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不同组合配位剂对化学镀镍−钨−磷合金的影响 被引量:1
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作者 吕小虎 沈岳军 +2 位作者 苏琪 姚助 刘定富 《电镀与涂饰》 CAS 北大核心 2021年第4期263-268,共6页
以柠檬酸钠为主要配位剂,乳酸、甘氨酸、硫酸铵分别为辅助配位剂,在硬铝上二次浸锌后化学镀Ni-W-P合金。基础镀液和工艺条件为:NiSO_(4)·6H_(2)O 20 g/L,Na_(2)WO_(4)·2H_(2)O 20 g/L,NaH_(2)PO_(2)·H_(2)O 30 g/L,CH_(3... 以柠檬酸钠为主要配位剂,乳酸、甘氨酸、硫酸铵分别为辅助配位剂,在硬铝上二次浸锌后化学镀Ni-W-P合金。基础镀液和工艺条件为:NiSO_(4)·6H_(2)O 20 g/L,Na_(2)WO_(4)·2H_(2)O 20 g/L,NaH_(2)PO_(2)·H_(2)O 30 g/L,CH_(3)COONa·3H_(2)O 20 g/L,硫脲2 mg/L,pH 8.0,温度85℃,时间1 h。研究了不同配位剂组合对化学镀Ni-W-P合金沉积速率及镀层显微硬度和孔隙率的影响。结果表明,使用30 g/L柠檬酸钠+10 mL/L乳酸时,所得镀层的孔隙率最低,为0.63个/cm^(2);使用30 g/L柠檬酸钠+10 g/L甘氨酸时,镀层的显微硬度较单一使用柠檬酸钠时有所提高;使用30 g/L柠檬酸钠+25 g/L硫酸铵时,沉积速率最高,为14.69 mg/(cm^(2)·h),镀层的显微硬度高达786.9 HV。 展开更多
关键词 镍−−磷合金 化学镀 配位剂 沉积速率 显微硬度 孔隙率
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高压开关断路器操动机构化学镀镍−钨−磷三元合金及镀层性能
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作者 刘超峰 王斌 +5 位作者 曲欣 李宁 王珊 陈思远 刘拥军 杨晓颖 《电镀与涂饰》 CAS 北大核心 2023年第19期8-12,共5页
针对高压开关断路器机构上的液压缸、活塞杆等零部件加工精度要求高,面临磨损、高油压、腐蚀等复杂工况的问题,以高压开关机构零部件常用的45钢为基体,进行Ni-W-P三元合金化学镀。考察了Ni-W-P合金镀层的显微形貌、耐蚀性、显微硬度和... 针对高压开关断路器机构上的液压缸、活塞杆等零部件加工精度要求高,面临磨损、高油压、腐蚀等复杂工况的问题,以高压开关机构零部件常用的45钢为基体,进行Ni-W-P三元合金化学镀。考察了Ni-W-P合金镀层的显微形貌、耐蚀性、显微硬度和耐磨性。结果显示,化学镀Ni-W-P合金镀层的综合性能优于电镀Zn-Ni合金,并且能够通过样机试验,有望替代现有的电镀Zn-Ni合金工艺。 展开更多
关键词 高压开关断路器 镍−−磷三元合金 化学镀 耐磨性
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CNTs/Ni-W/CC复合电极的构筑及电解水析氢催化性能 被引量:1
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作者 施嘉伦 盛敏奇 马凯文 《电镀与涂饰》 CAS 北大核心 2021年第7期501-506,共6页
在碳布材料(CC)表面首先电沉积W原子分数约为13%的Ni-W合金,再通过化学气相沉积(CVD)在其表面生长碳纳米管(CNTs),构筑出一种自支撑CNTs/Ni-W/CC复合电极。电化学测试表明:该复合电极在1 mol/L NaOH水溶液中表现出良好的电解水析氢(HER... 在碳布材料(CC)表面首先电沉积W原子分数约为13%的Ni-W合金,再通过化学气相沉积(CVD)在其表面生长碳纳米管(CNTs),构筑出一种自支撑CNTs/Ni-W/CC复合电极。电化学测试表明:该复合电极在1 mol/L NaOH水溶液中表现出良好的电解水析氢(HER)催化性能。在不同温度下保温2 h所获样品中,900°C保温后的样品具有最佳析氢催化活性,其在10 mA/cm2阴极电流密度下的HER过电位为118.2 mV,Tafel斜率为97.4 mV/dec,并且其阴极电流密度在较高的阴极过电位下可超越商用Pt/C材料。此外,在持续的电催化反应工作过程中,该样品的HER催化活性可长期保持稳定。 展开更多
关键词 镍−钨合金 电沉积 碳纳米管 化学气相沉积 碳布 复合电极 析氢反应 电化学催化
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Microstructural evolution and mechanical properties of TIG welded superalloy GH625 被引量:5
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作者 顾玉丽 陶春虎 +1 位作者 魏振伟 刘昌奎 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第1期100-106,共7页
The tungsten inert gas welding(TIG) technique was employed to weld the nickel-based wrought superalloy GH625, and the microstructures, element distribution, grain boundary character and mechanical properties of the ... The tungsten inert gas welding(TIG) technique was employed to weld the nickel-based wrought superalloy GH625, and the microstructures, element distribution, grain boundary character and mechanical properties of the welded joint were investigated systematically. The results indicated that the welded seam was of austenite dendrite crystal structure and no obvious heat affected zone(HAZ) was observed. A number of precipitated δ phases with homogeneous distribution were observed in the interdendritic region of the weld fusion zone. The abnormal phenomenon observed in the weld fusion zone of GH625, i.e., higher hardness and larger grain size compared with the base metal, may be attributed to the precipitated δ phase in the weld fusion zone. The higher tensile strength in the base metal was mainly attributed to the presence of more contents of fine grains and twin boundaries, while the lower elongation in the welded joint was mainly owing to the precipitated δ phase. 展开更多
关键词 nickel-based wrought superalloy TIG welding microstructure MICROHARDNESS tensile property
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Mechanical behaviors of NiAl-Cr(Mo)-based near eutectic alloy with Ti, Hf, Nb and W additions 被引量:4
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作者 汤林志 张志刚 +1 位作者 李树索 宫声凯 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第2期212-216,共5页
Effects of Ti, Hf, Nb and W alloying elements addition on the microstructure and the mechanical behaviors of NiAl-Cr(Mo) intermetallic alloy were investigated by means of XRD, SEM, EDX and compression tests. The res... Effects of Ti, Hf, Nb and W alloying elements addition on the microstructure and the mechanical behaviors of NiAl-Cr(Mo) intermetallic alloy were investigated by means of XRD, SEM, EDX and compression tests. The results show that Ni-31Al-30Cr-4Mo-2(Ti, Hf, Nb, W) alloy consists of four phases: NiAl, ??Cr solid solution, Cr2Nb and Ni2Al(Ti, Hf). The mechanical properties are improved significantly compared with the base alloy. The compression yield strength at 1 373 K is 467 MPa and the room temperature compression ductility is 17.87% under the strain rate of 5.56??0-3 s-1, due to the existence of Cr2Nb and Ni2Al(Ti, Hf) phases for strengthening and Ti solid solution in NiAl matrix and coarse Cr(Mo, W) solid solution phase at cellular boundaries for ductility. The elevated temperature compression deformation behavior of the alloy can be properly described by power-law equation: ε=0.898 σ8.47exp[-615/(RT)]. 展开更多
关键词 NiAl-Cr(Mo)-based alloy Heusler phase Cr(Mo W) solid solution mechanical properties
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Inconel 617 and Stellite 6 alloys for tooling in thixoforming of steels 被引量:18
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作者 Y.BI ROL 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第9期1656-1662,共7页
Thermal fatigue and high temperature wear are the two principle failure mechanisms for thixoforming dies. Samples of Inconel 617 and Stellite 6 alloys were submitted to thermal cycling under conditions which approxima... Thermal fatigue and high temperature wear are the two principle failure mechanisms for thixoforming dies. Samples of Inconel 617 and Stellite 6 alloys were submitted to thermal cycling under conditions which approximate thixoforming of steels and to sliding wear tests at 750 ℃. The experimental results thus obtained were compared with those of the X32CrMoV33 hot work tool steel. The Inconel 617 and Stellite 6 samples are much more resistant to oxidation and to softening than the hot work tool steel, providing a superior resistance to thermal fatigue cracking. The wear resistance of the Inconel 617 and Stellite 6 alloys at 750 ℃ is also markedly superior. The adhesive oxides growing slowly on Inconel 617 and Stellite 6 alloys sustain the wear action without spalling and are claimed to be responsible for the superior wear resistance of these alloys at 750 ℃. 展开更多
关键词 steel THIXOFORMING TOOLING thermal fatigue WEAR
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Dynamic mechanical characterization and optimization of particle-reinforced W-Ni-Fe composites
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作者 SONG WeiDong NING JianGuo 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第9期1651-1658,共8页
A visco-plastic rate-dependent homogenization theory for particle-reinforced composites was derived and the equivalent elastic constants and the equivalent visco-plastic parameters of these composites were obtained. A... A visco-plastic rate-dependent homogenization theory for particle-reinforced composites was derived and the equivalent elastic constants and the equivalent visco-plastic parameters of these composites were obtained. A framework of homogenization the- ory for particle-reinforced W-Ni-Fe composites, a kind of tungsten alloy, was established. Based on the homogenization theory and a fixed-point iteration method, a unit cell model with typical microstructnres of the composite was established by using dynamic analysis program. The effects of tungsten content, tungsten particle shape and particle size and interface strength on the mechanical properties and the crack propagation of the W-Ni-Fe composite are analyzed under quasi-static and dynamic loadings. The stress-strain curves of the composite are given and the relation between the macro-mechanical characteristics and the microstructure parameters is explored, which provides an important theoretical basis for the optimization of the W-Ni-Fe composites. 展开更多
关键词 W Ni Fe composite dynamic mechanical property microstructure homogenization theory optimization
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