By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consist...By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consisted of sword-like nanobelts and toothed nanosaws with a single-crystal hexagonal wurtzite structure. The deposition temperature played an important role in determining the size and morphology of the CdS nanostruetures. A combination of vapor-liquid-solid and vapor-solid growth mechanisms were proposed to interpret the formation of CdS nanostructures. Photoluminescence measurement indicated that the nanobelts and nanosaws have a prominent green emission at about 512 nm, which is the band-to-band emission of CdS. The waveguide characteristics of both types of CdS nanos-truetures were observed and discussed.展开更多
Up to now, the evaporation and condensation, as well as the biological absorption and inorganic absorptions, have been proved to be major factors in Cd isotope fractionation. And Cd isotopes have been widely applied i...Up to now, the evaporation and condensation, as well as the biological absorption and inorganic absorptions, have been proved to be major factors in Cd isotope fractionation. And Cd isotopes have been widely applied in studies on the universal evolution and marine environment and so on. However, only a few researches have been conducted in applying Cd isotopes to trace the source of metallogenic material and the evolution of the ore-forming fluid in a complex mineralization environment, especially in a hydrothermal ore-formation system. We measured the Cd isotopic compositions of sphalerite, galena, and ores from five lead-zinc deposits in SW China, and found that the ~14/11~Cd values varied from -1.53%o to 0.34%0, with a total range of 1.87%o, which is greater than most of measured geological samples. Meanwhile, through contrasting the Cd content with Cd isotopic compositions of different deposits, it may be concluded that different genetic lead-zinc deposits have different Cd content and isotopic compositions, which could be a tool for the studies on the origin of ore deposits. Also, the biominera]iza- tion and crystal fractionation may also result in Cd isotope fractionation. In a word, although the research of Cd isotopes is presently at the preliminary stage （especially in hydrothermal ore-formation system）, this study demonstrated that Cd isotopes can give a clue in tracing the evolution of ore-forming fluid and metallogenic environment.展开更多
文摘By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consisted of sword-like nanobelts and toothed nanosaws with a single-crystal hexagonal wurtzite structure. The deposition temperature played an important role in determining the size and morphology of the CdS nanostruetures. A combination of vapor-liquid-solid and vapor-solid growth mechanisms were proposed to interpret the formation of CdS nanostructures. Photoluminescence measurement indicated that the nanobelts and nanosaws have a prominent green emission at about 512 nm, which is the band-to-band emission of CdS. The waveguide characteristics of both types of CdS nanos-truetures were observed and discussed.
基金supported by National Basic Research Program of China(Grant No.2009CB421005)Chinese Academy of Sciences for Key Topics in Innovation Engineering(Grant No.KZCX2-YW-Q04-01)
文摘Up to now, the evaporation and condensation, as well as the biological absorption and inorganic absorptions, have been proved to be major factors in Cd isotope fractionation. And Cd isotopes have been widely applied in studies on the universal evolution and marine environment and so on. However, only a few researches have been conducted in applying Cd isotopes to trace the source of metallogenic material and the evolution of the ore-forming fluid in a complex mineralization environment, especially in a hydrothermal ore-formation system. We measured the Cd isotopic compositions of sphalerite, galena, and ores from five lead-zinc deposits in SW China, and found that the ~14/11~Cd values varied from -1.53%o to 0.34%0, with a total range of 1.87%o, which is greater than most of measured geological samples. Meanwhile, through contrasting the Cd content with Cd isotopic compositions of different deposits, it may be concluded that different genetic lead-zinc deposits have different Cd content and isotopic compositions, which could be a tool for the studies on the origin of ore deposits. Also, the biominera]iza- tion and crystal fractionation may also result in Cd isotope fractionation. In a word, although the research of Cd isotopes is presently at the preliminary stage （especially in hydrothermal ore-formation system）, this study demonstrated that Cd isotopes can give a clue in tracing the evolution of ore-forming fluid and metallogenic environment.
