This paper mainly aims at the modeling problem of the photovoltaic (PV) array with a 30 kW PV grid-connected generation system. An iterative method for the time-varying parameters is proposed to model a plant of PV ar...This paper mainly aims at the modeling problem of the photovoltaic (PV) array with a 30 kW PV grid-connected generation system. An iterative method for the time-varying parameters is proposed to model a plant of PV array. The relationship of PV cell and PV array is obtained and the solution for PV array model is unique. The PV grid-connected generation system is used to demonstrate the effectiveness of the proposed method by comparing the calculated values with the actual output of the system.展开更多
An oriented array of electron transporting nanowires, grown directly on a transparent conductor constitutes an optimal architecture for efficient photovoltaic applications. In addition, semiconductor nanocrystals can ...An oriented array of electron transporting nanowires, grown directly on a transparent conductor constitutes an optimal architecture for efficient photovoltaic applications. In addition, semiconductor nanocrystals can work as efficient light absorbers because of their tunable optical properties. In this paper, we use an oriented array of TiO2 nanowires grown directly on a transparent conductive electrode and subsequently sensitized with colloidally grown CdSeS nanocrystal quantum dots （QDs）, using an efficient bi-linker assisted methodology, to demonstrate photovoltaic cells. Upon excitation with light, exciton dissociation takes place at the nanowire-nanocrystal interface, after which, electrons are transported to the fluorine-doped tin oxide （FTO） electrode via single-crystalline TiO2 nanowire channels. We demonstrate that an ex situ ligand exchange of QDs followed by sensitization on oxygen-plasma treated TiO2 nanowires results in enhanced loading of QDs, as compared to the in situ ligand exchange approach. An array of 1μm long TiO2 nanowire sensitized with CdSeS nanocrystals exhibits photovoltaic effects with a short-circuit current of 2-3 mA/cm2, an open circuit voltage of 0.6-0.7 V and a fill factor of 52-5%, resulting in devices with efficiencies of up to 0.6%.展开更多
基金Supported by the National Natural Science Foundation of China (61233004, 61074061)the State Key Development Program for Basic Research of China (2013CB035500)+1 种基金the National High Technology Research and Development Program of China(2011AA040901)Key Project of Ministry of Railways of China (J2011J004)
文摘This paper mainly aims at the modeling problem of the photovoltaic (PV) array with a 30 kW PV grid-connected generation system. An iterative method for the time-varying parameters is proposed to model a plant of PV array. The relationship of PV cell and PV array is obtained and the solution for PV array model is unique. The PV grid-connected generation system is used to demonstrate the effectiveness of the proposed method by comparing the calculated values with the actual output of the system.
文摘An oriented array of electron transporting nanowires, grown directly on a transparent conductor constitutes an optimal architecture for efficient photovoltaic applications. In addition, semiconductor nanocrystals can work as efficient light absorbers because of their tunable optical properties. In this paper, we use an oriented array of TiO2 nanowires grown directly on a transparent conductive electrode and subsequently sensitized with colloidally grown CdSeS nanocrystal quantum dots （QDs）, using an efficient bi-linker assisted methodology, to demonstrate photovoltaic cells. Upon excitation with light, exciton dissociation takes place at the nanowire-nanocrystal interface, after which, electrons are transported to the fluorine-doped tin oxide （FTO） electrode via single-crystalline TiO2 nanowire channels. We demonstrate that an ex situ ligand exchange of QDs followed by sensitization on oxygen-plasma treated TiO2 nanowires results in enhanced loading of QDs, as compared to the in situ ligand exchange approach. An array of 1μm long TiO2 nanowire sensitized with CdSeS nanocrystals exhibits photovoltaic effects with a short-circuit current of 2-3 mA/cm2, an open circuit voltage of 0.6-0.7 V and a fill factor of 52-5%, resulting in devices with efficiencies of up to 0.6%.
