梅岭霉素的分离纯化

利用南昌霉素在较低pH介质中加热时易降解而梅岭霉素较稳定的性质,结合溶剂萃取法除去杂质,纯化梅岭霉素。经全波长扫描、HPLC和质谱分析等,推测梅岭霉素同系物的分子结构。

Effect of Si on growth kinetics of intermetallic compounds during reaction between solid iron and molten aluminum

The effect of Si on the growth kinetics of intermetallic compounds during the reaction of solid iron and molten aluminum was investigated with a scanning electron microscope coupled with an energy dispersive X-ray spectroscope, and hot-dip aluminized experiments. The results show that the intermetallic layer is composed of major Fe2Al5 and minor FeAl3. The Al-Fe-Si ternary phase, rl/rg, is formed in the Fe2Al5 layer. The tongue-like morphology of the Fe2Als layer becomes less distinct and disappears finally as the content of Si in aluminum bath increases. Si in the bath improves the prohibiting ability to the growth of Fe2Als and FeAl3. When the contents of Si are 0, 0.5%, 1.0%, 1.5%, 2.0% and 3.0%, the activation energies of Fe2Al5 are evaluated to be 207, 186, 169, 168, 167 and 172 kJ/mol, respectively. The reduction of the activation energy might result from the lattice distortion caused by Si atom penetrating into the Fe2Al5 phase. When Si atom occupies the vacancy site, it blocks easy diffusion path and results in the disappearance of tongue-like morphology.

Intermetallics and phase relations of Mg-Zn-Ce alloys at 400 ℃

The crystal structures,compositions and phase relations of the intermetallics of Mg-Zn-Ce system in the Mg-rich corner at 400 ℃ were identified through equilibrium alloy method.For Mg-Zn-Ce system,there is a linear ternary compound（T phase）,whose chemical formula is（Mg1-xZnx）11Ce.The range of Zn content in T phase is from 9.6% to 43.6%（molar fraction）.The crystal structure of T phase is C-centered orthorhombic lattice with lattice parameters of a=0.96-1.029 nm,b=1.115-1.204 nm,c=0.940-1.015 nm.And the lattice parameters of T phase are decreasing a little with increasing Zn content.According to the results of composition and crystal structure,the maximal solubility of Zn in Mg12Ce is about 7.8%（molar fraction）,and the chemical formula of the solid solution can be identified as（Mg1-xZnx）12Ce.The isothermal section of Mg-Zn-Ce system in Mg-rich corner at 400 ℃ was constructed.

Multilayered Ti-Al intermetallic sheets fabricated by cold rolling and annealing of titanium and aluminum foils

Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques.The results reveal that when the sintering temperature is above the melting point of aluminum,the self-propagating high-temperature synthesis reaction occurs between Ti and Al,and forms various phases of Ti-based solid solutions including α-Ti Ti3Al,TiAl,TiAl2 and α-Ti including TiAl3,etc.When the sintering time increased,Ti-based solid solution,TiAl2 and TiAl3 disappeared gradually,and the sheet containing Ti3Al and TiAl phases in a multilayered structure formed finally.A lot of voids were also observed in the sintered structures,which were caused by the melting Al,Kirkendall effect and the difference of molar volumes between reactants and products.The voids were eliminated and a dense sample was obtained by the following hot press.

Characteristic atom occupation patterns of Au_3Cu,AuCu_3,AuCuI and AuCuII based on experimental data of disordered alloys

The potential energies, volumes and electronic structures of characteristic atoms coordinated by neighboring configurations were obtained from the experimental heats of formation and lattice parameters of disordered Au1-xCux alloys. From characteristic atom occupation （CAO） patterns of L12-Au3Cu, L12-AuCu3 and Llo-AuCu compounds, their electronic structures, volumetric and energetic properties were calculated. The CAO pattern of Johasson-Linde（J-L） model shows that the transition AuCuI→AuCulI is an exothermic and volume contraction reaction, which is opposite from experimental phenomena. According to CAO pattern of Guymont-Feutelais-Legendre（G-F-L） model, the AuCulI cell consists of two periodic antidirection （PAD） AuCuI regions and two PAD boundary regions. The equations derived from CAO pattern of G-F-L model can be used to calculate energetic properties, volumetric properties and ordering degrees of the PAD AuCuI region and PAD boundary region, as well as corresponding average properties of the AuCulI phase. The results are consistent with experimental phenomena.

Isothermal section of Mg-rich corner in Mg-Zn-Al ternary system at 335 °C

The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). It is experimentally testified that theα-Mg solid solution is not in equilibrium with the Mg32(Al, Zn)49 (τ) ternary intermetallic compound orq quasicrystalline phase, but only in equilibrium with one ternary intermetallic compound Al5Mg11Zn4 (φ). The whole composition range of theφ phase was also obtained at 335 °C, i.e., 52.5%?56.4% Mg, 13.6%?24.0% Al, 19.6%?33.9% Zn (mole fraction). The solubility of Al in the MgZn phase is remarkably more than that in the Mg7Zn3 phase, and the maximum is about 8.6% Al. Aluminum and zinc are simultaneously soluble in theα-Mg solid solution.

Transient Properties of a Bistable System with Delay Time Driven by Non-Gaussian and Gaussian Noises:Mean First-Passage Time

The mean first-passage time of a bistable system with time-delayed feedback driven by multiplicative non-Gaussian noise and additive Gaussian white noise is investigated. Firstly, the non-Markov process is reduced to the Markov process through a path-integral approach; Secondly, the approximate Fokker-Planck equation is obtained by applying the unified coloured noise approximation, the small time delay approximation and the Novikov Theorem. The functional analysis and simplification are employed to obtain the approximate expressions of MFPT. The effects of non-Gaussian parameter （measures deviation from Gaussian character） r, the delay time τ, the noise correlation time to, the intensities D and a of noise on the MFPT are discussed. It is found that the escape time could be reduced by increasing the delay time τ, the noise correlation time τ0, or by reducing the intensities D and α. As far as we know, this is the first time to consider the effect of delay time on the mean first-passage time in the stochastic dynamical system.

Applications of Three DNA Barcodes in Assorting Intertidal Red Macroalgal Flora in Qingdao, China

This study is part of the endeavor to construct a comprehensive DNA barcoding database for common seaweeds in China. Identifications of red seaweeds, which have simple morphology and anatomy, are sometimes difficult solely depending on morphological characteristics. In recent years, DNA barcode technique has become a more and more effective tool to help solve some of the taxonomic difficulties. Some DNA markers such as COI（cytochrome oxidase subunit I） are proposed as standardized DNA barcodes for all seaweed species. In this study, COI, UPA （universal plastid amplicon, domain V of 23S rRNA）, and ITS （nuclear internal transcribed spacer） were employed to analyze common species of intertidal red seaweeds in Qingdao （119.3°-121°E, 35.35°-37.09°N）. The applicability of using one or a few combined barcodes to identify red seaweed species was tested. The results indicated that COI is a sensitive marker at species level. However, not all the tested species gave PCR amplification products due to lack of the universal primers. The second barcode UPA had effective universal primers but needed to be tested for the effectiveness of resolving closely related species. More than one ITS sequence types were found in some species in this investigation, which might lead to confusion in further analysis. Therefore ITS sequence is not recommended as a universal barcode for seaweeds identification.

Noether-Mei Symmetry of Mechanical System in Phase Space

In this paper, a new kind of symmetry and its conserved quantities of a mechanical system in phase space are studied. The definition of this new symmetry, i,e., a Noether-Mei symmetry, is presented, and the criterion of this symmetry is also given. The Noether conserved quantity and the Mei conserved quantity deduced from the Noether-Mei symmetry of the system are obtained. Finally, two examples are given to illustrate the Bpplication of the results.

Biomass and Carbon Sequestration Potential of Poplar-Wheat Inter-cropping System in Irrigated Agro-ecosystem in India

An attempt has been made to assess the productivity as well as the carbon sequestration potential of this mixture. The grain as well as straw yields were significantly lower in poplar block plantations than in the open （14 to 64% and 13 to 66% grain and straw yield, respectively under one to six year plantation）. The annual productivity of poplars was recorded maximum after fourth year and later the annual wood increment decreased （42.4, 39.8 and 35.6 m^3/ha/yr after 4^th, 5^th and 6^th year, respectively）. The enrichment of soil through litter and roots enhanced the organic carbon in the surface layer of soil （0-15 cm） under poplar blocks as compared to open fields with wheat crop only. The carbon storage potential in agroforestry system was recorded very high in comparison to sole crop. The carbon storage in agroforestry system increased with the age of the plantation and the major contribution came from the timber, roots and litter （37.30 mg/ha after six years）. However, wheat crop yield decreased under poplar but this may be compensated by the poplar trees in terms of biomass, economic returns and the carbon sequestration potential.

Modified Cascade Synchronization Scheme for Discrete-Time Hyperchaotic Systems

In this paper, the modified cascade synchronization scheme is proposed to investigate the synchronization in discrete-time hyperchaotic systems. By choosing a general kind of proportional scaling error functions and based on rigorous control theory, we take the discrete-time hyperchaotic system due to Wang and 3D generalized Henon map as two examples to achieve the modified cascade synchronization, respectively. Numerical simulations are used to verify the effectiveness of the proposed technique.

Synchronization and Bifurcation Analysis in Coupled Networks of Discrete-Time Systems

Synchronization and bifurcation analysis in coupled networks of discrete-time systems are investigated in the present paper. We mainly focus on some special coupling matrix, i.e., the sum of each row equals a nonzero constant u and the network connection is directed. A result that the network can reach a new synchronous state, which is not the asymptotic limit set determined by the node state equation, is derived. It is interesting that the network exhibits bifurcation if we regard the constant u as a bifurcation parameter at the synchronous state. Numerical simulations are given to show the efficiency of our derived conclusions.

Phylogenetic relationships within the genus Aspidisca(Protozoa,Ciliophora,Euplotida) revealed by ITS1-5.8S-ITS2 region sequences

Abstract The internal transcribed spacer regions （ITS1 and ITS2） and 5.8S rRNA genes were sequenced in six populations of four Aspidisca species, namely A. leptaspis, A. orthopogon, A. rnagna and A. aculeata. Phylogenetic trees were constructed by means of Bayesian inference （BI）, Maximum Parsimony （MP）, Neighbor-Joining （NJ）, and Maximum Likelihood （ML） to assess the inter- and intra-species relationships within the genus Aspidisca. All trees show similar topologies with stable supports and indicate that： （1） four well known groups, i.e., Oligotrichia, Stichotrichia, Choreotrichia and Hypotrichia, are distinctly outlined within the class Spirotrichea, and all are monophyletic other than Hypotrichia; （2） members of Aspidisca can be distinguished well, based on the ITSI-5.SS-ITS2 region sequences, and A. leptaspis and A. magna shared a closer relationship than other species; （3） Aspidisca and Euplotes branch early in the subclass Hypotrichia. To compare the phylogenetic relationships based on different genes, SSU rRNA trees were also constructed with nearly the same species inclusion, which revealed different topologies of inter-species, inter-genera and inter-subclasses.

Realization of R-tree for GIS on hybrid clustering algorithm

The characteristic of geographic information system（GfS） spatial data operation is that query is much more frequent than insertion and deletion, and a new hybrid spatial clustering method used to build R-tree for GIS spatial data was proposed in this paper. According to the aggregation of clustering method, R-tree was used to construct rules and specialty of spatial data. HCR-tree was the R-tree built with HCR algorithm. To test the efficiency of HCR algorithm, it was applied not only to the data organization of static R-tree but also to the nodes splitting of dynamic R-tree. The results show that R-tree with HCR has some advantages such as higher searching efficiency, less disk accesses and so on.

Physical-Layer Encryption in Massive MIMO Systems with Spatial Modulation

Massive multiple input and multiple output(MIMO) is a key technology of the fifth generation(5 G) wireless communication systems, which brings various advantages, such as high spectral efficiency and energy efficiency. In MIMO system, spatial modulation(SM) has recently emerged as a new transmission method. In this paper, in order to improve the security in SM-MIMO, a physical layer encryption approach named chaotic antenna-index three-dimensional modulation and constellation points rotated(CATMCPR) encryption scheme is proposed, which utilizes the chaotic theory and spatial modulation techniques. The conventional physical-layer encryption in SM-MIMO suffers from spectral efficiency(SE) performance degradation and usually needs a preshared key, prior channel state information(CSI) or excess jamming power. By contrast, we show that the CATMCPR scheme can not only achieve securely communication but also improve above drawbacks. We evaluate the performances of the proposed scheme by an analysis and computer simulations.

New and More General Rational Formal Solutions to （2＋1）-Dimensional Toda System

With the aid of computerized symbolic computation and Riccati equation rational expansion approach, some new and more general rational formal solutions to （2＋1）-dimensional Toda system are obtained. The method used here can also be applied to solve other nonlinear differential-difference equation or equations.

Microstructure and properties of high silicon aluminum alloy with 2% Fe prepared by rheo-casting

The morphology changes of both Fe-containing intermetallic compounds and the primary Si phase of Al-20Si-2Fe- 2Cu-0.4Mg-1.0Ni-0.5Mn （mass fraction, %） alloy produced by semi-solid rheo-diecasting were studied. The semi-solid slurry of high silicon aluminum alloy was prepared by direct ultrasonic vibration （DUV） which was imposed on the alloy near the liquidus temperature for about 2 rain. Then, standard test samples of 6.4 mm in diameter were formed by semi-solid rheo-diecasting. The results show that the DUV treatment suppresses the formation of needle-like ,β-Al5（Fe,Mn）Si phase, and the Fe-containing intermetallic compounds exist in the form of fine Al4（Fe, Mn）Si2 particles. Additionally, the primary Si grows up as fine and round particles with uniform distribution in α（Al） matrix of this alloy under DUV treatment. The tensile strengths of the samples at the room temperature and 573 K are 230 MPa and 145 MPa, respectively. The coefficient of thermal expansion （CTE） between 25 ℃ and 300 ℃ is 16.052 8×10^-6 ℃^-1, and the wear rate is 1.55%. The hardness of this alloy with 2% Fe reaches HB146.3. It is discovered that modified morphology and uniform distribution of the Fe-containing intermetallic compounds and the primary Si phase are the main reasons for reducing the CTE and increasing the wear resistance of this alloy.

Redefining/Reconstructing the ＂In-between＂： An Urban Transformation Scenario for the Haydarpasa Harbour, Istanbul

Istanbul as a ＂third world＂ metropolis is a dynamic open system, where complex and multiple economical, social and physical conditions are overlapped. Still the city is a focus point of social （economical, cultural, and ethnical） and spatial dualisms and their genuine contradictions--polarizations particularly in the last 30 years. Istanbul＇s natural characteristics such as geographical conditions （slope topography and the physical relationship with the sea）, and also the artificial urban properties that include the historical architectural monuments, the industrial heritage, the contemporary urban transformation applications, the harbours and docklands as borderlines or in-between zones also identify this fragmented, hybrid, and divided urban structure. The Haydarpasa Harbour as an artificial urban borderline between the ruined and peak zones lJskudar and Kadikoy on the Asian side of the city is a kind of representative in-between area, an isolate city in city, which triggers the social and physical collage and ＂deconstructs＂ the development process of lstanbul＇s morphology. This paper aims to analyze these social and spatial aspects, which endure urban polarization in Istanbul. The underlying reasons of these contradictions and eventual outcome of the peak and the ruined zones in lstanbul and their border districts typologies will be analyzed. This paper will also make a compared evaluation of Haydarpasa Harbour （intersection point of two adjacent districts in Istanbul） and the completed urban design transformation projects/scenarios on the harbor area regarding the creation of a sustainable urban development for the city by enabling a new productive public space in-between [Jskudar （＂ruined＂ zone） and Kadikoy （＂peak＂ zone） in Istanbul.

Permeability variation characteristics of coal after injecting carbon dioxide into a coal seam

A theoretical basis for the optimization of carbon dioxide injection parameters and the development of the drainage system can be provided by identifying the permeability change characteristic of coal and rock after injection of carbon dioxide into the coal seam. Sihe, Yuwu, and Changcun mines were used as research sites. Scanning electron microscopy and permeability instruments were used to measure coal properties such as permeability and surface structure of the coal samples at different pH values of carbon dioxide solution and over different timescales. The results show that the reaction between minerals in coal and carbonate solution exhibit positive and negative aspects of permeability-the dissolution reaction between carbonate minerals in coal and acid solution improves the conductivity of coal whilst, on the other hand, the clay minerals in the coal （mainly including montmorillonite, illite and kaolinite） exhibit expansion as a result of ion exchange with the H~ in acid solution, which has a negative effect on the per- meability of the coal. The permeability of coal samples increased at first and then decreased with immer- sion time, and when the soaking time is 2-3 months the permeability of the coal reached a maximum. In general, for coals with permeabilities less than 0.2 mD or greater than 2 roD, the effect on the permeabil- ity is low： when the permeability of the coal is in the range 0.2-2 mD, the effect on the permeability is highest. Research into permeability change characteristics can provide a theoretical basis for carbon diox- ide injection under different reservoir permeability conditions and subsequent drainage.

Evaluation and Performance of the APSIM Crop Growth Model for German Winter Wheat, Maize and Fieldpea Varieties in Monocropping and Intercropping Systems

Competition for solar radiation between plants grown in multi-species cropping systems can severely limit crop production of individual species within that system. There are various approaches for modeling light interception within mixed-cropping and row or strip intercropping systems. To extend the knowledge about model behavior and different model approaches under interspecific competition conditions, the Agricultural Production Systems Simulator （APSIM） was evaluated and calibrated for field experiments previously described and simulated by the Decision Support System for Agrotechnology Transfer （DSSAT）. Initially the APSIM plant model was successfully modified to simulate wheat, maize and fieldpea monocultures in the European agro-ecological zone. Once calibrated, the APSIM model was then used to simulate a strip relay intercropping maize/wheat and maize/fieldpea system. In DSSAT, a shading algorithm was introduced to modify the daily weather input in order to take competition for solar radiation into account. In contrast, APSIM simulates interspecific competition using a modified Beer＇s law for multi-component canopy conditions. After a re-evaluation of the model regarding a minimum change of crop coefficients and variables, APSIM was able to simulate dry matter and grain yield of German maize, wheat and fieldpea varieties adequately. However, APSIM is a point-based model, and many of the processes that influence strip cropping cannot be accommodated by adjusting Beer＇s Law alone. So far none of the tested frameworks successfully modeled strip or relay intercropping. The processes governing growth in the numerous and very diversifying intercropping systems are complex and at this point in time have not been captured in sufficient detail.