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裂解汽油一段镍基加氢催化剂LY-2008 被引量:6
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作者 梁顺琴 吴杰 王廷海 《石油科技论坛》 2013年第1期45-47,68,共3页
国内裂解汽油加氢装置一段加氢催化剂主要有贵金属钯基催化剂和非贵金属镍基催化剂两种。由于近年国内部分厂家裂解汽油性质恶化,催化剂加氢负荷提高,杂质含量增高,造成钯基催化剂适应性不足,镍系催化剂应用日趋广泛,市场规模迅速扩大... 国内裂解汽油加氢装置一段加氢催化剂主要有贵金属钯基催化剂和非贵金属镍基催化剂两种。由于近年国内部分厂家裂解汽油性质恶化,催化剂加氢负荷提高,杂质含量增高,造成钯基催化剂适应性不足,镍系催化剂应用日趋广泛,市场规模迅速扩大。中国石油兰州化工研究中心成功研制的新型镍基裂解汽油一段选择性加氢催化剂LY-2008,通过添加助剂消除传统催化剂中的镍铝尖晶石结构,从而弱化了活性组分Ni的吸附性能,提高了催化剂的加氢选择性。该催化剂用于中间馏分和全馏分裂解汽油的一段加氢,具有高选择性、良好的加氢活性、较强的稳定性能及操作平稳等特点,拥有较好的推广前景。 展开更多
关键词 镍基加氢催化剂LY-2008
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不同载体负载的Ni基加氢催化剂对生物油加氢裂化制备芳香烃的影响研究 被引量:2
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作者 于泰莅 蔡勤杰 张素平 《可再生能源》 CAS CSCD 北大核心 2022年第6期711-718,共8页
文章对一个两段式生物油加氢裂化过程进行研究,考察了不同载体(SiO_(2),ZrO_(2),CeO_(2)和Al_(2)O_(3))负载的Ni基催化剂的影响。反应过程中引入协同反应物甲醇,在裂化阶段进行二次供氢,与温和加氢的供氢作用联合抑制生物油加氢裂化的... 文章对一个两段式生物油加氢裂化过程进行研究,考察了不同载体(SiO_(2),ZrO_(2),CeO_(2)和Al_(2)O_(3))负载的Ni基催化剂的影响。反应过程中引入协同反应物甲醇,在裂化阶段进行二次供氢,与温和加氢的供氢作用联合抑制生物油加氢裂化的结焦。研究发现,Ni/金属氧化物催化剂上的酸性位能够与Ni协同作用促进生物油中酚类的加氢转化,从而使其在低生物油水相/甲醇掺混比下具有较好表现;过多的酸性位会强化气化反应,同时较强的酸性位会促进结焦,这都会降低目标产物芳香烃的产率。受这些因素的影响,当生物油水相/甲醇掺混比为2∶1时,基于Ni/SiO_(2)和Ni/Al_(2)O_(3)的加氢裂化过程的油相产率均约为13.4%,Ni/CeO_(2)加氢裂化过程的油相产率约为16.2%。Ni/ZrO_(2)具有合适的酸性位数量,使其在提高整体加氢效率的同时尽可能削弱了气化和结焦副反应,在生物油水相/甲醇掺混比为2∶1时具有最佳表现,油相产物产率约为19.3%,且油相产物中芳香烃的含量在95%以上。 展开更多
关键词 芳香烃 生物油 共裂化 镍基加氢催化剂 甲醇
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Development of Light Cycle Oil(LCO) Hydrocracking Technology over a Commercial W-Ni Based Catalyst 被引量:9
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作者 Peng Chong Yang Xuejing +4 位作者 Fang Xiangchen Huang Xinlu Cheng Zhenmin Zeng Ronghui Guo Rong 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2015年第4期30-36,共7页
Because of its high density and low cetane number, the light cycle oil(LCO) containing heavy aromatics(60%—80%) can hardly be transformed through the conventional hydro-upgrading technology. In this report, a novel L... Because of its high density and low cetane number, the light cycle oil(LCO) containing heavy aromatics(60%—80%) can hardly be transformed through the conventional hydro-upgrading technology. In this report, a novel LCO hydrocracking technology(FD2G) was proposed for the utilization of LCO to manufacture high value-added products. Through the ingenious combination of hydroprocessing catalyst and the hydrocracking process, the high octane gasoline and the ultra-low sulfur diesel(ULSD) blendstocks were produced simultaneously. The influence of catalyst type, reaction temperature, pressure, respectively, on the research octane number(RON) of produced gasoline was studied in a fixed bed hydrogenation reactor. It indicated that high reaction temperature and medium pressure would favor the production of highoctane gasoline through the conversion of bi-aromatic and tri-aromatic hydrocarbons. The typical results of FD2 G technology on commercial units showed that it could produce clean diesel with a sulfur content of less than 10 μg/g and clean gasoline with a research octane number(RON) of up to 92. It would be contributed to the achievement of the maximum profit of a refinery, the FD2 G technology could provide a higher economic efficiency than the other diesel quality upgrading technology under the current gasoline and diesel price system. 展开更多
关键词 LCO hydrocracking high octane gasoline ULSD aromatics
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Multiple Confined-Zone-Based Nickel Hydrogenation Catalyst Made by Shanxi Institute of Coal Chemistry
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《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2015年第4期19-19,共1页
The Shanxi Institute of Coal Chemistry,Chinese Academy of Sciences has designed and prepared a multiple confined-zone-based nickel hydrogenation catalyst by means of the atomic layer deposition(ALD)technology.In compa... The Shanxi Institute of Coal Chemistry,Chinese Academy of Sciences has designed and prepared a multiple confined-zone-based nickel hydrogenation catalyst by means of the atomic layer deposition(ALD)technology.In comparison with the non-confined-zone based catalyst,the multiple confined-zone-based nickel catalyst possesses an enhanced catalytic reactivity and catalytic stability for hydrogenation of cinnamaldehyde and nitrobenzene. 展开更多
关键词 Shanxi confined hydrogenation reactivity nickel nitrobenzene calcination template synthesize sized
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