucleoids, and condensed next to the cell membrane; however, dissolved Ag+ is only one of the antibacterial mechanisms of AgNPs. 展开更多
关键词 ammonia-oxidizing bacterium cell necrosis CYTOTOXICITY silver ions survival rate
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