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酸性介质中长效析氧阳极的研究 被引量:3
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作者 谭琛 苏艳舟 《氯碱工业》 CAS 2005年第2期21-23,共3页
开发了一种新型长效析氧阳极,该含铱阳极在有机电解合成化学、海水电解及电极箔生产等领域得到了成功的应用。通过析氧电流曲线、稳态极化曲线、强化考核寿命微观形貌及相结构分析,得出最佳制备工艺:①析氧阳极的活性氧化物应选择贵金... 开发了一种新型长效析氧阳极,该含铱阳极在有机电解合成化学、海水电解及电极箔生产等领域得到了成功的应用。通过析氧电流曲线、稳态极化曲线、强化考核寿命微观形貌及相结构分析,得出最佳制备工艺:①析氧阳极的活性氧化物应选择贵金属氧化物IrO2,其在涂层中的质量分数为10%~80%;②在活性氧化物中掺杂惰性金属氧化物是延长涂层寿命的可行办法;③氧化涂层的氧化温度在400~600℃;④增加涂层厚度可延长阳极寿命,提高催化活性。 展开更多
关键词 析氧阳极 酸性介质 阳极制备工艺
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Preparation process and characterization of new Pt/stainless steel wire mesh catalyst designed for volatile organic compounds elimination 被引量:1
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作者 张婷 陈敏 +1 位作者 高园园 郑小明 《Journal of Central South University》 SCIE EI CAS 2012年第2期319-323,共5页
A novel 0.1% Pd-0.05% (mass fraction) Pt/stainless steel wire mesh catalyst was prepared for volatile organic compounds (VOCs) elimination. The catalyst was synthesized by stainless steel wire mesh as support and ... A novel 0.1% Pd-0.05% (mass fraction) Pt/stainless steel wire mesh catalyst was prepared for volatile organic compounds (VOCs) elimination. The catalyst was synthesized by stainless steel wire mesh as support and then treated by anodic oxidation technology to develop a porous membrane on the support. During the anodic oxidation process, various electrolytes were used to investigate the formation of porous membrane. And the catalytic performance of the catalysts was tested by using toluene and acetone combustion as model reaction. The temperatures of complete toluene and acetone conversion were decreased to 180℃ and 240 ℃, respectively. The morphologies of the stainless steel wire mesh supports and catalysts were characterized by means of scanning electron microscopy (SEM) and temperature-programmed reduction (TPR). 展开更多
关键词 volatile organic compounds anodic oxidation ELECTROLYTE PD
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