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改进的M-MIVM在镍基固态合金中的应用 被引量:1
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作者 姚春玲 刘振楠 +2 位作者 刘聪 龙晓波 程涌 《有色金属工程》 CAS 北大核心 2022年第5期58-66,74,共10页
合金的热力学性质在材料科学和工程中起着重要的作用。对于复杂体系,利用灵活可靠的热力学模型进行理论计算具有重要价值和科学意义。改进的M-MIVM能够同时表达分子构型的微观状态数(熵)和分子相互作用(焓)对过量吉布斯自由能的贡献,具... 合金的热力学性质在材料科学和工程中起着重要的作用。对于复杂体系,利用灵活可靠的热力学模型进行理论计算具有重要价值和科学意义。改进的M-MIVM能够同时表达分子构型的微观状态数(熵)和分子相互作用(焓)对过量吉布斯自由能的贡献,具有坚实的物理基础,可预测实际固溶体的热力学性质。该模型的一个显著优点在于仅利用二元无限稀活度系数或二元活度数据就可以描述和预测多元固溶体的热力学性质。利用改进的M-MIVM对Au-Ni、Co-Ni、Cr-Ni、Cu-Ni、Fe-Ni、Ni-Pd、Ni-Pt、Ni-V、Co-Fe、Cr-Fe、Co-Fe-Ni、Cr-Fe-Ni、C-Co-Fe-Ni系等固溶体合金的活度进行了预测。结果表明,除Cr-Ni、Ni-V两个二元非连续固溶体外,其余体系的活度模型预测值与实验数据吻合较好,13个体系总的相对平均偏差仅为4.75%,且预测效果优于MIVM,能够满足工程计算要求。改进的M-MIVM在镍基固态合金应用中具有一定的准确性、稳定性和适用性,可为镍基合金设计提供较为可靠的热力学数据。 展开更多
关键词 热力学模型 改进的M-MIVM 镍基固态合金 热力学活度
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High temperature deformation behavior and microstructure evolution of wrought nickel-based superalloy GH4037 in solid and semi-solid states 被引量:6
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作者 Ju-fu JIANG Guan-fei XIAO +2 位作者 Ying WANG Ying-ze LIU Ying ZHANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第3期710-726,共17页
Cylindrical samples of Ni-based GH4037 alloy were compressed at solid temperatures(1200,1250 and 1300℃) and semi-solid temperatures(1340,1350,1360,1370 and 1380℃) with different strain rates of 0.01,0.1 and 1 s-1.Hi... Cylindrical samples of Ni-based GH4037 alloy were compressed at solid temperatures(1200,1250 and 1300℃) and semi-solid temperatures(1340,1350,1360,1370 and 1380℃) with different strain rates of 0.01,0.1 and 1 s-1.High temperature deformation behavior and microstructure evolution of GH4037 alloy were investigated.The results indicated that flow stress decreased rapidly at semi-solid temperatures compared to that at solid temperatures.Besides,the flow stress continued to increase after reaching the initial peak stress at semi-solid temperatures when the strain rate was 1 s-1.With increasing the deformation temperature,the size of initial solid grains and recrystallized grains increased.At semi-solid temperatures,the grains were equiaxed,and liquid phase existed at the grain boundaries and inside the grains.Discontinuous dynamic recrystallization(DDRX) characterized by grain boundary bulging was the main nucleation mechanism for GH4037 alloy. 展开更多
关键词 nickel-based superalloy high temperature deformation SEMI-SOLID microstructure evolution dynamic recrystallization
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