A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with...A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.展开更多
On YBCO/LaAlO3/YBCO substrate with the dimension of 10 mm 20 mm, a miniature HTSC (high tem- perature superconductivity) bandpass filter with multi-zig- zag line structure is developed. At 77 K, the center frequency i...On YBCO/LaAlO3/YBCO substrate with the dimension of 10 mm 20 mm, a miniature HTSC (high tem- perature superconductivity) bandpass filter with multi-zig- zag line structure is developed. At 77 K, the center frequency is 1.2 GHz, the bandwidth is 50 MHz, and the insertion loss is 0.12 dB.展开更多
基金the Natural Science Foundation of Jiangsu province (Grant No Bk2001031)
文摘A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.
基金This work was supported by the“863”Project(Grant No.863-CD060201)the National Superconductor Institute.
文摘On YBCO/LaAlO3/YBCO substrate with the dimension of 10 mm 20 mm, a miniature HTSC (high tem- perature superconductivity) bandpass filter with multi-zig- zag line structure is developed. At 77 K, the center frequency is 1.2 GHz, the bandwidth is 50 MHz, and the insertion loss is 0.12 dB.
