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碳包覆MnSn_2锂离子电池负极材料合成及性能
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作者 袁正勇 邱从平 彭振博 《电源技术》 CAS CSCD 北大核心 2012年第1期40-41,129,共3页
用球磨-热解法合成了碳包覆锂离子电池锰锡合金负极材料MnSn2/C。通过XRD、TEM和电化学测试对材料进行了表征。制备的材料粒径大小分布在1~2μm之间,合金材料表面完全被碳包覆,碳层厚度约为60~120 nm。在充放电电压为1.5 V到0 V范围内... 用球磨-热解法合成了碳包覆锂离子电池锰锡合金负极材料MnSn2/C。通过XRD、TEM和电化学测试对材料进行了表征。制备的材料粒径大小分布在1~2μm之间,合金材料表面完全被碳包覆,碳层厚度约为60~120 nm。在充放电电压为1.5 V到0 V范围内,初始可逆充电比容量为675 mAh/g,经过20周的循环后,充电比容量仍然保持为440mAh/g。与没有碳包覆的MnSn2负极材料相比,其循环性能有较大提高。 展开更多
关键词 锰锡合金 锂离子电池 负极材料
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Effects of Mn and Sn on microstructure of Al-7Si-Mg alloy modified by Sr and Al-5Ti-B 被引量:4
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作者 邱科 王日初 +3 位作者 彭超群 王乃光 蔡志勇 张纯 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第11期3546-3552,共7页
The effects of Mn and Sn on the microstructure of Al?7Si?Mg alloy modified by Sr and Al?5Ti?B were studied. The results show that the columnar dendrites structure is observed with high content of Sr, indicating a pois... The effects of Mn and Sn on the microstructure of Al?7Si?Mg alloy modified by Sr and Al?5Ti?B were studied. The results show that the columnar dendrites structure is observed with high content of Sr, indicating a poisoning effect of the Al?5Ti?B grain refinement. In addition, Sr intermetallic compounds distribute on the TiB2 particles, which agglomerate inside the eutectic Si. The mechanism responsible for such poisoning was discussed. The addition of Mn changes the morphology of iron intermetallic compounds fromβ-Al5FeSi toα-Al(Mn,Fe)Si. Increasing the amount of Mn changes the morphology ofα-Al(Mn,Fe)Si from branched shape to rod-like shape with branched distribution, and finally convertsα-Al(Mn,Fe)Si to Chinese script shape. The microstructure observed by transmission electron microscopy (TEM) shows that Mg is more likely to interact with Sn in contrast with Si under the effect of Sn. Mg2Sn compound preferentially precipitates between the Si/Si interfaces and Al/Si interfaces. 展开更多
关键词 Al-7Si-Mg aluminum alloy grain refinement intermetallic compound manganese tin Al-5Ti-B SR
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