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EDTA滴定法测定镍-铬-铝-钇合金粉中的铝 被引量:6
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作者 李辉 陈明 《冶金分析》 CAS CSCD 北大核心 2003年第1期51-53,共3页
提出测定镍 铬 铝 钇合金粉中铝的方法。试样经硝酸 -盐酸溶解后 ,高氯酸冒烟盐酸除铬 ,在 pH5~ 6的六次甲基四胺缓冲介质中 ,以 5 Br PADAP、乳化剂OP和Tween 80作混合指示剂 ,用铜标准溶液滴定以 [BF4 ] - 置换Al EDTA中的EDTA ... 提出测定镍 铬 铝 钇合金粉中铝的方法。试样经硝酸 -盐酸溶解后 ,高氯酸冒烟盐酸除铬 ,在 pH5~ 6的六次甲基四胺缓冲介质中 ,以 5 Br PADAP、乳化剂OP和Tween 80作混合指示剂 ,用铜标准溶液滴定以 [BF4 ] - 置换Al EDTA中的EDTA ,间接计算出铝的含量。方法简便 ,终点敏锐 ,分析结果令人满意。 展开更多
关键词 EDTA滴定法 测定 镍-铬-铝-钇合金粉
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EB-PVD沉积Ni-Cr-Al合金的组织和力学性能的研究 被引量:4
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作者 关春龙 赫晓东 +1 位作者 李垚 孙晔 《航空材料学报》 EI CAS CSCD 2005年第1期11-14,共4页
利用电子束物理气相沉积(EB-PVD)方法制备出厚度为0.5mm的Ni-Cr-Al高温合金。研究了该合金在制备状态和长期时效后的显微组织及其力学性能。结果表明,制备态合金表面的晶粒尺寸约为185nm,并且材料断面呈层状结构。合金在760℃下时效16h,... 利用电子束物理气相沉积(EB-PVD)方法制备出厚度为0.5mm的Ni-Cr-Al高温合金。研究了该合金在制备状态和长期时效后的显微组织及其力学性能。结果表明,制备态合金表面的晶粒尺寸约为185nm,并且材料断面呈层状结构。合金在760℃下时效16h,72h和120h后,材料断面的层状结构消失,且明显看到晶粒的存在。合金时效16h后,在靠近基板一侧形成柱状晶,但远离基板一侧为等轴晶。760℃长时间时效形成的主要强化相为γ'相。断口结果表明,制备态合金室温断口为混合型断口,接近基板一侧发生沿柱状晶边界的脆性断裂,而在另一侧为韧窝为主的韧性断裂。材料经长时间的真空时效后,断口由脆性断口转变为韧性断口。合金的室温显微硬度随时效时间的增加而下降,这是由于γ'相不断长大所引起。与制备态合金相比,时效后合金的力学性能明显改善。 展开更多
关键词 电子束物理气相沉积 显微组织 力学性能 柱状晶 镍-铬-铝 高温合金 航空材料
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Mechanical behaviors of NiAl-Cr(Mo)-based near eutectic alloy with Ti, Hf, Nb and W additions 被引量:4
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作者 汤林志 张志刚 +1 位作者 李树索 宫声凯 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第2期212-216,共5页
Effects of Ti, Hf, Nb and W alloying elements addition on the microstructure and the mechanical behaviors of NiAl-Cr(Mo) intermetallic alloy were investigated by means of XRD, SEM, EDX and compression tests. The res... Effects of Ti, Hf, Nb and W alloying elements addition on the microstructure and the mechanical behaviors of NiAl-Cr(Mo) intermetallic alloy were investigated by means of XRD, SEM, EDX and compression tests. The results show that Ni-31Al-30Cr-4Mo-2(Ti, Hf, Nb, W) alloy consists of four phases: NiAl, ??Cr solid solution, Cr2Nb and Ni2Al(Ti, Hf). The mechanical properties are improved significantly compared with the base alloy. The compression yield strength at 1 373 K is 467 MPa and the room temperature compression ductility is 17.87% under the strain rate of 5.56??0-3 s-1, due to the existence of Cr2Nb and Ni2Al(Ti, Hf) phases for strengthening and Ti solid solution in NiAl matrix and coarse Cr(Mo, W) solid solution phase at cellular boundaries for ductility. The elevated temperature compression deformation behavior of the alloy can be properly described by power-law equation: ε=0.898 σ8.47exp[-615/(RT)]. 展开更多
关键词 NiAl-Cr(Mo)-based alloy Heusler phase Cr(Mo W) solid solution mechanical properties
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Oxidation behaviors of Ni-Cr-Al superalloy foams at 1 000 °C in air
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作者 汤慧萍 王岩 +2 位作者 刘咏 李维杰 韩朝 《Journal of Central South University》 SCIE EI CAS 2013年第12期3345-3353,共9页
The oxidation behaviors of Ni-16Cr-xAl (x=4.5%, 9.0%, mass fraction) superalloy foams in air at 1000℃ were investigated. The effects of AI content on the resistance to high temperature oxidation were examined. The ... The oxidation behaviors of Ni-16Cr-xAl (x=4.5%, 9.0%, mass fraction) superalloy foams in air at 1000℃ were investigated. The effects of AI content on the resistance to high temperature oxidation were examined. The oxidation mechanisms of the foams were discussed. The results show that the resistance to the oxidation of the Ni-16Cr-xA1 based alloy at 1 000 ℃ increases with the content of A1 increasing from 4.5% to 9.0%. Complex oxide products are formed on the surface of the superalloy foams after the oxidation. Cr203 and A1203 are the predominant oxides for the scales of the foams with 4.5% A1 and 9% A1, respectively. Excellent high temperature oxidation resistance and superior pore conformation stability for the Ni-16Cr-xA1 based superalloy foam with 9% A1 can be mainly attributed to the formation of relatively continuous and protective A1203 oxides on the surface of the foam. 展开更多
关键词 Ni-Cr-A1 based superalloy foam high temperature oxidation oxide scale pore conformation stability
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磁控溅射AlCrFeNiTi高熵合金薄膜的组织和表面形貌 被引量:3
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作者 张微 刘亮 +4 位作者 商剑 赵作福 张越 齐锦刚 王冰 《电镀与涂饰》 CAS 北大核心 2021年第19期1489-1493,共5页
用直流磁控溅射法在单晶硅片上制备了AlCrFeNiTi高熵合金薄膜,采用X射线衍射仪、扫描电镜和原子力显微镜考察了溅射参数对薄膜结构及表面形貌的影响。结果表明,当溅射功率一定,随着衬底温度升高,AlCrFeNiTi高熵合金薄膜由非晶向2个BCC... 用直流磁控溅射法在单晶硅片上制备了AlCrFeNiTi高熵合金薄膜,采用X射线衍射仪、扫描电镜和原子力显微镜考察了溅射参数对薄膜结构及表面形貌的影响。结果表明,当溅射功率一定,随着衬底温度升高,AlCrFeNiTi高熵合金薄膜由非晶向2个BCC相转变,衍射峰强度也随之增大,同时薄膜的结晶度提高,晶粒尺寸增大,导致薄膜粗糙度增加。当衬底温度一定时,随着溅射功率增大,X射线衍射峰强度大幅度上升,薄膜表面晶粒迅速长大,但因为溅射功率过大会导致表面形成缺陷,所以表面粗糙度先减小后增大。 展开更多
关键词 高熵合金 ---- 磁控溅射 功率 衬底温度 组织 表面形貌 粗糙度
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