The creep strain of conventionally treated 2195 alloy is very low,increasing the difficulty of manufacturing Al-Cu-Li alloy sheet parts by creep age forming.Therefore,finding a solution to improve the creep formabilit...The creep strain of conventionally treated 2195 alloy is very low,increasing the difficulty of manufacturing Al-Cu-Li alloy sheet parts by creep age forming.Therefore,finding a solution to improve the creep formability of Al-Cu-Li alloy is vital.A thorough comparison of the effects of cryo-deformation and ambient temperature large pre-deformation(LPD)on the creep ageing response in the 2195 alloy sheet at 160℃with different stresses has been made.The evolution of dislocations and precipitates during creep ageing of LPD alloys are revealed by X-ray diffraction and transmission electron microscopy.High-quality 2195 alloy sheet largely pre-deformed by 80%without edge-cracking is obtained by cryo-rolling at liquid nitrogen temperature,while severe edge-cracking occurs during room temperature rolling.The creep formability and strength of the 2195 alloy are both enhanced by introducing pre-existing dislocations with a density over 1.4×10^(15)m^(−2).At 160℃and 150 MPa,creep strain and creep-aged strength generally increases by 4−6 times and 30−50 MPa in the LPD sample,respectively,compared to conventional T3 alloy counterpart.The elongation of creep-aged LPD sample is low but remains relevant for application.The high-density dislocations,though existing in the form of dislocation tangles,promote the formation of refined T1 precipitates with a uniform dispersion.展开更多
Based on a 5% (mass fraction) Re-containing single crystal nickel-based superalloy with 3% (mass fraction) Cr, the microstructural variation with Cr addition was investigated. The experimental results show that se...Based on a 5% (mass fraction) Re-containing single crystal nickel-based superalloy with 3% (mass fraction) Cr, the microstructural variation with Cr addition was investigated. The experimental results show that segregation of alloying elements was enhanced in as-cast microstructure with Cr addition; and the volume fraction of eutectic is increased. However, the solidus and liquidus temperatures are remarkably reduced. With the increase of Cr content, the average γ' size and volume fraction are decreased in the fully heat treated microstructure. X-ray diffraction results indicate that γ/γ' lattice misfit becomes more negative. According to the energy dispersive spectroscopy (EDS) results, Cr is mainly distributed in the γ matrix; and more y-forming elements, such as Re and W, enter the γ matrix, while the γ/γ' partition ratio of Cr is inversely decreased.展开更多
This paper attempts to analyze Blanche's psyche in relation to her employing defense mechanism to restore her mental health and herself in A Streetcar Named Desire (1947) by the American playwright Tennessee Willia...This paper attempts to analyze Blanche's psyche in relation to her employing defense mechanism to restore her mental health and herself in A Streetcar Named Desire (1947) by the American playwright Tennessee Williams. It focuses on her replacing reality with fantastic embodiments or illusion. She has taken unacceptable impulses into acceptable forms by unconsciously blocking the impulses such as superego and thereby reducing agony for the earlier traumatic experiences left indelible marks on her mind, and anxiety for survival. Her anxiety becomes too overwhelming that her ego urgently employs defense mechanisms to protect her. With her new hopes and dreams she desires to replace the highly stressful loss. Under mental and social stress, her illusion and her falsification of reality nevertheless became unable to overcome recurring trauma-causing situation in reality and her healing process thereby leaving her on the verge of extinction.展开更多
Temperature has great influence on the stacking fault energy (SFE). Both SFE and dγ 0/dT for Fe-based alloys containing substitutional or interstitial atoms increase with increasing temperature. Based on the thermody...Temperature has great influence on the stacking fault energy (SFE). Both SFE and dγ 0/dT for Fe-based alloys containing substitutional or interstitial atoms increase with increasing temperature. Based on the thermodynamic model of SFE, the equation $\frac{{d\gamma _0 }}{{dT}} = \frac{{d\gamma ^{ch} }}{{dT}} + \frac{{d\gamma ^{se\user1{g}} }}{{dT}} + \frac{{d\gamma ^{MG} }}{{dT}}$ and those expressions for three items involved are established. The calculatedγ 0/dT is generally consistent with the experimental. The influence of chemical free energy on the temperature dependence of SFE is almost constant, and is obviously stronger than that of magnetic and segregation contributions. The magnetic transition and the segregation of alloying elements at stacking faults cause a decrease in SFE of the alloys when temperature increases; that is, dγ MG/dT<0 and dγ seg/dT<0. Meanwhile, such an influence decreases with increasing temperature, except for the dγ seg/dT} of Fe?Mn?Si alloys. With these results, the experimental phenomena that the SFE of Fe-based alloys is not zero at the thermo-dynamically equilibrated temperature (T 0) of the λ and ε phases and they are positive both atT>T 0 andT<T 0 can be reasonably explained.展开更多
基金Projects(52274404,52305441,U22A20190)supported by the National Natural Science Foundation of ChinaProjects(2022JJ20065,2023JJ40739)supported by the Natural Science Foundation of Hunan Province,China+2 种基金Project(2022RC1001)supported by the Science and Technology Innovation Program of Hunan Province,ChinaProject(2023ZZTS0972)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2021YFB3400903)supported by the National Key R&D Program of China。
文摘The creep strain of conventionally treated 2195 alloy is very low,increasing the difficulty of manufacturing Al-Cu-Li alloy sheet parts by creep age forming.Therefore,finding a solution to improve the creep formability of Al-Cu-Li alloy is vital.A thorough comparison of the effects of cryo-deformation and ambient temperature large pre-deformation(LPD)on the creep ageing response in the 2195 alloy sheet at 160℃with different stresses has been made.The evolution of dislocations and precipitates during creep ageing of LPD alloys are revealed by X-ray diffraction and transmission electron microscopy.High-quality 2195 alloy sheet largely pre-deformed by 80%without edge-cracking is obtained by cryo-rolling at liquid nitrogen temperature,while severe edge-cracking occurs during room temperature rolling.The creep formability and strength of the 2195 alloy are both enhanced by introducing pre-existing dislocations with a density over 1.4×10^(15)m^(−2).At 160℃and 150 MPa,creep strain and creep-aged strength generally increases by 4−6 times and 30−50 MPa in the LPD sample,respectively,compared to conventional T3 alloy counterpart.The elongation of creep-aged LPD sample is low but remains relevant for application.The high-density dislocations,though existing in the form of dislocation tangles,promote the formation of refined T1 precipitates with a uniform dispersion.
基金Projects (2010CB631200, 2010CB631206) supported by the National Basic Research Program of ChinaProject (50931004) supported by the National Natural Science Foundation of China
文摘Based on a 5% (mass fraction) Re-containing single crystal nickel-based superalloy with 3% (mass fraction) Cr, the microstructural variation with Cr addition was investigated. The experimental results show that segregation of alloying elements was enhanced in as-cast microstructure with Cr addition; and the volume fraction of eutectic is increased. However, the solidus and liquidus temperatures are remarkably reduced. With the increase of Cr content, the average γ' size and volume fraction are decreased in the fully heat treated microstructure. X-ray diffraction results indicate that γ/γ' lattice misfit becomes more negative. According to the energy dispersive spectroscopy (EDS) results, Cr is mainly distributed in the γ matrix; and more y-forming elements, such as Re and W, enter the γ matrix, while the γ/γ' partition ratio of Cr is inversely decreased.
文摘This paper attempts to analyze Blanche's psyche in relation to her employing defense mechanism to restore her mental health and herself in A Streetcar Named Desire (1947) by the American playwright Tennessee Williams. It focuses on her replacing reality with fantastic embodiments or illusion. She has taken unacceptable impulses into acceptable forms by unconsciously blocking the impulses such as superego and thereby reducing agony for the earlier traumatic experiences left indelible marks on her mind, and anxiety for survival. Her anxiety becomes too overwhelming that her ego urgently employs defense mechanisms to protect her. With her new hopes and dreams she desires to replace the highly stressful loss. Under mental and social stress, her illusion and her falsification of reality nevertheless became unable to overcome recurring trauma-causing situation in reality and her healing process thereby leaving her on the verge of extinction.
基金This work was supported by the National Natural Science Foundation of China (Grant No.59671023) the Fund for Ph. D. Program, the Ministry of Education (No. 97024835) of China and the Emerson Electric Co. USA.
文摘Temperature has great influence on the stacking fault energy (SFE). Both SFE and dγ 0/dT for Fe-based alloys containing substitutional or interstitial atoms increase with increasing temperature. Based on the thermodynamic model of SFE, the equation $\frac{{d\gamma _0 }}{{dT}} = \frac{{d\gamma ^{ch} }}{{dT}} + \frac{{d\gamma ^{se\user1{g}} }}{{dT}} + \frac{{d\gamma ^{MG} }}{{dT}}$ and those expressions for three items involved are established. The calculatedγ 0/dT is generally consistent with the experimental. The influence of chemical free energy on the temperature dependence of SFE is almost constant, and is obviously stronger than that of magnetic and segregation contributions. The magnetic transition and the segregation of alloying elements at stacking faults cause a decrease in SFE of the alloys when temperature increases; that is, dγ MG/dT<0 and dγ seg/dT<0. Meanwhile, such an influence decreases with increasing temperature, except for the dγ seg/dT} of Fe?Mn?Si alloys. With these results, the experimental phenomena that the SFE of Fe-based alloys is not zero at the thermo-dynamically equilibrated temperature (T 0) of the λ and ε phases and they are positive both atT>T 0 andT<T 0 can be reasonably explained.