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作为Zn^(2+)荧光化学传感器的一种新型喹啉衍生物
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作者 刘庆云 张强 《内蒙古师范大学学报(自然科学汉文版)》 CAS 北大核心 2012年第3期289-292,共4页
设计并合成了一种Zn2+离子的荧光化学传感器5-氯-8-(N,N-二乙醇乙酰胺基)氧基喹啉(化合物1),并经1 H-NMR、元素分析等方法对其进行了结构表征.采用荧光光谱法,在甲醇溶剂中研究了Li+、Na+、K+、Mg2+、Ca2+、Ba2+、Sr2+、Pb2+、Mn2+、Co2... 设计并合成了一种Zn2+离子的荧光化学传感器5-氯-8-(N,N-二乙醇乙酰胺基)氧基喹啉(化合物1),并经1 H-NMR、元素分析等方法对其进行了结构表征.采用荧光光谱法,在甲醇溶剂中研究了Li+、Na+、K+、Mg2+、Ca2+、Ba2+、Sr2+、Pb2+、Mn2+、Co2+、Ni 2+、Cu2+、Zn2+、Cd2+、Hg2+、Tb3+离子对化合物1光谱的影响.结果表明,化合物1能够作为Zn2+离子高灵敏度和选择性的荧光探针,而其他金属离子对其只能引起非常小的荧光变化. 展开更多
关键词 5-氯-8-(N N-二乙醇乙酰胺基)氧基喹啉 合成 荧光 锌化学传感器
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The Process of Immobilization of ZnO Nanorods Surface with Galactose Oxidase
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作者 La Phan Phtrong Ha Ngo Van Chi Quang Tran Quang Trung 《Journal of Pharmacy and Pharmacology》 2017年第10期766-770,共5页
ZnO nanorods, with the c-axis orientation used for transparent conductors, solar cells, sensors especially the functionalized ZnO nanorods with some kinds of enzymes have been used for biosensor. In this work, we desc... ZnO nanorods, with the c-axis orientation used for transparent conductors, solar cells, sensors especially the functionalized ZnO nanorods with some kinds of enzymes have been used for biosensor. In this work, we describe the process immobilization of galactose oxidase on ZnO nanorods surface with glutaraldehyde as a cross-linker molecule to make the working electrode in electrochemical biosensor. ZnO nanorods were grown on FTO (Fluorine-doped tin oxide) substrate by solution method at low temperature. The crystalline phase and orientation of ZnO nanorods were identified using X-ray diffraction. The efficiency of the immobilization was calculated by Braford method showed that about 36% enzyme content was immobilized on ZnO nanorods surface. The working electrode based on the immobilized ZnO nanorods was tested in galactose solution by CV (cyclic voltammetry) method indicated the value of current intensity is about 0.14 μA. These results clearly demonstrate the potential of galactose sensor based on ZnO nanorod. 展开更多
关键词 ZNO solution method Bmford method galactose oxidase galactose biosensor.
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