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三维晶粒长大速率方程的大尺度Potts模型Monte carlo仿真验证 被引量:13
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作者 王浩 刘国权 秦湘阁 《金属学报》 SCIE EI CAS CSCD 北大核心 2008年第1期13-18,共6页
采用Potts模型Monte Carlo方法对3种现存的三维个体晶粒长大速率拓扑依赖性方程进行了仿真验证.结果表明,Rivier速率方程认为晶粒体积变化率dV_f/dt与晶粒面数f成线性关系,与仿真结果明显不符,不适用于描述三维晶粒长大过程的动力学.当... 采用Potts模型Monte Carlo方法对3种现存的三维个体晶粒长大速率拓扑依赖性方程进行了仿真验证.结果表明,Rivier速率方程认为晶粒体积变化率dV_f/dt与晶粒面数f成线性关系,与仿真结果明显不符,不适用于描述三维晶粒长大过程的动力学.当晶粒面数f(?)8时,Yu-Liu速率方程和MacPherson-Srolovitz速率方程均与仿真结果很好吻合,表明这两者均可以用来定量描述三维晶粒长大过程的动力学;当f<8时,这两个方程均与仿真结果有显著差异. 展开更多
关键词 三维晶粒长大 拓扑依赖性长大速率方程 POTTS模型 MONTE Caxlo仿真
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基于MacPherso-Srolovitz拓扑依赖速率方程的三维晶粒尺寸分布研究 被引量:5
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作者 王浩 刘国权 《金属学报》 SCIE EI CAS CSCD 北大核心 2008年第7期769-774,共6页
以MacPherson-Srolovitz提出的三维个体晶粒长大拓扑依赖速率方程以及三维晶粒组织的晶粒尺寸一晶粒面数间的抛物线型统计关系为基础,导出了相应的描述三维准稳态晶粒尺寸分布的函数族.采用纯Fe实验数据以及顶点法、基元演化法,相场模型... 以MacPherson-Srolovitz提出的三维个体晶粒长大拓扑依赖速率方程以及三维晶粒组织的晶粒尺寸一晶粒面数间的抛物线型统计关系为基础,导出了相应的描述三维准稳态晶粒尺寸分布的函数族.采用纯Fe实验数据以及顶点法、基元演化法,相场模型和Monte Carlo法进行了验证,结果表明,函数族中峰值左偏的函数适合三维准稳态晶粒尺寸分布的定量表述.将该函数与Liu等提出的2种三维准稳态晶粒尺寸分布函数进行的对比表明:此3种函数的解析表达形式有所不同,但其曲线图在一定条件下相互吻合.此外,MacPherson-Srolovitz三维拓扑依赖速率方程、Hillert三维速率方程及Yu-Liu三维速率方程尽管表达形式不同均能较好地反映三维正常晶粒长大的动力学规律. 展开更多
关键词 三维晶粒长大 准稳态晶粒尺寸分布 长大速率方程 计算机仿真
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TC21钛合金时效析出α相的长大动力学 被引量:2
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作者 余新平 董洪波 《机械工程材料》 CAS CSCD 北大核心 2015年第10期101-105,共5页
为研究TC21钛合金时效时析出α相的长大动力学,采用JMatPro软件模拟计算得到了钛合金时效相平衡时α相和β相的化学成分与时效温度的关系,计算得到了在500~900℃下等温时效时析出α相的长大速率与温度的关系式,并进行了试验验证。结果表... 为研究TC21钛合金时效时析出α相的长大动力学,采用JMatPro软件模拟计算得到了钛合金时效相平衡时α相和β相的化学成分与时效温度的关系,计算得到了在500~900℃下等温时效时析出α相的长大速率与温度的关系式,并进行了试验验证。结果表明:在750℃以下等温时效时,析出α相的长大速率较慢,时效温度高于800℃时,长大速率随温度升高而迅速增加,这是由合金元素的扩散系数随温度的变化而决定的;试验得到的TC21钛合金在900℃等温时效时析出α相的长大速率与模拟计算得到的结果一致,析出α相的生长速率随温度升高不断增大。 展开更多
关键词 TC21钛合金 时效温度 析出α相 长大速率
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磁化水对细颗粒水汽凝结长大的影响 被引量:3
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作者 张园园 张军 +1 位作者 尹杰 徐欢欢 《煤炭学报》 EI CAS CSCD 北大核心 2020年第12期4178-4183,共6页
为促进燃煤电厂烟气中细颗粒物水汽凝结长大,提高其脱除效率,提出了采用磁化水强化低过饱和度下颗粒长大效果的方法。以润湿性差的炭质颗粒为研究对象,测量了水磁化前后的表面张力变化以及对炭质颗粒接触角的影响;将热水与冷气溶胶接触... 为促进燃煤电厂烟气中细颗粒物水汽凝结长大,提高其脱除效率,提出了采用磁化水强化低过饱和度下颗粒长大效果的方法。以润湿性差的炭质颗粒为研究对象,测量了水磁化前后的表面张力变化以及对炭质颗粒接触角的影响;将热水与冷气溶胶接触形成过饱和环境,利用生长管实验研究了磁化水和普通水条件下炭质颗粒的水汽相变长大特性;基于经典异质核化理论,计算了磁化水对炭质颗粒长大所需的临界饱和度和过渡阶段长大速率的影响。实验结果表明:在800 mT磁场强度下,经过30 min循环磁化,水的表面张力降低了4.5 mN/m,与炭质颗粒的接触角降低了3°,炭质颗粒的润湿性得到改善;与普通水相比,磁化水条件下炭质颗粒几何平均粒径从原始的1.42μm长大到3μm以上,长大效果更佳,并且在较低过饱和水平下促进效果更明显。理论计算结果表明,在磁化水作用下,相同粒径的炭质颗粒异质凝结长大所需的临界饱和度明显下降,更有利于促进粒径较小的颗粒发生异质凝结;磁化水有助于提高低过饱和度下炭质颗粒过渡阶段的长大速率,磁化水条件下炭质颗粒过渡阶段的长大速率总是大于普通水;当生长管中过饱和水平较低时,相比于普通水,磁化水可明显提高过渡阶段炭质颗粒的长大速率,并且大颗粒凝结长大效果更好。磁化水耦合水汽相变技术将有助于促进炭质颗粒水汽凝结长大,间接提高烟气除尘效率。 展开更多
关键词 磁化水 细颗粒 临界饱和度 长大速率 水汽相变
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疲劳裂纹扩展的非平衡统计模型 被引量:2
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作者 胡海云 邢修三 《广西师范大学学报(自然科学版)》 CAS 2002年第1期60-63,共4页
为了研究金属中微观结构对疲劳裂纹扩展性能的影响 ,在建立的宏观与微观相结合的疲劳断裂非平衡统计理论中 ,考虑了材料微观结构因素 ,得到了包括疲劳短裂纹及长裂纹的整个金属疲劳寿命内的普适裂纹扩展速率公式 。
关键词 疲劳短裂纹 疲劳长裂纹 涨落长大速率 非平衡统计理论 裂纹扩展 非平衡统计断裂力学
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粒度分布信息在铝酸钠溶液加晶种分解动力学研究中的应用 被引量:4
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作者 张俊 张平民 +2 位作者 陈金清 尹周澜 陈启元 《广东有色金属学报》 2003年第1期21-26,共6页
阐述了在铝酸钠溶液加晶种分解的动力学研究中充分利用粒度分布信息的意义。通过分析铝酸钠溶液加晶种分解过程中固相产物的粒度分布情况,提出用(dN/dt)_(成核),(dN/dt))(附聚)和(dr/dt)_(径向长大)分别表示二次成核、附聚长大和晶粒径... 阐述了在铝酸钠溶液加晶种分解的动力学研究中充分利用粒度分布信息的意义。通过分析铝酸钠溶液加晶种分解过程中固相产物的粒度分布情况,提出用(dN/dt)_(成核),(dN/dt))(附聚)和(dr/dt)_(径向长大)分别表示二次成核、附聚长大和晶粒径向长大的速率,并分别得到了其速率表达式,采用微分法研究了晶粒径向长大,结果表明通过控制适当的反应条件,能够突出晶粒径向长大这一基本过程。利用粒度分布信息求得的晶粒径向长大速率与实际长大速率基本一致。 展开更多
关键词 氧化铝 拜耳法 铝酸钠溶液 粒度分布 晶粒长大 长大速率 动力学
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电场对纳米晶Fe基合金软磁性能的影响 被引量:1
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作者 钟海坚 唐建成 《江西化工》 2009年第1期5-6,共2页
本文通过分析外加电场对纳米晶合金的形核速率和晶粒长大速率的影响规律,探讨外加电场对纳米晶合金显微组织的优化,以期获得改善其软磁性能的可行性依据。
关键词 外加电场 形核速率 晶粒长大速率 体积分数 软磁性能
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热疲劳非平衡统计理论 被引量:5
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作者 王丽营 邢修三 《北京理工大学学报》 EI CAS CSCD 北大核心 2001年第2期151-156,共6页
用非平衡统计的概念和方法建立微观机理与宏观性能相结合的热疲劳理论 .给出了热疲劳微裂纹的演化方程 ,结合热应力公式和微裂纹演化的位错机理 ,求得了热疲劳微裂纹的长大速率和几率密度分布函数 .同时给出了与实验结果基本相符的微裂... 用非平衡统计的概念和方法建立微观机理与宏观性能相结合的热疲劳理论 .给出了热疲劳微裂纹的演化方程 ,结合热应力公式和微裂纹演化的位错机理 ,求得了热疲劳微裂纹的长大速率和几率密度分布函数 .同时给出了与实验结果基本相符的微裂纹平均长度随热循环周数变化的表达式 ,进而由热疲劳断裂几率得到了热疲劳寿命的解析表达式 ,最终得出温度差。 展开更多
关键词 热疲劳 微裂纹演化方程 微裂纹长大速率 热疲劳寿命
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Effect of ruthenium on γ' precipitation behavior and evolution in single crystal superalloys 被引量:4
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作者 刘丽荣 金涛 +2 位作者 刘金来 孙晓峰 胡壮麒 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第1期14-22,共9页
The effect of Ru on γ' precipitation behavior and evolution in single crystal superalloys with different Ru contents were investigated by scanning electron microscopy with energy dispersive spectroscopy,3D atomic pr... The effect of Ru on γ' precipitation behavior and evolution in single crystal superalloys with different Ru contents were investigated by scanning electron microscopy with energy dispersive spectroscopy,3D atomic probing,differential scanning calorimetry.The results show that the solvus of the γ' phase decreases gradually with increasing Ru content in the alloys by casting or by the same solution and aging treatments,the alloy with a larger Ru content yields a smaller γ' phase.The addition of Ru increases the growth rate and coarsening rate of the γ' phase.Ru mainly distributes in the γ phase,which causes more Re and Mo partition into the γ' phase,increasing the absolute value of mismatch and the rafting rate of the γ' phase. 展开更多
关键词 single crystal superalloy RUTHENIUM gamma prime PRECIPITATION growth rate coarsening rate MISMATCH
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Nonequilibrium Statistical Modeling of Fatigue Crack Growth Behaviour
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作者 胡海云 邢修三 《Journal of Beijing Institute of Technology》 EI CAS 2001年第3期240-245,共6页
In order to study the influence of microstructural texture on the growth of short fatigue cracks in metals, the nonequilibrium statistical theory of fatigue fracture correlating a microscopic mechanism with the macros... In order to study the influence of microstructural texture on the growth of short fatigue cracks in metals, the nonequilibrium statistical theory of fatigue fracture correlating a microscopic mechanism with the macroscopic properties is modified to take into consideration the microstructural features of a material, thereby allowing a rationalisation of the experimental data of short fatigue crack growth and long fatigue crack growth. The nonequilibrium statistical theory thus developed relates the growth of cracks with a dislocation mechanism to simulate short fatigue crack growth with the long fatigue crack growth behaviour and predicts the fatigue crack growth rates throughout the fatigue lifetime. The results is finally compared with that of other fatigue theories. 展开更多
关键词 short fatigue crack long fatigue crack fluctuation growth rate nonequilibrium statistical theory
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Culture techniques and growth characteristics of Dinophysis acuminata and its prey 被引量:1
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作者 佟蒙蒙 周启星 +3 位作者 KULIS M.David 江天久 齐雨藻 ANDERSON M.Donald 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2010年第6期1230-1239,共10页
The dinoflagellate Dinophysis acurninata Claparede & Lachrnann is a toxic alga that causes diarrhetic shellfish poisoning. No Dinophysis species were maintained in culture for a long period of time until 2006 when Pa... The dinoflagellate Dinophysis acurninata Claparede & Lachrnann is a toxic alga that causes diarrhetic shellfish poisoning. No Dinophysis species were maintained in culture for a long period of time until 2006 when Park successfully established D. acuminata in culture using a three-step feeding protocol in which the cryptophyte, Geminigera cryophila, is fed to Myrionecta rubra (=Mesodinium rubrum), a ciliate that is in turn fed to D. acuminata. In this paper, we present the details of culturing D. acuminata from the Northeastern United States. The protocols described herein can be adopted for laboratory studies of this species. The effects of temperature on the growth and ingestion rates of D. acuminata were also examined. The results show that D. acuminata growth rate was 0.23/d at 10℃ and 0.11/d at 4℃when fed M. rubra prey. The maximum prey ingestion rate was 2.80 Dinophysis cell/d at 10℃, although the rate decreased slightly at 4℃. In overall, temperature showed a greater influence on growth rate of D. acuminata than on the ingestion rate under the study conditions, and the quantity of available food was also an important regulator to D. acurninata growth. 展开更多
关键词 Dinophysis acuminata Myrionecta rubra Geminigera cryophila growth rate ingestion rate
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高温形变对精细钢丝用高碳钢盘条珠光体团尺寸的影响
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作者 郭大勇 高航 +3 位作者 潘阳 杨迎强 王秉喜 宫文赫 《金属热处理》 CAS CSCD 北大核心 2024年第4期146-149,共4页
开展了高温形变对高碳钢盘条珠光体组织转变和珠光体团尺寸影响的试验研究。结果表明,高温形变使珠光体的形核率和长大速率增加,奥氏体向珠光体的转变速率加快。高温形变使试样室温珠光体团细化,珠光体团尺寸分布均匀性得到提升。在形... 开展了高温形变对高碳钢盘条珠光体组织转变和珠光体团尺寸影响的试验研究。结果表明,高温形变使珠光体的形核率和长大速率增加,奥氏体向珠光体的转变速率加快。高温形变使试样室温珠光体团细化,珠光体团尺寸分布均匀性得到提升。在形变量分别为20%和40%条件下,相变时间为3 s时,试样的珠光体转变量由不形变条件下的11%增加到32%和53%;试样的珠光体团尺寸由不形变条件下的53.2μm降低到37.8μm和23.1μm,标准差由不形变条件下的29.9μm降低到11.8μm和7.9μm。实际生产可以通过提高轧制速度的方法,细化LX80A高碳钢盘条的珠光体团,降低盘条珠光体团尺寸分布标准差,从而提高盘条的拉拔性能。 展开更多
关键词 高碳钢 高温形变 珠光体团 形核和长大速率
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Primary study on respiration type of lingwu Changzao (Ziziphus. jujube Mill)
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作者 ZHANG Guang-di YU Xiao-yan +3 位作者 FENG Mei XU Wen-ping YANG Dong LIU Guo-hua 《Journal of Agricultural Science and Technology》 2009年第1期30-34,共5页
Lingwu Changzao (Ziziphus. jujube Mill) is a Ningxia local variety, it has a good table quality despite its short postharvest life. The respiration rate, the weight change of single fruit during growth development a... Lingwu Changzao (Ziziphus. jujube Mill) is a Ningxia local variety, it has a good table quality despite its short postharvest life. The respiration rate, the weight change of single fruit during growth development and the losing water of postharvest of fruit were studied. The results showed that the curve of fruit growth development was a double sigmoid characteristic. When the surface colour of fruit changed form jade-green to alizarin crimson, the respiration rate tended to fall during a entire growth development of fruit, which showed a fluctuation phenomenon. The respiration rate descended when the surface color changed from coloring to baby red, but after a crimson stage the respiration rate recurred to its original downtrend. With increasing of single fruit weight, phenomenon of respiration climacteric has not happened and the respiration rate curve showed a concavity characteristic at some stages. As a result, there was not a phenomenon of respiration climacteric with a double sigmoid growth development curve characteristic of fruit. 展开更多
关键词 Lingwu Changzao (Ziziphus. jujube Mill) respiration type fruit growth characteristics
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原位观察铌对高碳钢珠光体相变的影响 被引量:8
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作者 苏雪 王厚昕 +3 位作者 朱敏 张琪 田俊羽 徐光 《钢铁》 CAS CSCD 北大核心 2022年第4期88-96,共9页
为了研究微合金元素铌(Nb)对高碳钢中珠光体相变的影响,在高温激光共聚焦显微镜下原位观察了不含铌和含铌高碳钢连续冷却过程中珠光体动态形核和长大行为。结果表明,在高碳钢中添加铌增加了珠光体形核点的数量,这是因为铌提高珠光体单... 为了研究微合金元素铌(Nb)对高碳钢中珠光体相变的影响,在高温激光共聚焦显微镜下原位观察了不含铌和含铌高碳钢连续冷却过程中珠光体动态形核和长大行为。结果表明,在高碳钢中添加铌增加了珠光体形核点的数量,这是因为铌提高珠光体单位面积形核数量。同时,铌元素减慢珠光体长大速率是由于铌显著阻碍珠光体长大,但当铌质量分数超过0.014%后,阻碍珠光体长大速率的效果不再进一步增加。从以上结果可知,在高碳钢中添加铌促进珠光体形核,但是减慢珠光体长大速率。所以,为了更加准确地研究铌元素对珠光体相变的影响,选用不含铌及铌质量分数为0.027%的两种高碳钢,在Gleeble-3500热模拟试验机上进行与高温原位观察试验相同试验工艺的热膨胀试验。通过热膨胀试验发现,铌的添加增大过冷度,导致降低了珠光体相变温度区间,但是铌显著阻碍碳在奥氏体中的扩散系数,所以铌减慢珠光体长大速率。另外,铌减慢连续冷却条件下的珠光体相变动力学,推迟珠光体相变,从而降低珠光体相变速率,表明铌对珠光体长大的阻碍作用强于其对珠光体形核的促进作用。因此,在高碳钢中,铌元素的添加推迟珠光体相变。此外,铌的添加增大过冷度,使含铌高碳钢的珠光体片层细化,提高了含铌高碳钢的硬度,但在铌质量分数超过0.014%后,细化效果不再进一步增强。 展开更多
关键词 铌微合金化 高碳钢 原位观察 珠光体相变 珠光体长大速率
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Microstructural evolution and mechanism of grain growth in magnesia ceramics prepared by high pressure and temperature with ultra-high heating rate 被引量:3
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作者 LIU JiangHao FU ZhengYi +5 位作者 WANG WeiMin ZHANG JinYong WANG Hao WANG YuCheng LEE SooWohn NIIHARA Koichi 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第6期1085-1092,共8页
The fast densification method of combustion reaction plus quick pressing was adopted to prepare nanocrystalline ceramics.The densification process of magnesia compact with a particle size of 100 nm was investigated,un... The fast densification method of combustion reaction plus quick pressing was adopted to prepare nanocrystalline ceramics.The densification process of magnesia compact with a particle size of 100 nm was investigated,under the applied pressure of up to 170 MPa,and the temperature range of 1740–2080 K with ultra-high heating rate(above 1700 K/min).High-purity magnesia ceramics with a relative density of 98.8%and an average grain size of 120 nm was obtained at 1740 K,and the grain growth during the densification process was effectively restrained.The characteristic morphology of evaporation-condensation was observed in the compact prepared at 2080 K,which revealed the actual process of mass transfer by gas diffusion.Moreover,the investigation on the microstructure evolution and mechanism of grain growth was carried out,on the basis of as-preserved nanocrystalline ceramics.The result indicated that the grain growth of the nanocrystalline MgO was controlled by the mechanism of evaporation-condensation rather than surface diffusion.Furthermore,the pressure had an influence of restraining the grain growth based on solid diffusion and strengthening the effect of gas diffusion with the increasing temperature.Under the particular conditions,there existed an appropriate temperature for the densification of nanocrystalline magnesia,while the excessive temperature would exaggerate grain growth and impede densification. 展开更多
关键词 grain growth DENSIFICATION heating rate evaporation-condensation surface diffusion nanocrystalline ceramics
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Study on Drug Property Differences of Shexiang (Moschus) and Bingpian (Borneolum Synthcticum) Based on Analysis of Biothermodynamics
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作者 程丹红 王建 +5 位作者 曾南 夏厚林 傅勇 鄢丹 赵艳玲 肖小河 《Journal of Traditional Chinese Medicine》 SCIE CAS CSCD 2011年第1期21-26,共6页
Objective: To study the drug property differences of Shexiang (Moschus) and Bingpian (Borneolum Synthcticum) with biothermodynamics, and to verify the objectivity and authenticity of the drug property. Methods: The gr... Objective: To study the drug property differences of Shexiang (Moschus) and Bingpian (Borneolum Synthcticum) with biothermodynamics, and to verify the objectivity and authenticity of the drug property. Methods: The growth-thermogram curves of Escherichia coli (E. coli) affected by Shexiang (Moschus) and Bingpian (Borneolum Synthcticum) at different concentrations were determined with microcalorimetry, and the power-time curves (thermogram curves) of E. coli metabolism and characteristic parameters, such as growth rate constant (k), maximum output power (Pm), peak time (tp), total heat-output (Qt), etc. were analyzed with the principal component analysis (PCA) to find the close correlative parameters, so as to objectively reflect the drug property differences of Shexiang (Moschus) and Bingpian (Borneolum Synthcticum). Results: The values of P2 in the second exponential growth phase increased with the increase of the concentrations of Shexiang (Moschus) and Bingpian (Borneolum Synthcticum), and the P2 of Shexiang (Moschus) was larger than that of Bingpian (Borneolum Synthcticum); Q2 increased with the increase of the concentrations of Shexiang (Moschus), but for Bingpian (Borneolum Synthcticum) it was opposite. It is indicated that they have different effects on P2 and Q2 of E. coli in the second exponential growth phase, and have differences in warm and cold natures. Conclusion: The microcalorimetry can accurately and objectively appraise differences of the drug property of Shexiang (Moschus) and Bingpian (Borneolum Synthcticum) and verify the objectivity and authenticity of the drug property, so as to provide a new and useful method for studies of the drug property of Chinese drugs. 展开更多
关键词 Shexiang and Bingpian biothermodynamics properties of Chinese drugs
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