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火花放电原子发射光谱仪快速测定合金饰品中镉元素方法研究
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作者 沈方红 沈霞 +2 位作者 陈旭来 蒋伟 蔡海兵 《上海化工》 CAS 2018年第5期20-23,共4页
镉是一种毒性较强的重金属元素,过量的镉元素会伤害人体、污染环境。采用火花源原子发射光谱法快速测定铜合金及铝合金饰品中镉的质量分数,采用单因素法筛选出最佳测试条件(铜合金冲洗时间为3 s、预燃时间为25 s、曝光时间为4 s;铝合金... 镉是一种毒性较强的重金属元素,过量的镉元素会伤害人体、污染环境。采用火花源原子发射光谱法快速测定铜合金及铝合金饰品中镉的质量分数,采用单因素法筛选出最佳测试条件(铜合金冲洗时间为3 s、预燃时间为25 s、曝光时间为4 s;铝合金冲洗时间为3 s、预燃时间为11 s、曝光时间为4 s)。实验结果表明该法的精密度和准确度均符合相关标准要求。随机抽取合金饰品产品对测试结果进行风险评估,发现部分样品含镉元素,最高质量分数为0.004 5%(标准限值为0.01%),来源主要是原材料及电镀工艺,属可控因素。 展开更多
关键词 火花放电 原子发射光谱 铜合金 铝合金 镉质量分数
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Effects of Soil pH,Texture,Moisture,Organic Matter and Cadmium Contenton Cadmium Diffusion Coefficient 被引量:7
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作者 WUQI-TANG J.L.MOREL 《Pedosphere》 SCIE CAS CSCD 1994年第2期97-103,共7页
The supply of cadmium from soil to plant roots mainly depends on the diffusion process. This work was conducted tostudy the effect of some soil properties on cadmium diffusion coefficient (D) in soil. Measurements we... The supply of cadmium from soil to plant roots mainly depends on the diffusion process. This work was conducted tostudy the effect of some soil properties on cadmium diffusion coefficient (D) in soil. Measurements were made using the Shofield and Graham-Bryce's isotopic labelling method. Cadmium diffusion coefficients varied from 10 ̄(-7) to 10 ̄(-9) cm ̄2s ̄(-1),Higher values were observed in acid sandy soils and lower values in calcareous clay soils. Liming an acid soil resulted in a sub-stantial decrease of D. Addition of cadmium as nitrate salt generally increased D, while addition of sewage sludge and organ-ic matter resulted in a significant decrease of cadmium diffusion. The rhizospheric activity also induced a moderate reduction in D. The relationships between D 10 ̄(-9)cm ̄2s ̄(-1)) on the one hand and soil PH, moisture (Mc, g kg ̄(-1)), organic matter (OM, gkg ̄1 ), clay (Cy, g kg ̄(-1)) and cadmium content (Cd, mg kg ̄(-1)) on the other were obtained by the multigle regression:D=182. 1-29.g1 pH+0.210Mc-0.303OM+0.011Cy+1.64Cd (R ̄2=0.859,n=22 ). 展开更多
关键词 CADMIUM corn rhizosphere diffusion coefficient soil properties
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