Experimental study on closed-cycle solar adsorption cooling system

A closed-cycle solar-powered adsorption cooling system is designed.The system is mainly composed of the evacuated tubular solar collectors with an area of 150 m^2,two adsorption chillers with a rated cooling capacity of 15 kW,a cooling tower,fan coils and circulating pumps.The experiments were carried out to study the operating characteristics and the performance of the system.It is found that the operation of the system presents wave characteristics because of low water capacity.The water temperatures of the inlet and the outlet of the solar collector array cyclically swing since the water entering the solar collector array comes directly from the adsorption chillers.Besides,the inlet water temperature of the adsorption chillers varies distinctly.However,the cooling effect of the system is satisfactory.Compared with an open-cycle system,the closed-cycle system has the advantage of a high electric COP（coefficient of performance）because of the reduced use of circulating pumps.

Soil Microbial Characteristics Under Long-Term Heavy Metal Stress:A Case Study in Zhangshi Wastewater Irrigation Area,Shenyang

Soil samples were collected from Zhangshi Wastewater Irrigation Area in the suburb of Shenyang City,China,an area with a 30-year irrigation history with heavy metal-containing wastewater.The chemical properties and microbial characteristics of the soils were examined to evaluate the present situation of heavy metal pollution and to assess the soil microbial characteristics under long-term heavy metal stress.In light of the National Environmental Quality Standards of China,the soil in the test area was heavily polluted by Cd and to a lesser degree by Zn and Cu,even though wastewater irrigation ceased in 1993.Soil metabolic quotient (qCO_2) had a significant positive correlation,while soil microbial quotient (qM) had a negative correlation with content of soil heavy metals.Soil microbial biomass carbon (MBC) had significantly negative correlation with Cd,but soil substrate-induced respiration (SIR),dehydrogenase activity (DHA),cellulase activity, and culturable microbial populations had no persistent correlations with soil heavy metal content.Soil nutrients,except for phosphorous,showed positive effects on soil microbial characteristics,which to a certain degree obscured the adverse effects of soil heavy metals.Soil Cd contributed more to the soil microbial characteristics,but qM and qCO_2 were more sensitive and showed persistent responses to heavy metals stress.It could be concluded that qM and qCO_2 can be used as bioindicators of heavy metal pollution in soils.

Influence of solar wind energy flux on the interannual variability of ENSO in the subsequent year

Previous studies have tended to adopt the quasi-decadal variability of the solar cycle （e.g.sunspot number （SSN） or solar radio flux at 10.7 cm （F10.7） to investigate the effect of solar activity on El Ni（n）o-Southern Oscillation （ENSO）.As one of the major terrestrial energy sources,the effect of solar wind energy flux in Earth＇s magnetosphere （Ein） on the climate has not drawn much attention,due to the big challenge associated with its quantitative estimation.Based on a new Ein index estimated by three-dimensional magnetohydrodynamic simulations from a previous study,this study reveals that Ein exhibits both quasi-decadal variability （periodic 11-year） and interannual （2-4 years） variability,which has rarely before been detected by SSN and F10.7.A significant interannual relationship between the annual mean Ein and subsequent early-winter ENSO is further revealed.Following high Ein,the sea level pressure in the subsequent early winter shows significant positive anomalies from Asia southward to the Maritime Continent,and significant negative anomalies over the Southeast and Northeast Pacific,resembling the Southern Oscillation.Meanwhile,significant upper-level anomalous convergence and divergence winds appear over the western and eastern Pacific,which is configured with significant lower-level anomalous divergence and convergence,indicating a weakening of the Walker circulation.Consequently,notable surface easterly wind anomalies prevail over the eastern tropical Pacific,leading to El Ni（n

Effects of polyaniline on electrochemical properties of composite inert anodes used in zinc electrowinning

In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI（polyaniline）-WC（tungsten carbide） composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition（DPE） of PANI and WC particles with Pb2＋ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy（SEM）.The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2＋,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.

Biphenyl Bis [π-cyclopentadienyl ） iron] Dication as an Efficient Cationic Photoinitiator for Epoxy Polymerization

Ferrocenium monocations as photoinitiators for cationic photopolymerization suffer from a limitation of low absorption and low reactivity under high-pressure Hg lamp. Here, a ferrocenium dication salt, biphenyl bis [π-cyclopentadienyl）iron] hexafluorophosphate （[bis（Cp-Fe）-biphenyl] （PF6）2 was synthesized by the ligand exchange reaction between ferrocene and biphenyl. The chemical structure was characterized with FTIR and ^1HNMR. The separation of ferrocenium monocation cyclopentadien-iron-biphenyl hexafluorophosphate （[Cp-Fe-biphenyl] PF6） and dication [bis（Cp-Fe）-biphenyl] （PF6）2 was carried out by column chromatography. The photoactivity of initiating photopolyinerization of epoxide ER14221 was studied as a cationic photoinitiator. [Bis（Cp-Fe）-biphenyl] （PF6）2 can efficiently absorb radiation above 300nm and its photoactivity is higher than that of its monocation.

New photo-thermal-synthesized polymer for self-compacting concrete to increase productivity, minimize pollution, and eliminate steam curing in precast concrete

The objective in this study is to apply the sustainable chemistry and photo-thermal synthesis technology to produce the sustainable eco-superplasticiser for the sustainable high performance SCC concrete especially in hot tropical countries. A photo-thermal synthesized eco-superplasticiser （PSES） was produced by using photo-thermal catalyst in a solar chemical reactor. In this preliminary study, an unique high early strength of SCC concrete has been successfully produced by imposing an unique proportion of the photo-thermal-synthesized eco- Superplasticiser （PSES）, local fly ash, sand and aggregate. The SCC concrete is preliminary tried in the precast concrete product to produce the complicated geometries as Tunnel segment, U-shape beam, and Box girder which have the critical reinforcement and thin section concrete. Surprisingly, this SCC provide the benefits as eliminating steaming energy, increased productivity, and minimize pollution. These unique properties of sustainable SCC concrete can not be achieved by the convention concrete by using ligno, naphthalene and melamine base superplasficiser. The synthesized sustainable eco-superplasticiser is a perfect choice to fully utilized the renewable energy and improve the concrete working environment.

ON THE DESIGN OF A NEW HUMAN COMFORT INDEX

In designing the human comfort index (CI) used in Guangzhou, a Gaussian curve was adopted as the fundamental profile to develop a traw hat?model of comfort index. The model projects low or high temperatures into low index values and the moderate temperatures into high index values. Air temperature was chosen as a basic factor in the model. Other factors such as humidity, sunshine and wind speed were introduced by considering them as temperature departures to an equivalent apparent temperature (EAT). Since the index is a relative index, 25C was chosen as an ideal apparent temperature (the most comfortable state) and a maximum CI value of 100 was assigned at this temperature. While in other circumstances, the index would be lower than 100. By utilizing this model, the daily comfort index values had been calculated for Guangzhou city for 1998-1999, using mean temperature, mean humidity, mean wind speed and total hours of sunshine. Results show that the new model was reasonable and practicable. Not only could it reflect the monthly variation of human comfort in Guangzhou, but also was sensitive to short-term changes of weather conditions.

Green large-scale production of N/O-dual doping hard carbon derived from bagasse as high-performance anodes for sodium-ion batteries

Sodium-ion batteries are considered as a promising candidate for lithium-ion batteries due to abundant sodium resources and similar intercalation chemistry.Hard carbon derived from biomass with the virtue of abundance and renewability is a cost-effective anode material.Herein,hard carbon is derived from renewable bagasse through a simple two-step method combining mechanical ball milling with carbonization.The hard carbon electrodes exhibit superior electrochemical performance with a high reversible capacity of 315 mA∙h/g.Furthermore,the initial capacity of the full cell,HC//NaMn0.4Ni0.4Ti0.1Mg0.1O2,is 253 mA∙h/g and its capacity retention rate is 77%after 80 cycles,which further verifies its practical application.The simple and low-cost preparation process,as well as excellent electrochemical properties,demonstrates that hard carbon derived from bagasse is a promising anode for sodium-ion batteries.

Possible Impact of the Summer North Atlantic Oscillation on Extreme Hot Events in China

This paper reveals that the summer North Atlantic Oscillation (SNAO) is closely related to the extreme hot event (EHE) variability in China during the period of 1979 2009, with a positive-phase (negative-phase) SNAO corresponding to less (more) EHEs in northern China. The summer circulation anomalies associated with the SNAO give further confirmation of the above relationship. In a positive-phase (negative-phase) SNAO year, there is an anomalous cyclone (anticyclone) over central East Asia, which can increase (decrease) the total cloud cover over this region. Such changes of the total cloud cover can then decrease (increase) the solar radiation reaching the surface, which is consequently unfavorable (favorable) to the formation of EHEs over northern China.

Preparation of BiOCl0.9I0.1/β-Bi2O3 composite for degradation of tetracycline hydrochloride under simulated sunlight

A novel and effective BiOCl0.9I0.1/x%β-Bi2O3 composite catalyst was synthesized through a precipitation method. The structure, morphology, and optical properties of the samples were certified by X-ray diffraction, UV-Vis diffuse reflectance, scanning electron microscopy, and X-ray photoelectron spectroscopic characterizations. Photocatalytic experiments demonstrated that the synthesized BiOCl0.9I0.1/x%β-Bi2O3 composite catalyst exhibited excellent photocatalytic performance toward the degradation of tetracycline hydrochloride(TCH) under simulated sunlight. Furthermore, the TCH degradation rate of BiOCl0.9I0.1/15%β-Bi2O3 increased by 27.6% and 61.4% compared with those of the pure BiOCl0.9I0.1 and pure β-Bi2O3, respectively. Due to the multiple vacancies and valence states possessed by BiOCl0.9I0.1/x%β-Bi2O3, namely Bi5+, Bi(3-x)+, Bi5+–O, Bi3+–O, I- and I3-, the charge separation in photocatalysis reactions can be effectively promoted. The Mott-Schottky measurements indicate that the conduction band(CB) level of BiOCl0.9I0.1/15%β-Bi2O3 becomes more negative relative to that of BiOCl0.9I0.1, guaranteeing an advantageous effect on the redox ability of the photocatalyst. This study provides a new bright spot for the construction of high-performance photocatalysts.

Synthesis and Crystal Structure of an Ion- pair Compound: [HL]_2[Ni(CN)_4]·4H_2O (L = 4-(2- Hydroxyphenyl)-1,5, 9-triazacyclododecan-2-one)

An ion-pair compound, [HL]2[Ni(CN)4]4H2O 1 has been obtained as an unexpected product when we attempt to prepare a heterometallic cyano-bridged complex by the reaction of GdCl3nH2O, K2Ni(CN)4 and L (L=4-(2-hydroxyphenyl)-1,5,9-triazacyclododecan-2-one) in aqueous solution, and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21/n with a = 12.380(1), b = 9.9637(8), c = 17.087(1) ? ?= 105.947(2)? V = 2026.6(3) ?, Rint = 0.0509, Z = 2, Dc = 1.297 g/cm3, C34H56O8N10Ni, Mr = 791.60, F(000) = 844, m(MoKa) = 0.538 mm1, S = 1.030, the final R = 0.0644 and wR = 0.1299 for 2023 observed reflections with I ≥ 2(I). The title compound 1 contains one anion of [Ni(CN)4]2, two cations of [HL]+ and four packing water molecules, which are held together by the NH···O and OH···O hydrogen bonds to form a three- dimensional framework.

The Analysis and Calculation on ECRH Anode Circuit on the HL-2A Tokamak

In the last year, ECRH system has been built in the HL-2A and the testing of gyrotron is also finished. In the project testing, one of the problems is current-peak occurring in the anode circuit of gyrotron. The current-peak is much larger than that of the value set in protection circuit. The frequent current-peak frequently occurring in the rising of anode-voltage often caused the protection circuit to mistaken trigger. The mistaken triggering often halted the normal gyrotron-testing. A set of equations of anode circuit are derived for analysis the phenomena of the current-peak. The calculation based on the deduced formula shows that value of the current-peak strongly depends on the inductance L, capacitance C and the ramp-time of anode voltage in the anode circuit. The conductance L and capacitance C are the characteristic inductance and capacitance of the cable that is used for anode HV power supply. The numerical calculation is exactly consistent with waveform of the current peak recorded by oscillograph, that means the derived formula are correct. In order to decrease the value of the current-peak, we should decrease capacitance C, and increase inductance L and ramp-time of anode voltage.

Preliminary Design Study on Concentrated Solar Power PVRs to Operate with RCBC

Parabolic through concentrators and parabolic dish concentrators followed by a PVR （pressurized volumetric receiver） are proposed, studying the performance behavior of a RCBC （regenerative closed Brayton cycle） operating with helium or hydrogen. A pressurized gas such as helium circulates along the volumetric receiver, capturing the concentrated thermal solar energy to be further converted into electric power via a thermal cycle. The overall efficiency of the plant has been computed under variable parameters to determine the operating conditions for which efficiency and specific power are acceptable. As consequence of the proposed analysis, it is concluded that direct coupling between volumetric receivers and thermal engines renders high efficiency while avoiding an intermediate heat transfer medium.

Relationship Between Built Environment, Socio-economic Factors and Carbon Emissions from Shopping Trip in Shenyang City, China

Promoting active travel behavior and decreasing transport-related carbon dioxide （CO2） emissions have become a priority in many Chinese cities experiencing rapid urban sprawl and greater automobile dependence. However, there are few studies that holistically examine the physical and social factors associated with travel CO2 emissions. Using a survey of 1525 shoppers conducted in Shenyang, China, this study estimated shopping-related travel CO2 emissions and examined how the built environment and individual socioeconomic characteristics contribute to shopping travel behavior and associated C02 emissions. We found that, firstly, private car trips generate nearly eight times more carbon emissions than shopping trips using public transport, on average. Second, there was sig- nificant spatial autocorrelation with CO2 emissions per trip, and the highest carbon emissions were clustered in the inner suburbs and between the first and second circumferential roads. Third, shopping travel CO2 emissions per trip were negatively correlated with sev- eral built environment features including population density, the quantity of public transport stations, road density, and shop density. They were also found to be significantly related to the individual socio-eeonomic characteristics of car ownership, employment status, and education level using a multinomial logistic regression model. These empirical findings have important policy implications, assisting in the development of measures that contribute to the sustainability of urban transportation and meet carbon mitigation targets.

Diffusion of Solar Energy Use in the Built Environment Supported by New Design

Places of large potentials of sustainable energy production and places of large energy consumption are often very different and separated by large distances across the globe. This paper first discusses potentials of solar technology in terms of global availability using PV （photovoltaic） technology and actual energy production. Solar energy is widely under-used and one way to reduce this is to improve production in low-energy places with high demand： large cities. According to this option, about 40% of the electricity consumption in the built environment could be produced by solar PV systems and energy storage systems. This paper discusses conditions in the built environment and functional and design qualities enabling an increased diffusion of the technologies In a comparative analysis of PV technologies, the criteria taken into account encompass efficiency of the type of solar cell and commercial availability. Special attention is paid to the design features of different PV systems, like flexibility, colour and transparency that might help in their utilization as integrated in building material and ornaments in modem architecture. The same procedure is followed for electricity storage devices. The preliminary conclusion is that at present the freedom of design is largest for a combination of crystalline silicon PV cells and Li-ion batteries.

Corrosion Behavior of Anodic Oxidized TiO_2 Film in Seawater

TiO2 films were formed on metallic titanium substrates by the anodic oxidation method in H2SO4 solution under the 80V D.C..Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions.Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves.The result showed that the TiO2 film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface.The average water contact angle of the film was 116.4? in dark, in contrast to an angle of 42.7? under the UV illumination for 2 hours, which demonstrates good hydrophobic property.The anti-corrosion behavior of the TiO2 film was declining with the extended immersion time.Under dark conditions, however, the hydrophobic TiO2 film retarded the water infiltrating into the substrate.The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight.All of those mentioned above indicate that the TiO2 film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.

Assessment Parameters of the Application of Solar Cell Technologies in the Built Environment

This paper presents a comprehensive overview of the different requirements for applications of solar cells in the built environment, particularly for the MENA （Middle East and North Africa） region. The authors emphasize the assessment of parameters additional to the cost and efficiency of the cells to make a more informed choice of the PV technology to use in specific buildings. They also emphasize the need for the wide use ofphotovoltaics in the built environment to produce electricity in the GCC （Gulf Cooperation Council） region and briefly mention the efforts being made in this regard.

Effects of solar radiation modification on the ocean carbon cycle:An earth system modeling study

Solar radiation modification(SRM,also termed as geoengineering)has been proposed as a potential option to counteract anthropogenic warming.The underlying idea of SRM is to reduce the amount of sunlight reaching the atmosphere and surface,thus offsetting some amount of global warming.Here,the authors use an Earth system model to investigate the impact of SRM on the global carbon cycle and ocean biogeochemistry.The authors simulate the temporal evolution of global climate and the carbon cycle from the pre-industrial period to the end of this century under three scenarios:the RCP4.5 CO_(2) emission pathway,the RCP8.5 CO_(2) emission pathway,and the RCP8.5 CO_(2) emission pathway with the implementation of SRM to maintain the global mean surface temperature at the level of RCP4.5.The simulations show that SRM,by altering global climate,also affects the global carbon cycle.Compared to the RCP8.5 simulation without SRM,by the year 2100,SRM reduces atmospheric CO_(2) by 65 ppm mainly as a result of increased CO_(2) uptake by the terrestrial biosphere.However,SRM-induced change in atmospheric CO_(2) and climate has a small effect in mitigating ocean acidification.By the year 2100,relative to RCP8.5,SRM causes a decrease in surface ocean hydrogen ion concentration([H^(+)])by 6% and attenuates the seasonal amplitude of[H^(+)]by about 10%.The simulations also show that SRM has a small effect on globally integrated ocean net primary productivity relative to the high-CO_(2) simulation without SRM.This study contributes to a comprehensive assessment of the effects of SRM on both the physical climate and the global carbon cycle.

Primary Analysis for the Establishment of Ecological City of Mianyang

This paper probes into the establishment of ecological city of Mianyang and directive thoughts,measures, and countermoves are put forward based on analyzing the current situation about ecological environment of MianyangCity.