Two reduced sequences of(s/s′)f (relative reduced partition function ratio) found in the present paper are LiSCN·B15C5>LiCCl3COO·B15C5 > LiClO4·B15C5 and LiClO4·4-mB15C5>LiClO4·B15C5...Two reduced sequences of(s/s′)f (relative reduced partition function ratio) found in the present paper are LiSCN·B15C5>LiCCl3COO·B15C5 > LiClO4·B15C5 and LiClO4·4-mB15C5>LiClO4·B15C5>LiClO4·Ph15C5,respectively.These solid lithium complexes with crown ethers were separated from tetrahydrofuran for the first sequence and from 3-methyl-1-butanol for the second one,respectively.Acording to the analysis of the data obtained,an independent character of the three factors(solvents,anion of lithium salts,and the sidegroup of 15C5 series),playing a part in contribution to(s/s′)f,have been brought to light preliminarily.展开更多
文摘Two reduced sequences of(s/s′)f (relative reduced partition function ratio) found in the present paper are LiSCN·B15C5>LiCCl3COO·B15C5 > LiClO4·B15C5 and LiClO4·4-mB15C5>LiClO4·B15C5>LiClO4·Ph15C5,respectively.These solid lithium complexes with crown ethers were separated from tetrahydrofuran for the first sequence and from 3-methyl-1-butanol for the second one,respectively.Acording to the analysis of the data obtained,an independent character of the three factors(solvents,anion of lithium salts,and the sidegroup of 15C5 series),playing a part in contribution to(s/s′)f,have been brought to light preliminarily.
