The population of surface broken bonds of some typical sulfide, oxide and salt-type minerals which may belong to cubic, tetragonal, hexagonal, or orthorhombic system, were calculated. In terms of the calculation resul...The population of surface broken bonds of some typical sulfide, oxide and salt-type minerals which may belong to cubic, tetragonal, hexagonal, or orthorhombic system, were calculated. In terms of the calculation results, the cleavage natures of these minerals were analyzed, and the relationship between surface broken bonds density and surface energy was also established. The results show that the surface broken bonds properties could be used to predict the cleavage nature of most of minerals, and the predicted cleavage planes agree well with those reported in previous literature. Moreover, this work explored a rule that, surface broken bonds density is directly related to surface energy with determination coefficient（R2） of over 0.8, indicating that the former is a dominant factor to determine the latter. Therefore, anisotropic surface broken bonds density can be used to predict the stability of mineral surface and the reactivity of surface atoms.展开更多
A reagent combination of sodium oleate(NaOl)and salicyl hydroximic acid was employed as the roughing and scavenging collectors,whereas styryl phosphoric acid(SPA)and octanol were employed as the cleaning collectors.Re...A reagent combination of sodium oleate(NaOl)and salicyl hydroximic acid was employed as the roughing and scavenging collectors,whereas styryl phosphoric acid(SPA)and octanol were employed as the cleaning collectors.Results of bench-scale flotation demonstrate that the dosage of SPA can be reduced by about 80%,and that a better flotation index can be obtained using the proposed reagent system.The results of adsorption amount and contact angle measurements indicate that the rutile surface adsorbed not only a large amount of residual NaOl but also SPA and a small amount of NaOl remained on the amphibole surface in strong acidic solution.The hydrophobic difference between rutile and amphibole surfaces was therefore amplified in cleaning,and their further separation became much easier consequently.展开更多
The authors presented geochronology and geochemical data of diorites from Nancha gold deposit in Tonghua region, with the aim to constraining its formation age, magma source and tectonic setting. LA-ICP-MS U-Pb dating...The authors presented geochronology and geochemical data of diorites from Nancha gold deposit in Tonghua region, with the aim to constraining its formation age, magma source and tectonic setting. LA-ICP-MS U-Pb dating results of zircons from the diorites indicate that the rocks were formed in the Middle Jurassic （171 ±2 Ma, MSWD = 1. 19）. Geochemically, these rocks have Si02 concentrations of 52. 52%-54. 90%,K20 of 2. 14%-3.84% , Na20 of 3. 17%-3. 35% , MgO of 7. 43%-9. 34% and high Mg# of 68. 57-72. 57. These rocks are characterized by enrichment in large ion lithophile elements（ LILE,such as K, Ba, Rb and Sr） and light rare earth elements （ LREE） , relatively depletion in high field strength elements （ HFSE, such as Ta, Nb, Ti and Zr） , and heavy rare earth elements （HREE）. These characteristics suggest that primary magma of the rocks were derived from the partial melting of mantle with miner crustal contamination, which may related to partial melting of mantle wedge by addition of sediment melt from subducting oceanic crust. Based on former and present studies, the authors consider that the Nancha ore deposit high-Mg diorites were formed in compres- sional structural setting which is similar to volcanic arc. It could be related to the subduction of the Paleo-Paci- fic plate beneath the Eurasian continent.展开更多
The railway transport is one of the main types of communications in the world. Analysis of service conditions of the most critical elements of the railway transport rolling stock （mils, wheels and tyres） shows that ...The railway transport is one of the main types of communications in the world. Analysis of service conditions of the most critical elements of the railway transport rolling stock （mils, wheels and tyres） shows that one of the main factors determining their reliability and service life is the structural-phase state of steel, which is formed in the process of its producing. Complication of service conditions leads to the more severe requirements, specified by the consumers, where the high level of strength and hardness should be combined with high values of ductility and toughness. Realization of these requirements is possible only at the integrated approach to the improvement of technology of their production on the basis of profound knowledge in kinetics of austenite decay processes of structure formation and its contribution to the mechanical properties. With the formation of mainly bainite-martensite structures in the HAZ （heat-affected zone） metal of welded joints of these steels and saturation of this region with diffusive hydrogen their susceptibility to the cold cracking is increased. In this connection this work presents the results of investigations of effect of the WTC （welding thermal cycles） on the nature of structural transformations, hardness, static strength and resistance to the formation of cold cracks in HAZ metal of high-strength carbon rail steel M76. For this purpose, the structure and kinetics of transformation of an overcooled austenite was studied using the advanced methods of physical materials science by the modeling of phase transformations in the Gleeble 3800 unit. It was found that the cause of reduction in mechanical properties of welded joints of steel M76 is the formation of regions with a completely martensite structure in the amount of up to 5%. Results of investigations will be applied for the optimizing the technology and conditions of FBW of the advanced rail steels. 10 Ref., 4 Tables, 11 Figures.展开更多
基金Project(50831006)supported by the National Natural Science Foundation of ChinaProject(2012BAB10B05)supported by the National Key Technologies R&D Program of China
文摘The population of surface broken bonds of some typical sulfide, oxide and salt-type minerals which may belong to cubic, tetragonal, hexagonal, or orthorhombic system, were calculated. In terms of the calculation results, the cleavage natures of these minerals were analyzed, and the relationship between surface broken bonds density and surface energy was also established. The results show that the surface broken bonds properties could be used to predict the cleavage nature of most of minerals, and the predicted cleavage planes agree well with those reported in previous literature. Moreover, this work explored a rule that, surface broken bonds density is directly related to surface energy with determination coefficient（R2） of over 0.8, indicating that the former is a dominant factor to determine the latter. Therefore, anisotropic surface broken bonds density can be used to predict the stability of mineral surface and the reactivity of surface atoms.
基金Projects(11575281,11290165,11305252,U1532260,51474254)supported by the National Natural Science Foundation of China
文摘A reagent combination of sodium oleate(NaOl)and salicyl hydroximic acid was employed as the roughing and scavenging collectors,whereas styryl phosphoric acid(SPA)and octanol were employed as the cleaning collectors.Results of bench-scale flotation demonstrate that the dosage of SPA can be reduced by about 80%,and that a better flotation index can be obtained using the proposed reagent system.The results of adsorption amount and contact angle measurements indicate that the rutile surface adsorbed not only a large amount of residual NaOl but also SPA and a small amount of NaOl remained on the amphibole surface in strong acidic solution.The hydrophobic difference between rutile and amphibole surfaces was therefore amplified in cleaning,and their further separation became much easier consequently.
文摘The authors presented geochronology and geochemical data of diorites from Nancha gold deposit in Tonghua region, with the aim to constraining its formation age, magma source and tectonic setting. LA-ICP-MS U-Pb dating results of zircons from the diorites indicate that the rocks were formed in the Middle Jurassic （171 ±2 Ma, MSWD = 1. 19）. Geochemically, these rocks have Si02 concentrations of 52. 52%-54. 90%,K20 of 2. 14%-3.84% , Na20 of 3. 17%-3. 35% , MgO of 7. 43%-9. 34% and high Mg# of 68. 57-72. 57. These rocks are characterized by enrichment in large ion lithophile elements（ LILE,such as K, Ba, Rb and Sr） and light rare earth elements （ LREE） , relatively depletion in high field strength elements （ HFSE, such as Ta, Nb, Ti and Zr） , and heavy rare earth elements （HREE）. These characteristics suggest that primary magma of the rocks were derived from the partial melting of mantle with miner crustal contamination, which may related to partial melting of mantle wedge by addition of sediment melt from subducting oceanic crust. Based on former and present studies, the authors consider that the Nancha ore deposit high-Mg diorites were formed in compres- sional structural setting which is similar to volcanic arc. It could be related to the subduction of the Paleo-Paci- fic plate beneath the Eurasian continent.
文摘The railway transport is one of the main types of communications in the world. Analysis of service conditions of the most critical elements of the railway transport rolling stock （mils, wheels and tyres） shows that one of the main factors determining their reliability and service life is the structural-phase state of steel, which is formed in the process of its producing. Complication of service conditions leads to the more severe requirements, specified by the consumers, where the high level of strength and hardness should be combined with high values of ductility and toughness. Realization of these requirements is possible only at the integrated approach to the improvement of technology of their production on the basis of profound knowledge in kinetics of austenite decay processes of structure formation and its contribution to the mechanical properties. With the formation of mainly bainite-martensite structures in the HAZ （heat-affected zone） metal of welded joints of these steels and saturation of this region with diffusive hydrogen their susceptibility to the cold cracking is increased. In this connection this work presents the results of investigations of effect of the WTC （welding thermal cycles） on the nature of structural transformations, hardness, static strength and resistance to the formation of cold cracks in HAZ metal of high-strength carbon rail steel M76. For this purpose, the structure and kinetics of transformation of an overcooled austenite was studied using the advanced methods of physical materials science by the modeling of phase transformations in the Gleeble 3800 unit. It was found that the cause of reduction in mechanical properties of welded joints of steel M76 is the formation of regions with a completely martensite structure in the amount of up to 5%. Results of investigations will be applied for the optimizing the technology and conditions of FBW of the advanced rail steels. 10 Ref., 4 Tables, 11 Figures.
