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新型粉末状聚苯乙烯气凝胶表面改性及吸附Cd(Ⅱ)特性
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作者 詹杰茗 蔡力锋 +2 位作者 杨磊 梁杰 吕源财 《化工新型材料》 CAS CSCD 北大核心 2021年第4期180-183,189,共5页
采用浓硫酸对新型粉末状聚苯乙烯气凝胶(PPA)进行表面改性,进一步研究了改性粉末状聚苯乙烯气凝胶(mPPA)对溶液中Cd(Ⅱ)的吸附特性。结果表明:浓硫酸表面改性对PPA纳米形貌和孔结构影响不大,PPA和mPPA均呈现独特的微孔-中孔-大孔呈层次... 采用浓硫酸对新型粉末状聚苯乙烯气凝胶(PPA)进行表面改性,进一步研究了改性粉末状聚苯乙烯气凝胶(mPPA)对溶液中Cd(Ⅱ)的吸附特性。结果表明:浓硫酸表面改性对PPA纳米形貌和孔结构影响不大,PPA和mPPA均呈现独特的微孔-中孔-大孔呈层次化分布的孔结构特征。表面改性可以大幅度提升气凝胶对Cd(Ⅱ)的吸附率,适当增加表面改性时间、溶液pH、吸附温度和吸附时间,有助于mPPA对溶液中Cd(Ⅱ)的吸附,其吸附率可达99.2%。mPPA对Cd(Ⅱ)的吸附动力学符合准二级动力学方程;该吸附为自发进行的吸热过程,属于物理吸附和化学吸附的协同作用,但以物理吸附为主。 展开更多
关键词 粉末状聚苯乙烯气凝胶 层次孔纳米结构 表面改性 (ii)离子 吸附
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Usage of Iranian scoria for copper and cadmium removal from aqueous solutions
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作者 Sara Seyfi Amir Reza Azadmehr +1 位作者 Mahdi Gharabaghi Abbas Maghsoudi 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第10期3760-3769,共10页
The competitive removal of copper and cadmium from aqueous solutions using scoria has been investigated. Scoria was characterized by various methods, such as XRD, XRF, FT-IR and SEM. The results show that scoria sampl... The competitive removal of copper and cadmium from aqueous solutions using scoria has been investigated. Scoria was characterized by various methods, such as XRD, XRF, FT-IR and SEM. The results show that scoria sample contained augite, enstatite, diopside, and olivine. These minerals were separated from each other and each mineral was then subjected to the adsorption experiments. It was found that the main absorbent constituent in scoria was augite. Finally, statistical experimental method was used to optimization of adsorption conditions(Initial concentration of copper and cadmium ions, the amount of scoria and temperature) for removal of Cu(II) and Cd(II) ions from solution in optimum conditions. The optimum conditions are obtained as follows: concentrations of Cu(II) and Cd(II) of 400×10-6 and 554×10-6, respectively; amount of scoria of 7 g; temperature of 38 ℃. Under these conditions Cu(II) and Cd(II) ions are absorbed onto the scoria more than 79% and 16%, respectively. 展开更多
关键词 SCORIA ADSORPTION REMOVAL factorial design
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