Thin films of tin and copper oxide forming heterojunction are being studied for applications in photovoltaic systems. The procedure for obtaining such a film was based on the technique of spray pyrolysis with working ...Thin films of tin and copper oxide forming heterojunction are being studied for applications in photovoltaic systems. The procedure for obtaining such a film was based on the technique of spray pyrolysis with working temperature of 600 ℃. The XRD （X-ray diffraction） showed the formation of tin oxides （SnO2） and copper （Cu2O） and its structural parameters are a, b and c, 4.7534 A^°, 4.7534 A^°, 3.1998 A^° （tetragonal form） and 4.2580 A^°, 4.2580 A^°, 4.2580 A^° （cubic form）, respectively. Highseore Plus program was used for phase identification and DBWSTool2.4 program used for refinement. The grain size was estimated by Williamson-Hall.展开更多
Distribution of metals on Pd-SnO2/D3520 catalysts and state of the catalystswere studied with SEM, XRD. The interactlbn between metals and supped or between Pd and Sn or Ph were studied by IR, XPS. In addition, the re...Distribution of metals on Pd-SnO2/D3520 catalysts and state of the catalystswere studied with SEM, XRD. The interactlbn between metals and supped or between Pd and Sn or Ph were studied by IR, XPS. In addition, the relationship ofthe activity for catalytic hydrogenation of the olefins and outer layer valence electrondensity of Pd was discussed. The results showed that these catalysts had suitablesurface state, the metals were uniformly dispersed on the surface layer of the suppnd. There were not obvious interaction between the metals and the supal. Therewas strong interaction between Pd and Sn (or Ph) in the catalysts. The catalytic activity for hydrogenation was related to outer layer valence electron density of Pd.展开更多
The Pengshan Sn-Pb-Zn polymetallic orefield is located in the Jiujiang-Ruichang region, which is a segment of the middle-lower Yangtze River metallogenic belt. The Pengshan late Yanshanian buried pluton with granitic ...The Pengshan Sn-Pb-Zn polymetallic orefield is located in the Jiujiang-Ruichang region, which is a segment of the middle-lower Yangtze River metallogenic belt. The Pengshan late Yanshanian buried pluton with granitic composition is a calc-alkaline pluton, intrusion of which is responsible for the formation of the Sn-Pb-Zn polymetallic deposit through providing thermodynamic condition and ore-forming material. The long-active basement rifts initially formed in the Jinning period and the domal structure with induced secondary order faults formed by emplacement of the pluton, such as ring-detachment fault, top-detachment fault and joint fissure, act as the passage-way for magma and ore-forming fluid and impounding structure for ore deposit. The magma to form the pluton with DI>90 is intensively differentiated. The variation of the ore-forming fluid in composition with falling in temperature caused by action of magmatic hydrothermal convection system combined with groundwater convection system attributes to mineralization of various types in the orefield. The mineralization process can be divided into six stages, i.e., greisenization, skarnization of early stage, fluorite-stanniferous silication stage, skarnization of advanced stage, quartz and cassiterite-sulfuration stage and carbonation stage. The mineral assemblages formed in different mineralization stages are different owing to temperature changing and may be overlapped in space. Malayaite is recognized from the mineral assemblage formed in the fluorite-stanniferous silication stage. The ores in the Pengshan Sn-Pb-Zn polymetallic deposit are spatially zoned with variation from As-Sn mineral assemblage of high temperature in the inner zone through Sn-Pb and Pb-Zn-Ag mineral assemblage of middle temperature in the middle zone to fluorite mineral assemblage of low temperature in the outer zone. The exchanging of Sn, Mg and Fe between biotite and hydrothermal fluid resulted from variation of physicochemical condition during evolution processes of the hydrothermal fluid and its role in mineralization are also discussed in this paper.展开更多
Tin-doped Indium Oxide （ITO） has been successfully prepared via solvothermal method with a mixture of Indium（Ill） acetylacetonate and Tin（IV） bis（acetylacetonate）dichioride in oleyamine solvent under the condi...Tin-doped Indium Oxide （ITO） has been successfully prepared via solvothermal method with a mixture of Indium（Ill） acetylacetonate and Tin（IV） bis（acetylacetonate）dichioride in oleyamine solvent under the condition of the different reaction time from 12 h to 48 h for the first time. The morphology, phase composition and particle size of the ITO powder were characterized by TEM and XRD. Two significant properties required for ITO samples to become noncarbon support for Pt in PEMFCs including specific surface area and electrical conductivity were studied.展开更多
Extreme ultraviolet lithography is most promising for the next generation lithography. However, debris from laser-produced plasma, particularly energetic ions, severely decreases the lifetime of extreme ultraviolet op...Extreme ultraviolet lithography is most promising for the next generation lithography. However, debris from laser-produced plasma, particularly energetic ions, severely decreases the lifetime of extreme ultraviolet optics. We measured the characteris- tics of ions from tin plasma by the time of flight method with a frequency-doubled Nd： YAG laser at the intensity of 3.5x1010 W/cm2 （532 nm, 8 ns）. Our measurement shows that the maximum and peak of tin ions energies from plasma under the above experimental parameters are about 4.2 and 1.8 keV, respectively. Moreover, it is found that kinetic energy angular distribution of tin ions can be fitted by cos0.8（θ）, where θ is the angle with respect to the target normal. We also investigated the mitigation effect of argon, helium gases to the tin ions, and found that tin ions from the plasma can be mitigated effectively at the pressure -38 mTorr for argon or -375 mTorr for helium, respectively.展开更多
文摘Thin films of tin and copper oxide forming heterojunction are being studied for applications in photovoltaic systems. The procedure for obtaining such a film was based on the technique of spray pyrolysis with working temperature of 600 ℃. The XRD （X-ray diffraction） showed the formation of tin oxides （SnO2） and copper （Cu2O） and its structural parameters are a, b and c, 4.7534 A^°, 4.7534 A^°, 3.1998 A^° （tetragonal form） and 4.2580 A^°, 4.2580 A^°, 4.2580 A^° （cubic form）, respectively. Highseore Plus program was used for phase identification and DBWSTool2.4 program used for refinement. The grain size was estimated by Williamson-Hall.
文摘Distribution of metals on Pd-SnO2/D3520 catalysts and state of the catalystswere studied with SEM, XRD. The interactlbn between metals and supped or between Pd and Sn or Ph were studied by IR, XPS. In addition, the relationship ofthe activity for catalytic hydrogenation of the olefins and outer layer valence electrondensity of Pd was discussed. The results showed that these catalysts had suitablesurface state, the metals were uniformly dispersed on the surface layer of the suppnd. There were not obvious interaction between the metals and the supal. Therewas strong interaction between Pd and Sn (or Ph) in the catalysts. The catalytic activity for hydrogenation was related to outer layer valence electron density of Pd.
文摘The Pengshan Sn-Pb-Zn polymetallic orefield is located in the Jiujiang-Ruichang region, which is a segment of the middle-lower Yangtze River metallogenic belt. The Pengshan late Yanshanian buried pluton with granitic composition is a calc-alkaline pluton, intrusion of which is responsible for the formation of the Sn-Pb-Zn polymetallic deposit through providing thermodynamic condition and ore-forming material. The long-active basement rifts initially formed in the Jinning period and the domal structure with induced secondary order faults formed by emplacement of the pluton, such as ring-detachment fault, top-detachment fault and joint fissure, act as the passage-way for magma and ore-forming fluid and impounding structure for ore deposit. The magma to form the pluton with DI>90 is intensively differentiated. The variation of the ore-forming fluid in composition with falling in temperature caused by action of magmatic hydrothermal convection system combined with groundwater convection system attributes to mineralization of various types in the orefield. The mineralization process can be divided into six stages, i.e., greisenization, skarnization of early stage, fluorite-stanniferous silication stage, skarnization of advanced stage, quartz and cassiterite-sulfuration stage and carbonation stage. The mineral assemblages formed in different mineralization stages are different owing to temperature changing and may be overlapped in space. Malayaite is recognized from the mineral assemblage formed in the fluorite-stanniferous silication stage. The ores in the Pengshan Sn-Pb-Zn polymetallic deposit are spatially zoned with variation from As-Sn mineral assemblage of high temperature in the inner zone through Sn-Pb and Pb-Zn-Ag mineral assemblage of middle temperature in the middle zone to fluorite mineral assemblage of low temperature in the outer zone. The exchanging of Sn, Mg and Fe between biotite and hydrothermal fluid resulted from variation of physicochemical condition during evolution processes of the hydrothermal fluid and its role in mineralization are also discussed in this paper.
文摘Tin-doped Indium Oxide （ITO） has been successfully prepared via solvothermal method with a mixture of Indium（Ill） acetylacetonate and Tin（IV） bis（acetylacetonate）dichioride in oleyamine solvent under the condition of the different reaction time from 12 h to 48 h for the first time. The morphology, phase composition and particle size of the ITO powder were characterized by TEM and XRD. Two significant properties required for ITO samples to become noncarbon support for Pt in PEMFCs including specific surface area and electrical conductivity were studied.
基金supported by the National Natural Science Foundation ofChina (Grant Nos. 60978014,61178022 and 11074027)the Basic Research Fund from Sci. & Tech. Department of Jilin Province (Grant Nos.20100521,20100168 and 20111812)
文摘Extreme ultraviolet lithography is most promising for the next generation lithography. However, debris from laser-produced plasma, particularly energetic ions, severely decreases the lifetime of extreme ultraviolet optics. We measured the characteris- tics of ions from tin plasma by the time of flight method with a frequency-doubled Nd： YAG laser at the intensity of 3.5x1010 W/cm2 （532 nm, 8 ns）. Our measurement shows that the maximum and peak of tin ions energies from plasma under the above experimental parameters are about 4.2 and 1.8 keV, respectively. Moreover, it is found that kinetic energy angular distribution of tin ions can be fitted by cos0.8（θ）, where θ is the angle with respect to the target normal. We also investigated the mitigation effect of argon, helium gases to the tin ions, and found that tin ions from the plasma can be mitigated effectively at the pressure -38 mTorr for argon or -375 mTorr for helium, respectively.
