Polyethylene (PE) films with additives consisting mainly of oleic acid and ferrous ions were subjected to accelerated degradation at simulated composting temperatures.Based on Fourier transform infrared spectroscopy a...Polyethylene (PE) films with additives consisting mainly of oleic acid and ferrous ions were subjected to accelerated degradation at simulated composting temperatures.Based on Fourier transform infrared spectroscopy and measurements of mechanical properties and viscosity average molecular weight,the degradation of the films was characterized and the degradation mechanism was discussed.The films containing additives with ferrous ions represent considerable decreases in molecular weight,and the carbonyl groups and hydroperoxides in the aging films show different trends of increase with the aging time.These results indicate that the ferrous ion plays an important role in the degradation of PE films and accelerates the degradation of PE.展开更多
The catalytic effects of the organic compounds of iron,tin and manganese on the degradation of low density polyethylene (LDPE) at compost temperature are discussed.A series of samples were aged in a simulating compost...The catalytic effects of the organic compounds of iron,tin and manganese on the degradation of low density polyethylene (LDPE) at compost temperature are discussed.A series of samples were aged in a simulating compost environment.The mechanical properties,viscosity average molecular weight (M η) of PE and hydroperoxide (POOH) concentration in the samples were measured.FT IR and DSC were also applied to characterize some samples.It was shown that the above mentioned metallic organic compounds can catalyze the degradation of LDPE efficiently.After 2 months aging,all samples with catalysts became fragile and the M η of the material decreased dramatically.Furthermore,the concentration of carbonyl and the degree of crystallinity of the material increased with the aging time.展开更多
[Objective] This study was conducted to find an effective method to control heavy metals in tobacco. [Method] Field experiments were carried out in the culture process of flue-cured tobacco, and the effects of applica...[Objective] This study was conducted to find an effective method to control heavy metals in tobacco. [Method] Field experiments were carried out in the culture process of flue-cured tobacco, and the effects of application of rapeseed cake at different amounts in reducing heavy metal contents in tobacco were investigated. [Result] The application of different amounts of rapeseed cake as the base fertilizer had a positive effect in reducing heavy metal contents in tobacco, and the treatment applied with oil cake accounting for 30% of total fertilizer showed an effect significantly different from that of the CK. [Conclusion] This study has a positive effect on the improvement of tobacco safety, and provides certain scientific guide for the improvement of tobacco safety by improving fertilization modes and fertilizer kinds and for the selection and pretreatment of fertilizers, which are of very important significance to practical production.展开更多
Oxytetracycline(OTC) and tetracycline(TC) are the most common TC antibiotics used in human and veterinary medicine.Residual amounts of these antibiotics in manure pose a potential threat to public and ecological healt...Oxytetracycline(OTC) and tetracycline(TC) are the most common TC antibiotics used in human and veterinary medicine.Residual amounts of these antibiotics in manure pose a potential threat to public and ecological health as a result of the potential for them to be released to the environment following land application of manure from animals treated with antibiotics.We investigated the degradation of OTC and TC during anaerobic composting.We tested the effects of temperature and antibiotic concentration on degradation rates in a control and in manure spiked with TCs.We examined changes in p H,biological degradation material(BDM),and moisture corresponding with antibiotic degradation of TCs in the swine manure.Results showed that the OTC and TC concentrations decreased by between 68.54% and 95.50% in all nine treatments following 14 days of anaerobic composting,and the highest removal ef ficiencies were observed at an incubation temperature of 55°C and initial concentrations of 10.36 μg·g^(-1),and 5.96 μg·g^(-1) of OTC and TC,respectively,which were degraded by 95.50%,and 90.06%.During composting at 55 °C and at added concentrations of 5 μg·g^(-1),OTC decreased rapidly,and the time required for50% and 90% degradation was 4.1 and 9.8 days,respectively;for TC,these values were 4.4 and 14.0 days,respectively.Removal ef ficiencies for all TCs correlated well with moisture content of the manure.These results show that composting may be a practical and useful means to reduce concentrations of OTC and TC in swine manure prior to its land application.展开更多
Long-term climatic data (maximum temperature, minimum temperature, rainfall and evaporation) for Big Bend in the Lowveld, a semi-arid region of Swaziland, were analysed for any changes or variations. Evaporation and...Long-term climatic data (maximum temperature, minimum temperature, rainfall and evaporation) for Big Bend in the Lowveld, a semi-arid region of Swaziland, were analysed for any changes or variations. Evaporation and rainfall data were analysed to assess water resources availability in the region. Analysis of the available data shows that there is no indication of decrease in rainfall with time, but the results show that there has been a steady increase in minimum temperatures over the last 25 years. The average effective water resources index, measured as the difference between mean annual rainfall and mean annual evaporation, for the region in the period from 1965 to 2001 was -1,500 mm. The large negative index implies low available water for the region, a situation that is likely to affect agricultural, hydropower and other water related development activities in the region. The negative effective water index implies deficits in the region's water resources which call for better management of the region's water resources. In the agriculture sector, this requires promoting technologies and practices that provide for water saving, improved water use performance and high water productivity. These include soil conservation tillage, wastewater reuse, runoff harvesting and soil fertility interventions through application of fertilizers, manures and mulches, and agronomic management. There is need for more analysis for the other regions in order to get a countrywide picture of the climate as well as water resources situations.展开更多
While lifestyle modifications are currently used as firstline treatment for subjects with gastroesophageal reflux disease (GERD), the pathogenetic role of lifestyle factors and consequently, the efficacy of lifestyle ...While lifestyle modifications are currently used as firstline treatment for subjects with gastroesophageal reflux disease (GERD), the pathogenetic role of lifestyle factors and consequently, the efficacy of lifestyle measures is controversial. Our aim was to systematically review the pathogenetic link between overweight/ obesity, dietary habits, physical activity and GERD, and the beneficial effect of specific recommended changes, by means of the available literature from the 1999 to the present. Obesity, in particular, abdominal obesity, plays a key role in determining GERD symptoms and complications through mechanical and metabolic effects. Controlled weight loss (by diet or surgery) is effective in improving GERD symptoms. No definitive data exist regarding the role of diet and, in particular, of specific foods or drinks, in influencing GERD clinical manifestations. Moderate physical activity seems to be beneficial for GERD, while vigorous activity may be dangerous in predisposed individuals. In conclusion, being obese/overweight and GERD-specific symptoms and endoscopic features are related, and weight loss significantly improves GERD clinical-endoscopic manifestations. The role of dietary behavior, mainly in terms of specific dietary components, remains controversial. Mild routine physical activity in association with diet modifications, i.e. a diet rich in fiber and low in fat, is advisable in preventing reflux symptoms.展开更多
Limestone soil is a poor quality soil with a low rate of nutrient supply due to the accumulation of organic carbon. Here, we examined the degradation of maize straw in limestone soil and red soil using indoor simulati...Limestone soil is a poor quality soil with a low rate of nutrient supply due to the accumulation of organic carbon. Here, we examined the degradation of maize straw in limestone soil and red soil using indoor simulation. Dynamic testing was conducted on soil chemical properties and soil fertility. We found that the degradation rate of straw in karst soil is higher than for non-karst soil. The highest degradation rate of straw occurred during the first 60 d, after which it rose slowly and balanced out at 98 d. The peak value of degradation of straw in karst soil was found at 28 d, while that in non-karst soil occurred at 42 d. The total period of degradation lasted 160 d; the degradation rate of straw in karst soil and non-karst soil was 77% and 75%, respectively. During the period of straw degradation, the pH of soil tended to decrease in the early stage and rise slowly in later stages and this is consistent with the pattern of degradation products during different stages of straw degradation. Straw return to fields can increase soil fertility, and the growth rate of available N and K content is significant. Compared to karst soil, the content of various fertility indicators in non-karst areas were lower according to total content tests, although the increase (percentage) in nonkarst area was higher; available P and K content were found to be higher in non-karst areas according to availability tests. Some available nutrients Jn straw return can be more readily released in non-karst soil, while karst soil can contribute to the accumulation of total nutrient content due to its special soil texture features, the firm binding of many nutrients with clay minerals and the slow supply of nutrients.展开更多
文摘Polyethylene (PE) films with additives consisting mainly of oleic acid and ferrous ions were subjected to accelerated degradation at simulated composting temperatures.Based on Fourier transform infrared spectroscopy and measurements of mechanical properties and viscosity average molecular weight,the degradation of the films was characterized and the degradation mechanism was discussed.The films containing additives with ferrous ions represent considerable decreases in molecular weight,and the carbonyl groups and hydroperoxides in the aging films show different trends of increase with the aging time.These results indicate that the ferrous ion plays an important role in the degradation of PE films and accelerates the degradation of PE.
文摘The catalytic effects of the organic compounds of iron,tin and manganese on the degradation of low density polyethylene (LDPE) at compost temperature are discussed.A series of samples were aged in a simulating compost environment.The mechanical properties,viscosity average molecular weight (M η) of PE and hydroperoxide (POOH) concentration in the samples were measured.FT IR and DSC were also applied to characterize some samples.It was shown that the above mentioned metallic organic compounds can catalyze the degradation of LDPE efficiently.After 2 months aging,all samples with catalysts became fragile and the M η of the material decreased dramatically.Furthermore,the concentration of carbonyl and the degree of crystallinity of the material increased with the aging time.
基金Supported by Science and Technology Project of Hongyun Honghe Tobacco(Group)Co.,Ltd.(HYHH2013YL01)Tea Science Specialty Practice and Training Base Construction Project of Institute of Agricultural and Garden Technology,Pu'er University~~
文摘[Objective] This study was conducted to find an effective method to control heavy metals in tobacco. [Method] Field experiments were carried out in the culture process of flue-cured tobacco, and the effects of application of rapeseed cake at different amounts in reducing heavy metal contents in tobacco were investigated. [Result] The application of different amounts of rapeseed cake as the base fertilizer had a positive effect in reducing heavy metal contents in tobacco, and the treatment applied with oil cake accounting for 30% of total fertilizer showed an effect significantly different from that of the CK. [Conclusion] This study has a positive effect on the improvement of tobacco safety, and provides certain scientific guide for the improvement of tobacco safety by improving fertilization modes and fertilizer kinds and for the selection and pretreatment of fertilizers, which are of very important significance to practical production.
基金Supported by the Innovative Team Foundation of Zhejiang Province(2013TD12)the International Science and Technology Cooperation Program of China(2014DFE90040)the Significant Science and Technology Project of Zhejiang Province(2015C33006)
文摘Oxytetracycline(OTC) and tetracycline(TC) are the most common TC antibiotics used in human and veterinary medicine.Residual amounts of these antibiotics in manure pose a potential threat to public and ecological health as a result of the potential for them to be released to the environment following land application of manure from animals treated with antibiotics.We investigated the degradation of OTC and TC during anaerobic composting.We tested the effects of temperature and antibiotic concentration on degradation rates in a control and in manure spiked with TCs.We examined changes in p H,biological degradation material(BDM),and moisture corresponding with antibiotic degradation of TCs in the swine manure.Results showed that the OTC and TC concentrations decreased by between 68.54% and 95.50% in all nine treatments following 14 days of anaerobic composting,and the highest removal ef ficiencies were observed at an incubation temperature of 55°C and initial concentrations of 10.36 μg·g^(-1),and 5.96 μg·g^(-1) of OTC and TC,respectively,which were degraded by 95.50%,and 90.06%.During composting at 55 °C and at added concentrations of 5 μg·g^(-1),OTC decreased rapidly,and the time required for50% and 90% degradation was 4.1 and 9.8 days,respectively;for TC,these values were 4.4 and 14.0 days,respectively.Removal ef ficiencies for all TCs correlated well with moisture content of the manure.These results show that composting may be a practical and useful means to reduce concentrations of OTC and TC in swine manure prior to its land application.
文摘Long-term climatic data (maximum temperature, minimum temperature, rainfall and evaporation) for Big Bend in the Lowveld, a semi-arid region of Swaziland, were analysed for any changes or variations. Evaporation and rainfall data were analysed to assess water resources availability in the region. Analysis of the available data shows that there is no indication of decrease in rainfall with time, but the results show that there has been a steady increase in minimum temperatures over the last 25 years. The average effective water resources index, measured as the difference between mean annual rainfall and mean annual evaporation, for the region in the period from 1965 to 2001 was -1,500 mm. The large negative index implies low available water for the region, a situation that is likely to affect agricultural, hydropower and other water related development activities in the region. The negative effective water index implies deficits in the region's water resources which call for better management of the region's water resources. In the agriculture sector, this requires promoting technologies and practices that provide for water saving, improved water use performance and high water productivity. These include soil conservation tillage, wastewater reuse, runoff harvesting and soil fertility interventions through application of fertilizers, manures and mulches, and agronomic management. There is need for more analysis for the other regions in order to get a countrywide picture of the climate as well as water resources situations.
文摘While lifestyle modifications are currently used as firstline treatment for subjects with gastroesophageal reflux disease (GERD), the pathogenetic role of lifestyle factors and consequently, the efficacy of lifestyle measures is controversial. Our aim was to systematically review the pathogenetic link between overweight/ obesity, dietary habits, physical activity and GERD, and the beneficial effect of specific recommended changes, by means of the available literature from the 1999 to the present. Obesity, in particular, abdominal obesity, plays a key role in determining GERD symptoms and complications through mechanical and metabolic effects. Controlled weight loss (by diet or surgery) is effective in improving GERD symptoms. No definitive data exist regarding the role of diet and, in particular, of specific foods or drinks, in influencing GERD clinical manifestations. Moderate physical activity seems to be beneficial for GERD, while vigorous activity may be dangerous in predisposed individuals. In conclusion, being obese/overweight and GERD-specific symptoms and endoscopic features are related, and weight loss significantly improves GERD clinical-endoscopic manifestations. The role of dietary behavior, mainly in terms of specific dietary components, remains controversial. Mild routine physical activity in association with diet modifications, i.e. a diet rich in fiber and low in fat, is advisable in preventing reflux symptoms.
基金National Natural Science Foundation of China(41302289)the Natural Science Foundation of Guangxi(2014GXNSFBA118225)+1 种基金the Project of the China Geological Survey(12120113005300)the Ministry of Land and Resource(201211086-05)
文摘Limestone soil is a poor quality soil with a low rate of nutrient supply due to the accumulation of organic carbon. Here, we examined the degradation of maize straw in limestone soil and red soil using indoor simulation. Dynamic testing was conducted on soil chemical properties and soil fertility. We found that the degradation rate of straw in karst soil is higher than for non-karst soil. The highest degradation rate of straw occurred during the first 60 d, after which it rose slowly and balanced out at 98 d. The peak value of degradation of straw in karst soil was found at 28 d, while that in non-karst soil occurred at 42 d. The total period of degradation lasted 160 d; the degradation rate of straw in karst soil and non-karst soil was 77% and 75%, respectively. During the period of straw degradation, the pH of soil tended to decrease in the early stage and rise slowly in later stages and this is consistent with the pattern of degradation products during different stages of straw degradation. Straw return to fields can increase soil fertility, and the growth rate of available N and K content is significant. Compared to karst soil, the content of various fertility indicators in non-karst areas were lower according to total content tests, although the increase (percentage) in nonkarst area was higher; available P and K content were found to be higher in non-karst areas according to availability tests. Some available nutrients Jn straw return can be more readily released in non-karst soil, while karst soil can contribute to the accumulation of total nutrient content due to its special soil texture features, the firm binding of many nutrients with clay minerals and the slow supply of nutrients.