Two organic sensitizers (LI-33 and LI-34) with double anchoring units were synthesized and utilized for dye sensitized solar cells (DSSCs), which contained thiophene or vinyl thiophene as n-bridge. The introductio...Two organic sensitizers (LI-33 and LI-34) with double anchoring units were synthesized and utilized for dye sensitized solar cells (DSSCs), which contained thiophene or vinyl thiophene as n-bridge. The introduction of double anchoring units can change their absorption spectra and energy levels in a large degree, thus, the better light-harvesting ability and the convenient electron transfer along the whole molecule can be obtained. The solar cell based on LI-34 exhibited a broad incident photon- to-current conversion efficiency (IPCE) spectrum and high conversion efficiency (η=6.05%) with coadsorbent CDCA.展开更多
基金supported by the National Natural Science Foundation of China(21372003,21325416)the National Basic Research Program of China(2011CB932702)
文摘Two organic sensitizers (LI-33 and LI-34) with double anchoring units were synthesized and utilized for dye sensitized solar cells (DSSCs), which contained thiophene or vinyl thiophene as n-bridge. The introduction of double anchoring units can change their absorption spectra and energy levels in a large degree, thus, the better light-harvesting ability and the convenient electron transfer along the whole molecule can be obtained. The solar cell based on LI-34 exhibited a broad incident photon- to-current conversion efficiency (IPCE) spectrum and high conversion efficiency (η=6.05%) with coadsorbent CDCA.