[Objective] This study aimed to improve the yield and quality of tobacco. [Method] Different proportion combinations of zinc sulfate and iron sulfate were applied to Jiyan 9, and its agronomic traits, field natural in...[Objective] This study aimed to improve the yield and quality of tobacco. [Method] Different proportion combinations of zinc sulfate and iron sulfate were applied to Jiyan 9, and its agronomic traits, field natural incidence, economic characters and chemical composition were compared among different treatments. [Result] Iron-zinc combined application improved the yield and quality of tobacco. Among all the treatments, Treatment 2 (FeSO4 15 kg/hm2 + ZnSO4 10 kg/hm2) and Treatment 5 (FeSO4 15 kg/hm2 + ZnSO4 15 kg/hm2) were the best. [Conclusion] This study will provide a theoretical basis for the improvement of yield and quality of tobacco.展开更多
Zinc is one of the hazardous metals commonly found in municipal solid waste incineration (MSWI) ash, and this study reveals the stabilization mechanisms when sintering zinc-laden ash and ceramic precursors as a wast...Zinc is one of the hazardous metals commonly found in municipal solid waste incineration (MSWI) ash, and this study reveals the stabilization mechanisms when sintering zinc-laden ash and ceramic precursors as a waste-to-resource strategy. Using ZnO to simulate the zinc-laden ash and sintering with kaolinite and mullite ce- ramic precursors, both zinc aluminate spinel (ZnA1204) and willemite (Zn2SiO4) phases were found in the products under the tested thermal conditions. The results also indicate that kaolinite and mullite precursors exhibit different incorporation behavior, and ZnA1204 and Zn2SiO4 were found to be competitive as the Zn-hosting phases in the system. A prolonged leaching test was used to evaluate the leachability of potential product phases in the system. The concentrations of zinc in ZnO and Zn2SiO4 leachates were about two orders of magnitude higher than that in ZnA1204 leachate, indicating the preference of forming ZnA1204 for zinc stabilization. Furthermore, the alumi- num-rich sludge generated from waterworks could be beneficially used as a material resource to stabilize zinc in this study. The X-ray diffraction (XRD) pattern collected from the 1150 ~C and 3-h sintered sample shows the suc- cess of incorporating zinc into the ZnA1204 spinel structure with waterworks sludge precursor. The formation of ZnA1204 indicates a strong potential for employing aluminum- and silicon-based materials to thermally immobilize zinc and achieve the beneficial use of metal-laden MSWI ash.展开更多
Stabilized ZnTiO4 was prepared by doping magnesium oxide through traditional solid state reaction. The experimental results indicate that zinc titanate crystals doped with magnesium oxide grow well and the decompositi...Stabilized ZnTiO4 was prepared by doping magnesium oxide through traditional solid state reaction. The experimental results indicate that zinc titanate crystals doped with magnesium oxide grow well and the decomposition into Zn2TiO4 and TiO2 is restrained through traditional solid state reaction, By adjusting molar ratio of MgO, better properties can be obtained The dielectric properties of the ceramics doped with 30% MgO( molar percentage) sintered at 1060℃ are as follows:the value of quality factor is greater than 20000(6.5 GHz ), the temperature coefficient of resonance frequency is about 2 ± 10^-6 /℃,the dielectric constant ranges from 180 to 22.Besides,it is proved that heat treatment can optimize microstructure and the value of quality factor, which increases from 23833.93 to 47584.00 after 2h of heat treatment at 1040℃.展开更多
The effect of ZnO and low y-radiation on PLA based-films was investigated to be used for food packaging application. Ham slices were inoculated with E. coli, L. innocua and S. enterica and then covered with PLA and PL...The effect of ZnO and low y-radiation on PLA based-films was investigated to be used for food packaging application. Ham slices were inoculated with E. coli, L. innocua and S. enterica and then covered with PLA and PLA/5% ZnO films. The samples were irradiated with a y-radiation dose of 0.3 kGy at dose rate of 13.5 kGy/h. Microbiological analysis was performed at 0, 1 and 5 days on samples stored at 4 ℃. Results showed that no consistent reduction of bacteria was obtained, even at the fifth day of storage, when the ham was covered with PLA/5% ZnO film and no γ-radiation was performed. The use of γ-radiation results necessary to reduce the bacteria growth. In fact E. coli and S. enterica were not detected after 5 days of storage; whereas in the case of test with L. innocua a reduction of 1.3 log CFU/g was observed after 5 days of storage. The antibacterial results indicate that the presence of ZnO in PLA film is effective only for E. coll. The differences of the results obtained here with those reported in literature (where ZnO particles are reported to be very effective as antimicrobial material) are accounted for the different methodologies used. In conclusion considering the positive results, even if small, obtained here at least only for the E. Coli and considering that PLA/5% ZnO film shows, compared to plain PLA film, good tensile properties (especially Young's modulus and stress at yielding) and good permeability (to O2 and CO2) induce to consider the PLA/5% ZnO composite film usable for food packaging when long shelf life and food safety are required, considering also that it is biodegradable and compostable.展开更多
Electrochemical technology was introduced to study the floatability of galena in some wastewater samples from different processes of mineral processing plant in Fankou Lead-Zinc Mine. It is shown that the residual col...Electrochemical technology was introduced to study the floatability of galena in some wastewater samples from different processes of mineral processing plant in Fankou Lead-Zinc Mine. It is shown that the residual collector molecules in the wastewater from the thickening of lead and zinc concentrates can benefit the formation of lead xanthanate onto the surface of galena, yet, some special chemical components in the wastewater from zinc tailings and effluent may induce some surface reactions on galena, and herewith the direct reuse of this water may bring disadvantageous influence on galena flotation.展开更多
Field trials to determine the yield response of potatoes to Umostart Super Zn (USZ) fertilizer (11.46.0 + 2 Zn + Humates) were carried out in 2004 using the cultivar Tigoni. During the long rains season, the tre...Field trials to determine the yield response of potatoes to Umostart Super Zn (USZ) fertilizer (11.46.0 + 2 Zn + Humates) were carried out in 2004 using the cultivar Tigoni. During the long rains season, the treatments included USZ at 15 kg ha^-1 at planting; 30 kg ha^-1 split into 15 kg ha^-1 at planting and 15 kg ha^-1 during final earthing-up; 30 kg ha^-1 at planting; and 45 kg ha^-1 at planting. Treatments during the short rains included USZ at 30 kg ha^-1 split into 15 kg ha^-1 at planting and 15 kg ha^-1 during final earthing-up; 30 kg ha^-1 at planting; 40 kg ha^-1 at planting; 50 kg ha^-1 at planting; 50 kg ha^-1 split into 25 kg ha^-1 at planting and 25 kg ha^-1 during final earthing-up; and 60 kg ha^-1 at planting. USZ was contrasted with Diammonium phosphate (DAP) fertilizer (18:46:0) at 300 kg ha^-1 and 500 kg ha^-1 applied at planting and a control in which no fertilizer was applied. The DAP 300 kg ha^-1 treatment was however, not included during the long rains season. The highest tuber yields among the USZ treatments were obtained in plots treated with 45 kg ha^-1 (27.11 t ha^-1) during the long rains and 60 kg ha^-1 (55.17 t ha^-1) during the short rains season. Application of USZ resulted in a yield increase of at least 3.90 and 19.06 t ha^-1 during the long and short rains seasons respectively.展开更多
The primary objective to these study was to test NPKCaMg-fertilization induced "Zn(2+)" bioavailability in triticale rhizosphere soils. Soil and plant samples were taken from experimental sites randomly, and were...The primary objective to these study was to test NPKCaMg-fertilization induced "Zn(2+)" bioavailability in triticale rhizosphere soils. Soil and plant samples were taken from experimental sites randomly, and were analysed in laboratory to plant available Zn^2+) content. Zinc "Zn(2+)" concentrations showed a large variability to interactions with soil's pH values. It ranged from 0.4 and 1.36 mg kg1. Soil's "Zn(2+)" contents had been significantly lower than International Soil Limit (ISL) value (70 mg kgl), consequently. Plant available "Zn(2+)" contents from triticale rhizosphere soils in Leaf+Straw ranged from 10.1 to 38.4 mg kgl, and in Seed from 26.9 to 52.0 mg kg1. "Zn(2+)"s Actual Translocation Index (ATI) from rhizosphere soils to Leaf+Straw had as average 23.6, and to grain 43. 1. "Zn(2+)" Leaf+Straw bioacummulation (g hal) had as average 13.4, Grain 23.2, and total (Leaf+Straw+Grain) 36.6. "Zn(2+)"translocation from soils to Leaf+Straw was 37% lower than to Grain. Ultimately, within the range of experimental conditions tested these results are present that "Zn(2+)" tends to accumulate to triticale organs to create the conditions for toxicity effects in Food Chane.展开更多
A field experiment was conducted to investigate the effects of soil amendments(lime,nano-Si foliar solution and used diatomite) on the growth and metal uptake of three maize(Zea mays L.) cultivars grown in a Cd and Zn...A field experiment was conducted to investigate the effects of soil amendments(lime,nano-Si foliar solution and used diatomite) on the growth and metal uptake of three maize(Zea mays L.) cultivars grown in a Cd and Zn-contaminated acidic soil.The addition of lime significantly increased the maize grain yields and decreased the concentrations of Zn and Cd in the grains and shoots of maize when compared with the control.Among the three maize cultivars,Yunshi-5 accumulated the lowest amounts of Cd and Zn in the grain.The concentrations of Zn and Cd in the grain of Yunshi-5 conformed to the Chinese feed standards.These data revealed that a combination of low metal-accumulating maize and chemical fixation could effectively provide a barrier to prevent metals from entering the human food chain.展开更多
基金Supported by Key Special Project for High-quality Filled Low-tar Tobacco Research and Development and Characteristic High-quality Tobacco Development of State Tobacco Monopoly Administration(TS-06-20110038)~~
文摘[Objective] This study aimed to improve the yield and quality of tobacco. [Method] Different proportion combinations of zinc sulfate and iron sulfate were applied to Jiyan 9, and its agronomic traits, field natural incidence, economic characters and chemical composition were compared among different treatments. [Result] Iron-zinc combined application improved the yield and quality of tobacco. Among all the treatments, Treatment 2 (FeSO4 15 kg/hm2 + ZnSO4 10 kg/hm2) and Treatment 5 (FeSO4 15 kg/hm2 + ZnSO4 15 kg/hm2) were the best. [Conclusion] This study will provide a theoretical basis for the improvement of yield and quality of tobacco.
基金Supported by the General Research Fund Scheme(HKU 716809E,HKU 716310E)Special Equipment Grant(SEG_HKU10) of the Research Grants Council of Hong Kong
文摘Zinc is one of the hazardous metals commonly found in municipal solid waste incineration (MSWI) ash, and this study reveals the stabilization mechanisms when sintering zinc-laden ash and ceramic precursors as a waste-to-resource strategy. Using ZnO to simulate the zinc-laden ash and sintering with kaolinite and mullite ce- ramic precursors, both zinc aluminate spinel (ZnA1204) and willemite (Zn2SiO4) phases were found in the products under the tested thermal conditions. The results also indicate that kaolinite and mullite precursors exhibit different incorporation behavior, and ZnA1204 and Zn2SiO4 were found to be competitive as the Zn-hosting phases in the system. A prolonged leaching test was used to evaluate the leachability of potential product phases in the system. The concentrations of zinc in ZnO and Zn2SiO4 leachates were about two orders of magnitude higher than that in ZnA1204 leachate, indicating the preference of forming ZnA1204 for zinc stabilization. Furthermore, the alumi- num-rich sludge generated from waterworks could be beneficially used as a material resource to stabilize zinc in this study. The X-ray diffraction (XRD) pattern collected from the 1150 ~C and 3-h sintered sample shows the suc- cess of incorporating zinc into the ZnA1204 spinel structure with waterworks sludge precursor. The formation of ZnA1204 indicates a strong potential for employing aluminum- and silicon-based materials to thermally immobilize zinc and achieve the beneficial use of metal-laden MSWI ash.
基金SUPPORTED BY NATIONAL NATURAL SCIENCE FOUNDATION OF CHINA( NO. 50172035).
文摘Stabilized ZnTiO4 was prepared by doping magnesium oxide through traditional solid state reaction. The experimental results indicate that zinc titanate crystals doped with magnesium oxide grow well and the decomposition into Zn2TiO4 and TiO2 is restrained through traditional solid state reaction, By adjusting molar ratio of MgO, better properties can be obtained The dielectric properties of the ceramics doped with 30% MgO( molar percentage) sintered at 1060℃ are as follows:the value of quality factor is greater than 20000(6.5 GHz ), the temperature coefficient of resonance frequency is about 2 ± 10^-6 /℃,the dielectric constant ranges from 180 to 22.Besides,it is proved that heat treatment can optimize microstructure and the value of quality factor, which increases from 23833.93 to 47584.00 after 2h of heat treatment at 1040℃.
文摘The effect of ZnO and low y-radiation on PLA based-films was investigated to be used for food packaging application. Ham slices were inoculated with E. coli, L. innocua and S. enterica and then covered with PLA and PLA/5% ZnO films. The samples were irradiated with a y-radiation dose of 0.3 kGy at dose rate of 13.5 kGy/h. Microbiological analysis was performed at 0, 1 and 5 days on samples stored at 4 ℃. Results showed that no consistent reduction of bacteria was obtained, even at the fifth day of storage, when the ham was covered with PLA/5% ZnO film and no γ-radiation was performed. The use of γ-radiation results necessary to reduce the bacteria growth. In fact E. coli and S. enterica were not detected after 5 days of storage; whereas in the case of test with L. innocua a reduction of 1.3 log CFU/g was observed after 5 days of storage. The antibacterial results indicate that the presence of ZnO in PLA film is effective only for E. coll. The differences of the results obtained here with those reported in literature (where ZnO particles are reported to be very effective as antimicrobial material) are accounted for the different methodologies used. In conclusion considering the positive results, even if small, obtained here at least only for the E. Coli and considering that PLA/5% ZnO film shows, compared to plain PLA film, good tensile properties (especially Young's modulus and stress at yielding) and good permeability (to O2 and CO2) induce to consider the PLA/5% ZnO composite film usable for food packaging when long shelf life and food safety are required, considering also that it is biodegradable and compostable.
文摘Electrochemical technology was introduced to study the floatability of galena in some wastewater samples from different processes of mineral processing plant in Fankou Lead-Zinc Mine. It is shown that the residual collector molecules in the wastewater from the thickening of lead and zinc concentrates can benefit the formation of lead xanthanate onto the surface of galena, yet, some special chemical components in the wastewater from zinc tailings and effluent may induce some surface reactions on galena, and herewith the direct reuse of this water may bring disadvantageous influence on galena flotation.
文摘Field trials to determine the yield response of potatoes to Umostart Super Zn (USZ) fertilizer (11.46.0 + 2 Zn + Humates) were carried out in 2004 using the cultivar Tigoni. During the long rains season, the treatments included USZ at 15 kg ha^-1 at planting; 30 kg ha^-1 split into 15 kg ha^-1 at planting and 15 kg ha^-1 during final earthing-up; 30 kg ha^-1 at planting; and 45 kg ha^-1 at planting. Treatments during the short rains included USZ at 30 kg ha^-1 split into 15 kg ha^-1 at planting and 15 kg ha^-1 during final earthing-up; 30 kg ha^-1 at planting; 40 kg ha^-1 at planting; 50 kg ha^-1 at planting; 50 kg ha^-1 split into 25 kg ha^-1 at planting and 25 kg ha^-1 during final earthing-up; and 60 kg ha^-1 at planting. USZ was contrasted with Diammonium phosphate (DAP) fertilizer (18:46:0) at 300 kg ha^-1 and 500 kg ha^-1 applied at planting and a control in which no fertilizer was applied. The DAP 300 kg ha^-1 treatment was however, not included during the long rains season. The highest tuber yields among the USZ treatments were obtained in plots treated with 45 kg ha^-1 (27.11 t ha^-1) during the long rains and 60 kg ha^-1 (55.17 t ha^-1) during the short rains season. Application of USZ resulted in a yield increase of at least 3.90 and 19.06 t ha^-1 during the long and short rains seasons respectively.
文摘The primary objective to these study was to test NPKCaMg-fertilization induced "Zn(2+)" bioavailability in triticale rhizosphere soils. Soil and plant samples were taken from experimental sites randomly, and were analysed in laboratory to plant available Zn^2+) content. Zinc "Zn(2+)" concentrations showed a large variability to interactions with soil's pH values. It ranged from 0.4 and 1.36 mg kg1. Soil's "Zn(2+)" contents had been significantly lower than International Soil Limit (ISL) value (70 mg kgl), consequently. Plant available "Zn(2+)" contents from triticale rhizosphere soils in Leaf+Straw ranged from 10.1 to 38.4 mg kgl, and in Seed from 26.9 to 52.0 mg kg1. "Zn(2+)"s Actual Translocation Index (ATI) from rhizosphere soils to Leaf+Straw had as average 23.6, and to grain 43. 1. "Zn(2+)" Leaf+Straw bioacummulation (g hal) had as average 13.4, Grain 23.2, and total (Leaf+Straw+Grain) 36.6. "Zn(2+)"translocation from soils to Leaf+Straw was 37% lower than to Grain. Ultimately, within the range of experimental conditions tested these results are present that "Zn(2+)" tends to accumulate to triticale organs to create the conditions for toxicity effects in Food Chane.
基金Supported by the National Natural Science Foundation of China (Nos.40801115 and 41071306)the Science and Technology Planning Project of Guangdong Province,China (Nos.2007A032303001,2009B030802016 and 2010B031800006)
文摘A field experiment was conducted to investigate the effects of soil amendments(lime,nano-Si foliar solution and used diatomite) on the growth and metal uptake of three maize(Zea mays L.) cultivars grown in a Cd and Zn-contaminated acidic soil.The addition of lime significantly increased the maize grain yields and decreased the concentrations of Zn and Cd in the grains and shoots of maize when compared with the control.Among the three maize cultivars,Yunshi-5 accumulated the lowest amounts of Cd and Zn in the grain.The concentrations of Zn and Cd in the grain of Yunshi-5 conformed to the Chinese feed standards.These data revealed that a combination of low metal-accumulating maize and chemical fixation could effectively provide a barrier to prevent metals from entering the human food chain.