The influence of various factors, mechanisms, and principles affecting runoff are summarized as periodic law, random law, and basin-wide law. Periodic law is restricted by astronomical factors, random law is restricte...The influence of various factors, mechanisms, and principles affecting runoff are summarized as periodic law, random law, and basin-wide law. Periodic law is restricted by astronomical factors, random law is restricted by atmospheric circulation, and basin-wide law is restricted by underlying surface. The commensurability method was used to identify the almost period law, the wave method was applied to deducing the random law, and the precursor method was applied in order to forecast runoff magnitude for the current year. These three methods can be used to assess each other and to forecast runoff. The system can also be applied to forecasting wet years, normal years and dry years for a particular year as well as forecasting years when floods with similar characteristics of previous floods, can be expected. Based on hydrological climate data of Baishan (1933-2009) and Nierji (1886-2009) in the Songhua River Basin, the forecasting results for 2010 show that it was a wet year in the Baishan Reservoir, similar to the year of 1995; it was a secondary dry year in the Nierji Reservoir, similar to the year of 1980. The actual water inflow into the Baishan Reservoir was 1.178 × 10 10 m 3 in 2010, which was markedly higher than average inflows, ranking as the second highest in history since records began. The actual water inflow at the Nierji station in 2010 was 9.96 × 10 9 m 3 , which was lower than the average over a period of many years. These results indicate a preliminary conclusion that the methods proposed in this paper have been proved to be reasonable and reliable, which will encourage the application of the chief reporter release system for each basin. This system was also used to forecast inflows for 2011, indicating a secondary wet year for the Baishan Reservoir in 2011, similar to that experienced in 1991. A secondary wet year was also forecast for the Nierji station in 2011, similar to that experienced during 1983. According to the nature of influencing factors, mechanisms and forecasting methods and the service objects, mid-to long-term hydrological forecasting can be divided into two classes:mid-to long-term runoff forecasting, and severe floods and droughts forecasting. The former can be applied to quantitative forecasting of runoff, which has important applications for water release schedules. The latter, i.e., qualitative disaster forecasting, is important for flood control and drought relief. Practical methods for forecasting severe droughts and floods are discussed in this paper.展开更多
In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the ele...In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the electron transport layer(ETL)not only presents an ameliorative work function,but also forms the cratered surface with increased ohmic contact area,revealing suppressed charge recombination and enhanced charge extraction in devices.Particularly,P-ZnO-based OSCs show improved light trapping in the active layer compared with ZnO-based ones.The universality of P-ZnO serving as ETL for efficient OSCs is verified on three photovoltaic systems of PBDB-T/DTPPSe-2 F,PM6/Y6,and PTB7-Th/PC_(71)BM.The enhancements of 8%in power conversion efficiency(PCE)can be achieved in the state-of-the-art OSCs based on PBDB-T/DTPPSe-2F,PM6/Y6,and PTB7-Th/PC_(71)BM,delivering PCEs of 14.78%,16.57%,and 9.85%,respectively.Furthermore,a promising PCE of14.13%under air-processed condition can be achieved for PZnO/PBDB-T/DTPPSe-2F-based OSC,which is among the highest efficiencies reported for air-processed OSCs in the literature.And the P-ZnO/PBDB-T/DTPPSe-2F-based device also presents superior long-term storage stability whether in nitrogen or ambient air-condition without encapsulation,which can maintain over 85%of its initial efficiency.Our results demonstrate the great potential of the porous hybrid PZnO as ETL for constructing high-performance and air-stable OSCs.展开更多
基金Under the auspices of National Natural Science Foundation(No.50879028)Open Fund of State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering of Nanjing Hydraulic Research institute(No.2009491311)+1 种基金Open Research Fund Program of State key Laboratory of Hydroscience and Engineering,Tsinghua University(No.sklhse-2010-A-02)Application Foundation Items of Science and Technology Department of Jilin Province(No.2011-05013)
文摘The influence of various factors, mechanisms, and principles affecting runoff are summarized as periodic law, random law, and basin-wide law. Periodic law is restricted by astronomical factors, random law is restricted by atmospheric circulation, and basin-wide law is restricted by underlying surface. The commensurability method was used to identify the almost period law, the wave method was applied to deducing the random law, and the precursor method was applied in order to forecast runoff magnitude for the current year. These three methods can be used to assess each other and to forecast runoff. The system can also be applied to forecasting wet years, normal years and dry years for a particular year as well as forecasting years when floods with similar characteristics of previous floods, can be expected. Based on hydrological climate data of Baishan (1933-2009) and Nierji (1886-2009) in the Songhua River Basin, the forecasting results for 2010 show that it was a wet year in the Baishan Reservoir, similar to the year of 1995; it was a secondary dry year in the Nierji Reservoir, similar to the year of 1980. The actual water inflow into the Baishan Reservoir was 1.178 × 10 10 m 3 in 2010, which was markedly higher than average inflows, ranking as the second highest in history since records began. The actual water inflow at the Nierji station in 2010 was 9.96 × 10 9 m 3 , which was lower than the average over a period of many years. These results indicate a preliminary conclusion that the methods proposed in this paper have been proved to be reasonable and reliable, which will encourage the application of the chief reporter release system for each basin. This system was also used to forecast inflows for 2011, indicating a secondary wet year for the Baishan Reservoir in 2011, similar to that experienced in 1991. A secondary wet year was also forecast for the Nierji station in 2011, similar to that experienced during 1983. According to the nature of influencing factors, mechanisms and forecasting methods and the service objects, mid-to long-term hydrological forecasting can be divided into two classes:mid-to long-term runoff forecasting, and severe floods and droughts forecasting. The former can be applied to quantitative forecasting of runoff, which has important applications for water release schedules. The latter, i.e., qualitative disaster forecasting, is important for flood control and drought relief. Practical methods for forecasting severe droughts and floods are discussed in this paper.
基金the National Natural Science Foundation of China(21905137)the Natural Science Foundation of Jiangsu Province(BK20180496)。
文摘In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the electron transport layer(ETL)not only presents an ameliorative work function,but also forms the cratered surface with increased ohmic contact area,revealing suppressed charge recombination and enhanced charge extraction in devices.Particularly,P-ZnO-based OSCs show improved light trapping in the active layer compared with ZnO-based ones.The universality of P-ZnO serving as ETL for efficient OSCs is verified on three photovoltaic systems of PBDB-T/DTPPSe-2 F,PM6/Y6,and PTB7-Th/PC_(71)BM.The enhancements of 8%in power conversion efficiency(PCE)can be achieved in the state-of-the-art OSCs based on PBDB-T/DTPPSe-2F,PM6/Y6,and PTB7-Th/PC_(71)BM,delivering PCEs of 14.78%,16.57%,and 9.85%,respectively.Furthermore,a promising PCE of14.13%under air-processed condition can be achieved for PZnO/PBDB-T/DTPPSe-2F-based OSC,which is among the highest efficiencies reported for air-processed OSCs in the literature.And the P-ZnO/PBDB-T/DTPPSe-2F-based device also presents superior long-term storage stability whether in nitrogen or ambient air-condition without encapsulation,which can maintain over 85%of its initial efficiency.Our results demonstrate the great potential of the porous hybrid PZnO as ETL for constructing high-performance and air-stable OSCs.