Tin nanoparticles with different size distribution were synthesized using chemical reduction method by applying NaBH4 as reduction agent.The Sn nanoparticles smaller than 100 nm were less agglomerated and no obviously...Tin nanoparticles with different size distribution were synthesized using chemical reduction method by applying NaBH4 as reduction agent.The Sn nanoparticles smaller than 100 nm were less agglomerated and no obviously oxidized.The melting properties of these synthesized nanoparticles were studied by differential scanning calorimetry.The melting temperatures of Sn nanoparticles in diameter of 81,40,36 and 34 nm were 226.1,221.8,221.1 and 219.5？欲espectively.The size-dependent melting temperature and size-dependent latent heat of fusion have been observed.The size-dependent melting properties of tin nanoparticles in this study were also comparatively analyzed by employing different size-dependent theoretical melting models and the differences between these models were discussed.The results show that the experimental data are in accordance with the LSM model and SPI model,and the LSM model gives the better understanding for the melting property of the Sn nanoparticles.展开更多
The electrical potential inside a cylinder with a space charge layer is used to express the neck potential barrier of nano-SnO2 gas elements, and the neck-controlled sensitivity and the grain size effect are studied. ...The electrical potential inside a cylinder with a space charge layer is used to express the neck potential barrier of nano-SnO2 gas elements, and the neck-controlled sensitivity and the grain size effect are studied. It is shown that the sensing properties are influenced by the microstructural features, such as the grain size, the geometry and connectivity between grains, and that the neck controlled sensitivity alone is higher than the neck-grain controlled sensitivity and the difference between the neck controlled sensitivity and the neck-grain controlled sensitivity is large in the high sensitivity range for nano-SnO2 gas elements, which suggests a possible approach to the improvement of the sensitivity of a sensor by decreasing the number of necks of a nano-grain SnO2 gas element.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51225204,21303222,and 21127901)the "Strategic Priority Research Program" of the Chinese Academy of Sciences(Grant No.XDA09010100)~~
基金Project(2006AA03Z339)supported by the National High-tech Research and Development Program of ChinaProject(50571057)supported by the National Natural Science Foundation of ChinaProject(08520740500)supported by Science and Technology Commission of Shanghai Municipality,China
文摘Tin nanoparticles with different size distribution were synthesized using chemical reduction method by applying NaBH4 as reduction agent.The Sn nanoparticles smaller than 100 nm were less agglomerated and no obviously oxidized.The melting properties of these synthesized nanoparticles were studied by differential scanning calorimetry.The melting temperatures of Sn nanoparticles in diameter of 81,40,36 and 34 nm were 226.1,221.8,221.1 and 219.5？欲espectively.The size-dependent melting temperature and size-dependent latent heat of fusion have been observed.The size-dependent melting properties of tin nanoparticles in this study were also comparatively analyzed by employing different size-dependent theoretical melting models and the differences between these models were discussed.The results show that the experimental data are in accordance with the LSM model and SPI model,and the LSM model gives the better understanding for the melting property of the Sn nanoparticles.
基金Chongqing Education Committee Foundation (No.020804)
文摘The electrical potential inside a cylinder with a space charge layer is used to express the neck potential barrier of nano-SnO2 gas elements, and the neck-controlled sensitivity and the grain size effect are studied. It is shown that the sensing properties are influenced by the microstructural features, such as the grain size, the geometry and connectivity between grains, and that the neck controlled sensitivity alone is higher than the neck-grain controlled sensitivity and the difference between the neck controlled sensitivity and the neck-grain controlled sensitivity is large in the high sensitivity range for nano-SnO2 gas elements, which suggests a possible approach to the improvement of the sensitivity of a sensor by decreasing the number of necks of a nano-grain SnO2 gas element.
