There is presented the review of publications connecting with creation of matrices for the immobilization of long-lived radionuclides and radioactive waste for storage and disposal, as well as for the transmutation. T...There is presented the review of publications connecting with creation of matrices for the immobilization of long-lived radionuclides and radioactive waste for storage and disposal, as well as for the transmutation. This paper substantiates the practicability and feasibility of obtaining the carbon matrces by carbonization of imidoderivatives.展开更多
Half-sandwich zirconium complex 3 containing tridentate carborane [S,S,O] ligand 2 [(HOC6H2R2-4,6)(CH2)SC(B10H10) C(Ph)2P=S, R=tBu] was synthesized by the reaction of CpZrCl3(Cp=η5-C5H5) with sodium salt of ligand 2....Half-sandwich zirconium complex 3 containing tridentate carborane [S,S,O] ligand 2 [(HOC6H2R2-4,6)(CH2)SC(B10H10) C(Ph)2P=S, R=tBu] was synthesized by the reaction of CpZrCl3(Cp=η5-C5H5) with sodium salt of ligand 2. Zirconium complex 3 was characterized by elemental and NMR analyses. DFT calculations were also performed on complex 3 to analyze the stereochemistry. The results from DFT calculations indicate that structure S1, in which no sulfur atom bonds to the zirconium atom, exists at the lowest energy level. In the presence of methylaluminoxane(MAO), complex 3 exhibited good catalytic activities for ethylene polymerization and long life-time up to 10 h. Moreover, the complex 3/MAO system displayed excellent catalytic activities toword ethylene copolymerization with 1-hexene or polar olefins.展开更多
文摘There is presented the review of publications connecting with creation of matrices for the immobilization of long-lived radionuclides and radioactive waste for storage and disposal, as well as for the transmutation. This paper substantiates the practicability and feasibility of obtaining the carbon matrces by carbonization of imidoderivatives.
基金supported by the National Natural Science Foundation of China (91122017, 21374019)the Shanghai Science and Technology Committee (13JC1400600, 13DZ2275200)the Program for Changjiang Scholars and Innovative Research Team in University (IRT1117)
文摘Half-sandwich zirconium complex 3 containing tridentate carborane [S,S,O] ligand 2 [(HOC6H2R2-4,6)(CH2)SC(B10H10) C(Ph)2P=S, R=tBu] was synthesized by the reaction of CpZrCl3(Cp=η5-C5H5) with sodium salt of ligand 2. Zirconium complex 3 was characterized by elemental and NMR analyses. DFT calculations were also performed on complex 3 to analyze the stereochemistry. The results from DFT calculations indicate that structure S1, in which no sulfur atom bonds to the zirconium atom, exists at the lowest energy level. In the presence of methylaluminoxane(MAO), complex 3 exhibited good catalytic activities for ethylene polymerization and long life-time up to 10 h. Moreover, the complex 3/MAO system displayed excellent catalytic activities toword ethylene copolymerization with 1-hexene or polar olefins.
